Abstract
This chapter discussed the introduction of nanoclay into natural fibre reinforced composites (in practice, reinforced with lignocellulosic fibres from plants, therefore referred here as plant fibre composites, abbreviated as PFC) in terms of improvement of mechanical and thermal properties. A number of issues are to be accounted for, which include the specificity and hierarchical structure of the different lignocellulosic fibres, therefore their significant variability in mechanical terms, which results also in a substantial dimensional variability when introduced in the composite. More specifically, the main effects encountered by this introduction, in amounts normally variable between 1 and 5 wt %, would concern the reduction of viscoelastic behaviour of the composite and achieving improved dimensional control, provided a sufficient interaction of the nanoclay in the compositeĀ is obtained. This is particularly significant on one side aiming at an effective production of injection moulded PFCs and on the other side in connection with the use of biodegradable matrices, focusing on the production of a fully sustainable composite.
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References
Alamri, H., Low, I.M., Alothman, Z.: Mechanical, thermal and microstructural characteristics of cellulose fibre reinforced epoxy/organoclay nanocomposites. Compos. B 43(7), 2762ā2771 (2012)
Ali, E.S., Ahmad, S.: Bionanocomposite hybrid polyurethane foam reinforced with empty fruit bunch and nanoclay. Compos. B 43(7), 2813ā2816 (2012)
Aly, M., Hashmi, M.S.J., Olabi, A.G., Messeiry, M., Hussain, A.I., Abadir, E.F.: Effect of nano-clay and waste glass powder on the properties of flax fibre reinforced mortar. ARPN J. Eng. Appl. Sci. 6(10), 19ā28 (2011)
Arrieta, M.P., LĆ³pez, J., FerrĆ”ndiz, S., Peltzer, M.A.: Characterization of PLA-limonene blends for food packaging applications. Polym. Testing 32(4), 760ā768 (2013)
Assaedi, H., Shaikh, F.U.A., Low, I.M.: Utilization of nanoclay to reinforce flax fabric-geopolymer composites. Int. J. Chem. Mol. Nucl. Mater. Metall. Eng. 9(12), 1297ā1305 (2015)
Barmar, M., Barikani, M., Fereidounnia, M.: Study of polyurethane/clay nanocomposites produced via melt intercalation method. Iran. Polym. J. 15(9), 709ā714 (2006)
Bensadoun, F., Kchit, N., Billotte, C., Bickerton, S., Trochu, F., Ruiz, E.: A study of nanoclay reinforcement of biocomposites made by liquid composite molding. Int. J. Polym. Sci. 964193 (2011)
Biswal, M., Mohanty, S., Nayak, S.K.: Influence of organically modified nanoclay on the performance of pineapple leaf fiber-reinforced polypropylene nanocomposites. J. Appl. Polym. Sci. 114(6), 4091ā4103 (2009)
Bordes, P., Pollet, E., AvĆ©rous, L.: Nano-biocomposites: biodegradable polyester/nanoclay systems. Prog. Polym. Sci. 34(2), 125ā155 (2009)
Chan, M., Lau, K., Wong, T., Ho, M., Hui, D.: Mechanism of reinforcement in a nanoclay/polymer composite. Compos. B 42(6), 1708ā1712 (2011)
Chen, L., Wong, S.C., Pisharath, S.: Fracture properties of nanoclay-filled polypropylene. J. Appl. Polym. Sci. 88(14), 3298ā3305 (2003)
Deepak, K., Reddy, N.S., Naidu, T.V.S.: Thermosetting polymer and nano clay based natural fiber bio- composites. Procedia Mater. Sci. 10, 626ā631 (2015a)
Deepak, K., Prabhakar Vattikuti, S.V., Venkatesh, B.: Experimental investigation of jute fiber reinforced nanoclay composite. Procedia Mater. Sci. 10, 238ā242 (2015b)
Deka, H., Karak, N.: Vegetable oil-based hyperbranched thermosetting polyurethane/clay nanocomposites. Nanoscale Res. Lett. 4, 758ā765 (2009)
