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SrSnO3 Applied in the Reduction of NO by CO: Influence of Transition Metal Do** on the Catalytic Activity

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Research Topics in Bioactivity, Environment and Energy

Part of the book series: Engineering Materials ((ENG.MAT.))

Abstract

Strontium stannate (SrSnO3) is a perovskite, which has been extensively studied due to its potential technological applications. In this work, SrSnO3 was doped with transition metals (Cu, Fe, Ni) by the modified Pechini method and evaluated in the catalytic reduction of NO with CO. The perovskite structure was obtained as the major phase for all samples. The catalytic activity of SrSnO3 was highly improved by all the dopants, as only 10% of conversion was obtained for SrSnO3, whereas samples with 5% of Cu presented the highest conversions, reaching 100% of NO into N2 and 100% of CO into CO2 at 550 °C. Conversions of 85% of NO into N2 and 90% of CO into CO2 were obtained for Ni doped samples at 600 °C, while 62% of conversion was obtained for Fe-doped samples, for both reactions. These results indicate that Cu is the best dopant, which leads to the greatest NO conversion with a smaller amount of dopant.

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Acknowledgements

The authors acknowledge Petrobras (Process Number 2014/00327-2), for the financing of this project and CNPq Proc. 151055/2012-2.

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Authors and Affiliations

  1. NPE-LACOM, Universidade Federal da Paraíba, João Pessoa, PB, Brazil

    Guilherme L. Lucena, Danniely M. Ribeiro, João Jarllys N. de Souza, Fagner Ticiano Gomes Vieira, Ary S. Maia & Ieda Maria Garcia dos Santos

  2. Instituto Federal da Paraíba, João Pessoa, PB, Brazil

    Danniely M. Ribeiro

  3. Research Center on Advanced Materials and Energy, Universidade Federal de São Carlos, São Carlos, SP, Brazil

    Cristiane A. Pereira & Ernesto A. Urquieta-González

  4. Departmento de Engenharia, Universidade Federal de Lavras, Lavras, MG, Brazil

    Cristiane A. Pereira

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  1. Physics, Centro Brasileiro de Pesquisas Físicas, Rio de Janeiro, Brazil

    Carlton A. Taft

  2. Departamento de Quimica, Federal University of São Carlos, São Carlos, Brazil

    Sergio R. de Lazaro

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Lucena, G.L. et al. (2022). SrSnO3 Applied in the Reduction of NO by CO: Influence of Transition Metal Do** on the Catalytic Activity. In: Taft, C.A., de Lazaro, S.R. (eds) Research Topics in Bioactivity, Environment and Energy. Engineering Materials. Springer, Cham. https://doi.org/10.1007/978-3-031-07622-0_4

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