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Synthesis of Nano- and Submicron-Sized Crystals for the Preparation of Oxide Glass-Ceramics with Advanced Magnetic and Dielectric Properties

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Nanoscience Advances in CBRN Agents Detection, Information and Energy Security

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Abstract

In the present study we explore the possibility to obtain nano- to submicron-sized crystals in an oxide glass-matrix which can serve as a part of the construction of various types of sensors. Two sets of compositions are developed: one in the systems Na2O/Al2O3/B2O3/SiO2/(V2O5)/Fe2O3 and Na2O/MnO/SiO2/Fe2O3 with very high concentrations of Fe2O3 (≥ 10 mol%) where the crystallization of magnetite Fe3O4 and solid solutions of the type (Fe, Mn)IIO⋅(Fe, Mn)III 2O3 is established and another in the systems Na2O/ Al2O3/BaO/TiO2/B2O3/SiO2 and Na2O/Al2O3/BaO/TiO2/B2O3/SiO2/Fe2O3. Here no or only small amounts of iron oxide (≤5.8 mol %) are used and the crystallization of cubic BaTiO3 crystals is achieved. The phase composition is investigated by X-ray diffraction and for selected glass-ceramic samples also by Raman spectroscopy. The microstructure of all synthesized materials is studied by SEM.

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Authors and Affiliations

  1. University of Chemical Technology and Metallurgy, 8 Kl. Ohridski Blvd, 1756, Sofia, Bulgaria

    R. Harizanova, A. Mazhdrakova, L. Vladislavova & I. Gugov

  2. Otto-Schott-Institut, Jena University, Fraunhoferstr. 6, 07743, Jena, Germany

    C. Bocker & C. Rüssel

  3. Institute for Physical Chemistry, Bulgarian Academy of Sciences, Acad. G. Bonchev Str. Bl. 11, 1113, Sofia, Bulgaria

    G. Avdeev

  4. Faculty of Physics, Sofia University, 5 James Bourchier Str., 1164, Sofia, Bulgaria

    M. Abrashev

Authors
  1. R. Harizanova
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  2. A. Mazhdrakova
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  3. L. Vladislavova
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  4. C. Bocker
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  5. G. Avdeev
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  6. M. Abrashev
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  7. I. Gugov
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  8. C. Rüssel
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Corresponding author

Correspondence to R. Harizanova .

Editor information

Editors and Affiliations

  1. Department of Physics, University of Chemical Technology and Metallurgy, Sofia, Bulgaria

    Plamen Petkov

  2. Department of Physics, Technical University of Moldova, Chisinau, Moldova

    Dumitru Tsiulyanu

  3. Dept. of Mathematics and Natural Sciences, University of Kassel, Kassel, Germany

    Wilhelm Kulisch

  4. Inst. of Nanostructure Technologies and Analytics, University of Kassel, Kassel, Germany

    Cyril Popov

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Harizanova, R. et al. (2015). Synthesis of Nano- and Submicron-Sized Crystals for the Preparation of Oxide Glass-Ceramics with Advanced Magnetic and Dielectric Properties. In: Petkov, P., Tsiulyanu, D., Kulisch, W., Popov, C. (eds) Nanoscience Advances in CBRN Agents Detection, Information and Energy Security. NATO Science for Peace and Security Series A: Chemistry and Biology. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-9697-2_37

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