Dewan, M.W., Hossain, M.K., Hosur, M., Jeelani, S.: Thermomechanical properties of alkali treated jute-polyester/nanoclay biocomposites fabricated by VARTM process. J. Appl. Polym. Sci. 128(6), 4110ā4123 (2013)
Divya, G.S., Kakhandaki, A., Suresha, B.: Wear behavior of coir reinforced treated and untreated hybrid composites. Int. J. Innovative Res. Dev. 3(5), paper no. 50754 (2014)
Faruk, O., Matuana, L.M.: Nanoclay reinforced HDPE as a matrix for wood-plastic composites. Compos. Sci. Technol. 68, 2073ā2077 (2008)
Faruk, O., Bledzki, A.K., Fink, H.-P., Sain, M.: Biocomposites reinforced with natural fibers: 2000ā2010. Prog. Polym. Sci. 37(11), 1552ā1596 (2012)
Gassan, J., Bledzki, A.K.: Effect of moisture content on the properties of silanized jute-epoxy composites. Polym. Compos. 18(2), 179ā184 (1997)
Gassan, J., Bledzki, A.K.: Thermal degradation of flax and jute fibers. J. Appl. Polym. Sci. 82(6), 1417ā1422 (2001)
George, J., Sreekala, M.S., Thomas, S.: A review on interface modification and characterization of natural fiber reinforced plastic composites. Polym. Eng. Sci. 41(9), 1471ā1485 (2001)
Hakamy, A., Shaikh, F.U.A., Low, I.M.: Microstructures and mechanical properties of hemp fabric reinforced organoclayācement nanocomposites. Constr. Build. Mater. 49, 298ā307 (2013)
Hakamy, A., Shaikh, F.U.A., Low, I.M.: Characteristics of hemp fabric reinforced nanoclayācement nanocomposites. Cement Concr. Compos. 50, 27ā35 (2014a)
Hakamy, A., Shaikh, F.U.A., Low, I.M.: Thermal and mechanical properties of hemp fabric-reinforced nanoclay-cement nano-composites. J. Mater. Sci. 49(4), 1684ā1694 (2014b)
Hakamy, A., Shaikh, F.U.A., Low, I.M.: Thermal and mechanical properties of NaOH treated hemp fabric and calcined nanoclay-reinforced cement nanocomposites. Mater. Des. 80, 70ā81 (2015)
Han, G., Lei, Y., Wu, Q., Kojima, Y., Suzuki, S.: Bambooāfiber filled high density polyethylene composites: effect of coupling treatment and nanoclay. J. Polym. Environ. 16(2), 123ā130 (2008)
Hapuarachchi, T.D., Peijs, T.: Multiwalled carbon nanotubes and sepiolite nanoclays as flame retardants for polylactide and its natural fibre reinforced composites. Compos. A 41(8), 954ā963 (2010)
Haq, M., BurgueƱo, R., Mohanty, A.K., Misra, M.: Hybrid bio-based composites from blends of unsaturated polyester and soybean oil reinforced with nanoclay and natural fibers. Compos. Sci. Technol. 68(15ā16), 3344ā3351 (2008)
Herrera-Franco, P.J., Valadez-GonzĆ”lez, A.: A study of the mechanical properties of short natural-fiber reinforced composites. Compos. B 36(8), 597ā608 (2005)
Holbery, J., Houston, D.: Natural-fiber-reinforced polymer composites in automotive applications. JOM 58(11), 80ā86 (2006)
Hossain, M.K., Dewan, M.W., Hosur, M., Jeelani, S.: Mechanical performances of surface modified jute fiber reinforced biopol nanophased green composites. Compos. B 42(6), 1701ā1707 (2011)
Huang, X., Netravali, A.: Characterization of flax fiber reinforced soy protein resin based green composites modified with nano-clay particles. Compos. Sci. Technol. 67(10), 2005ā2014 (2007)
Iman, M., Maji, T.K.: Effect of crosslinker and nanoclay on starch and jute fabric based green nanocomposites. Carbohydr. Polym. 89(1), 290ā297 (2012)
Iman, M., Bania, K.K., Maji, T.K.: Green jute-based cross-linked soy flour nanocomposites reinforced with cellulose whiskers and nanoclay. Ind. Eng. Chem. Res. 52(21), 6969ā6983 (2013)
Iman, M., Mandal, M., Maji, T.K.: Effect of zinc oxide and nanoclay on crosslinked jute-reinforced soy flour green nanocomposites. J. Compos. Mater. Published online before print, April 15, 2015. doi: 10.1177/0021998315580831
Islam, M.S., Hamdan, S., Talib, Z.A., Ahmed, A.S., Rahman Md, R.: Tropical wood polymer nanocomposite (WPNC): the impact of nanoclay on dynamic mechanical thermal properties. Compos. Sci. Technol. 72(16), 1995ā2001 (2012a) Ā
Islam, M.S.,Ā Khan,Ā T., Park, J.K.:Ā Nanoreinforced bacterial celluloseāmontmorillonite composites for biomedical applications. Carbohyd. Polym. 89(4),Ā 1189ā1197 (2012b)
Islam, M.S., Ahmad, M.B., Hasan, M., Aziz, S.A., Jawaid, M., Haafiz, M.K.M., Zakaria, S.A.H.: Natural fiber-reinforced hybrid polymer nanocomposites: effect of fiber mixing and nanoclay on physical, mechanical, and biodegradable properties. Bioresources 10(1), 1394ā1407 (2015)
Islam, M.S., Talib, Z.A., Hasan, M., Ramli, I., Haafiz, M.K.M., Jawaid, M., Islam, A., Inuwa, I.M.: Evaluation of mechanical, morphological, and biodegradable properties of hybrid natural fiber polymer nanocomposites. Polym. Compos. Available online, doi: 10.1002/pc.23616
Kaiser, M.R., Anuar, H.: Effect of nanoclay on thermal properties of polylactic acid-kenaf hybrid bio-composite. In: International Conference on Chemical Engineering (ICChE 2011), 29ā30 December 2011, Dhaka, Bangladesh, from http://irep.iium.edu.my/id/eprint/17072. Accessed 24 Jan 2016
Kaiser, M.R., Anuar, H., Samat, N.B., Razak, S.B.A.: Effect of processing routes on the mechanical, thermal and morphological properties of PLA-based hybrid biocomposite. Iran. Polym. J. 22(2), 123ā131 (2013)
Kalia, S., Kaith, B.S., Kaur, I.: Pretreatments of natural fibers and their application as reinforcing material in polymer compositesāa review. Polym. Eng. Sci. 49(7), 1253ā1272 (2009)
Kamardin, N.K., Taib, Y.M., Kalam, A.: The effects of kenaf fiber loading reinforced polypropylene and nanoclay. Jurnal Teknologi 76(3), 53ā56 (2015)
Katschnig, M., Battisti, M.: Processing of polymer-nanoclay composites, Chapter 3 in āPolymer nanoclay compositesā. In: Laske, S. (ed.) William Andrew Publishing, ISBN 978-0323299626 (2015)
Kiliaris, P., Papaspyrides, C.D.: Polymer/layered silicate (clay) nanocomposites: an overview of flame retardancy. Prog. Polym. Sci. 35(7), 902ā958 (2010)
Klemm, D., Heublein, B., Fink, H.-P., Bohn, A.: Cellulose: fascinating biopolymer and sustainable raw material. Angew. Chem. 44(22), 3358ā3393 (2005)
Kord, B.: Effect of nanoparticles loading on properties of polymeric composite based on hemp fiber/polypropylene. J. Thermoplast. Compos. Mater. 25(7), 793ā806 (2012)
Ku, H., Wang, H., Pattarachaiyakoop, N., Trada, M.: A review on the tensile properties of natural fiber reinforced polymer composites. Compos. B 42(4), 856ā873 (2011)
Kumar, R., Yakubu, M.K., Anandjiwala, R.D.: Biodegradation of flax fiber reinforced poly lactic acid. Express Polym. Lett. 4(7), 423ā430 (2010a)
Kumar, R., Yakabu, M.K., Anandjiwala, R.D.: Effect of montmorillonite clay on flax fabric reinforced poly lactic acid composites with amphiphilic additives. Compos. A 41(11), 1620ā1627 (2010b)
La Mantia, F.P., Morreale, M.: Green composites: a brief review. Compos. A 42(6), 579ā588 (2011)
Lashgari, A., Eshghi, A., Farsi, M.A.: Study on some properties of polypropylene based nanocomposites made using almond shell flour and organoclay. Asian J. Chem. 25(2), 1043ā1049 (2013)
Li, H., Huneault, M.A.: Comparison of sorbitol and glycerol as plasticizers for thermoplastic starch in TPS/PLA blends. J. Appl. Polym. Sci. 119(4), 2439ā2448 (2011)
Li, X., Tabil, L.G., Panigrahi, S.: Chemical treatments of natural fiber for use in natural fiber-reinforced composites: a review. J. Polym. Environ. 15(1), 25ā33 (2007)
Lim, L.T., Auras, R., Rubino, M.: Processing technologies for poly(lactic acid). Prog. Polym. Sci. 33(8), 820ā852 (2008)
Majeed, K., Jawaid, M., Hassan, A., Bakar, A.A., Khalil, H.P.S.A., Salem, A.A., Inuwa, I.: Potential materials for food packaging from nanoclay/natural fibres filled hybrid composites. Mater. Des. 46, 391ā410 (2013)
Mohan, T.P., Kanny, K.: Water barrier properties of nanoclay filled sisal fibre reinforced epoxy composites. Compos. A 42(4), 385ā393 (2011)
Mohanty, S., Verma, S.K., Nayak, S.K.: Dynamic mechanical and thermal properties of MAPE treated jute/HDPE composites. Compos. Sci. Technol. 66(3ā4), 538ā547 (2006)
Mosiewicki, M.A., Aranguren, M.I.: A short review on novel biocomposites based on plant oil precursors. Eur. Polymer J. 49(6), 1243ā1256 (2013)
Pillin, I., Montrelay, N., Grohens, Y.: Thermo-mechanical characterization of plasticized PLA: is the miscibility the only significant factor? Polymer 47(13), 4676ā4682 (2006)
Rahman Md, R., Hamdan, S., Islam Md, S., Ahmed, A.S.: Main content areaInfluence of Nanoclay/Phenol Formaldehyde Resin on Wood Polymer Nanocomposites. J. Appl. Sci. 12(14), 1481ā1487 (2012)
Ra**i, N., Jappes, J.T.W., Jeyaraj, P., Rajakarunakaran, S., Bennet, C.: Effect of montmorillonite nanoclay on temperature dependence mechanical properties of naturally woven coconut sheath/polyester composite. J. Reinf. Plast. Compos. 32(11), 811ā822 (2013)
Ray, S.S., Bousmina, M.: Biodegradable polymers and their layered silicate nanocomposites: in greening the 21st century materials world. Prog. Mater. Sci. 50(8), 962ā1079 (2005)
Ray, S.S., Okamoto, M.: Polymer/layered silicate nano-composites: a review from preparation to processing. Prog. Polym. Sci. 28, 1539ā1641 (2003)
Rozman, H.D., Rozyanty, A.R., Musa, L., Tay, G.S.: Ultra-violet radiation-cured biofiber composites from kenaf: the effect of montmorillonite on the flexural and impact properties. J. Wood Chem. Technol. 30(2), 152ā163 (2010)
Saheb, D.N., Jog, J.P.: Natural fiber polymer composites: a review. Adv. Polym. Technol. 18(4), 351ā363 (1999)
Saiful Md, I., Hasbullah, N.A.B., Hasan, M., Talib, Z.A., Jawaid, M., Haafiz, M.K.: Physical, mechanical and biodegradable properties of kenaf/coir hybrid fiber reinforced polymer nanocomposites. Mater Today Commun. 4, 69ā76 (2015)
Santulli, C.: Review. Impact properties of glass/plant fibre hybrid laminates. J. Mater. Sci. 42, 3699ā3707 (2007)
Satyanarayana, K.G., Kulkarni, A.G., Rohatgi, P.K.: Structure and properties of coir fibres. In: Proceedings of the Indian Academy of Sciences C 4(4), 419ā436 (1981)
Saw, S.K.: Static and dynamic mechanical analysis of coir fiber/montmorillonite nanoclay-filled novolac/epoxy hybrid nanocomposites, Eco-friendly Polymer Nanocomposites. In: Volume 75 of the series Advanced Structured Materials, 2015, 137ā154, ISBN 978-81-322-2469-3 (2015)
Sim, I.N., Han, S.O.: Effect on modified nanoclay on dynamic mechanical and thermomechanical properties of natural fiber/polypropylene biocomposites. J. Adhes. Sci. Technol. 27(12), 1313ā1323 (2013)
Singh, R.P., Ngo, T.D., Hu, W., Ton-That, T.M., Denault, J.: Performance improvement of green composites using nanoclays, Report of National Research Council, Canada, from nrc-cnrc.gc.ca. Accessed 10 Feb 2016 (2009)
Tateyama, H., Tsunematsu, K., Kimura, K., Hirosue, H., **nai, K., Furusawa, T.: Method for producing fluorine mica, Patent n. US 5204078 A, 20 Apr 1993
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Santulli, C. (2016). Nanoclay Based Natural Fibre Reinforced Polymer Composites: Mechanical and Thermal Properties. In: Jawaid, M., Qaiss, A., Bouhfid, R. (eds) Nanoclay Reinforced Polymer Composites. Engineering Materials. Springer, Singapore. https://doi.org/10.1007/978-981-10-0950-1_4
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