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Adulteration Analysis in Essential Oils

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Essential Oil Research

Abstract

Based on the numerous side effects of synthetically derived medicines, many people are trying to transform their lifestyles through naturopathy. Unfortunately, due to a lack of complete instrumental techniques and strict government regulation, adulteration of natural products is rampant all over the world. It is estimated that approximately 80% of commercially available, so-called “natural” essential oils are adulterated in some way. Through research and the establishment of proper standards, which include detailed chemical profiles of what authentic essential oils look like analytically, the relevance of adulterated oils in the industry should be minimized.

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References

  • Aprotosoaie AC, Hăncianu M, Costache I, Miron A (2014) Linalool: a review on a key odorant molecule with valuable biological properties. Flavour Fragr J 29:193–219. https://doi.org/10.1002/ffj.3197

    Article  CAS  Google Scholar 

  • Biedermann W, Koller H, Wedemeyer K (1978) Process for preparing thymol. United States Patent 4,086,283

    Google Scholar 

  • Bordenca C, Allison RK (1951) l-Carvone from d-limonene. Ind Eng Chem 43(5):1196–1198

    Article  CAS  Google Scholar 

  • Brumer M (2014) The mystery of drugs and perfumed olive oil: “Samim” and “besamim” in incense and holy anointment oil. J Intercult Interdiscip Archaeol 2014(1):89–102

    Google Scholar 

  • Carpenter MS, Easter WM (1955) The isopropyl cresols. J Org Chem 20(4):401–411

    Article  CAS  Google Scholar 

  • Chan WK, Tan LTH, Chan KG, Lee LH, Goh BH (2016) Nerolidol: a sesquiterpene alcohol with multi-faceted pharmacological and biological activities. Molecules 21:529. https://doi.org/10.3390/molecules21050529

    Article  CAS  PubMed Central  Google Scholar 

  • Culp RA, Noakes JE (1990) Identification of isotopically manipulated cinnamic aldehyde and benzaldehyde. J Agric Food Chem 38:1249–1255

    Article  CAS  Google Scholar 

  • Diaz-Chavez ML, Moniodis J, Madilao LL, Jancsik S, Keeling CI, Barbour EL, Ghisalberti EL, Plummer JA, Jones CG, Bohlmann J, Cirino PC (2013) Biosynthesis of sandalwood oil: Santalum album CYP76F cytochromes P450 produce santalols and bergamotol. PLoS One 8:e75053

    Article  CAS  Google Scholar 

  • Do TKT, Hadji-Minaglou F, Antoniotti S, Fernandez X (2015) Authenticity of essential oils. Trends Anal Chem 66:146–157. https://doi.org/10.1016/j.trac.2014.10.007

    Article  CAS  Google Scholar 

  • Ernst E (2002) Adulteration of Chinese herbal medicines with synthetic drugs: a systematic review. J Intern Med 252:107–113

    Article  CAS  Google Scholar 

  • Everstine K, Spink J, Kennedy S (2013) Economically motivated adulteration (EMA) of food: common characteristics of EMA incidents. J Food Prot 76(4):723–735. https://doi.org/10.4315/0362-028X.JFP-12-399

    Article  PubMed  Google Scholar 

  • Firenzuoli F, Jaitak V, Horvath G, Bassolé IHN, Setzer WN, Gori L (2014) Essential oils: new perspectives in human health and wellness. Evid Based Complement Alternat Med 2014:467363

    Article  Google Scholar 

  • Frey C (1988) Detection of synthetic flavorant addition to some essential oils by selected ion monitoring GC/MS. In: Lawrence BM, Mookherjee BD, Willis BJ (eds) Flavors and fragrance: a world perspective. Elsevier BV, Amsterdam, pp 517–524

    Google Scholar 

  • Guenther E (1992) The essential oils, volumes I–VI. Krieger Publishing Company, Malabar

    Google Scholar 

  • Harrewijn P, van Oosten AM, Piron PGM (2000) Natural terpenoids as messengers. Springer-Science+Business Media, Dordrecht

    Book  Google Scholar 

  • Heuberger E, Hongratanaworakit T, Böhm C, Weber R (2001) Effects of chiral fragrances on human autonomic nervous system parameters and self-evaluation. Chem Senses 26(3):281–292

    Article  CAS  Google Scholar 

  • Höld KM, Sirisoma NS, Ikeda T, Narahashi T, Casida JE (2000) α-Thujone (the active component of absinthe): γ-aminobutyric acid type A receptor modulation and metabolic detoxification. Proc Natl Acad Sci U S A 97(8):3826–3831

    Article  Google Scholar 

  • Huang WF, Wen KC, Hsiao ML (1997) Adulteration by synthetic therapeutic substances of traditional Chinese medicines in Taiwan. J Clin Pharmacol 37(4):344–350

    Article  CAS  Google Scholar 

  • International Organization for Standardization, ISO (2013) ISO 9235:2013: aromatic natural raw materials—vocabulary. https://www.iso.org/standard/51017.html. Accessed 28 Sep 2017

  • Krock KA, Ragunathan N, Wilkins CL (1994) Multidimensional gas chromatography coupled with infrared and mass spectrometry for analysis of Eucalyptus essential oils. Anal Chem 66(4):425–430

    Article  CAS  Google Scholar 

  • Kubeczka KH (2010) History and sources of essential oil research. In: Başer KHC, Buchbauer G (eds) Handbook of essential oils. CRC Press, Boca Raton, pp 3–38

    Google Scholar 

  • Lawrence BM (2002) Commercial essential oils: truths and consequences. In: Swift KAD (ed) Advances in flavours and fragrances. Royal Society of Chemistry, Cambridge, pp 57–83

    Chapter  Google Scholar 

  • Leiner J, Stolle A, Ondruschka B, Netscher T, Bonrath W (2013) Thermal behavior of pinan-2-ol and linalool. Molecules 18:8358–8375. https://doi.org/10.3390/molecules18078358

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  • Marriott PJ, Shellie R, Cornwell C (2001) Gas chromatographic technologies for the analysis of essential oils. J Chromatogr A 936:1–22

    Article  CAS  Google Scholar 

  • Merriam-Webster.com (n.d.) Adulterate, Merriam-Webster Dictionary. https://www.merriam-webster.com/dictionary/adulterate. Accessed 25 Sep 2017

  • NIIR Board (2004) Modern technology of perfumes, flavours and essential oils, 2nd edn. National Institute of Industrial Research, New Delhi

    Google Scholar 

  • Patočka J, Dvořák A (2004) Biomedical aspects of chiral molecules. J Appl Biomed 2:95–100

    Article  Google Scholar 

  • Radulović NS, Blagojević PD, Miltojević AB (2013) α-Linalool – a marker compound of forged/synthetic sweet basil (Ocimum basilicum L.) essential oils. J Sci Food Agric 93(13):3292–3303. https://doi.org/10.1002/jsfa.6175

    Article  CAS  PubMed  Google Scholar 

  • Rao NR, Kiran SS, Prasanthi NL (2010) Pharmaceutical impurities: an overview. Indian J Pharm Educ Res 44(3):301–310

    Google Scholar 

  • Remaud GS, Martin YL, Martin GG, Martin GJ (1997) Detection of sophisticated adulterations of natural vanilla flavors and extracts: application of the SNIF-NMR method to vanillin and p-hydroxybenzaldehyde. J Agric Food Chem 45:859–866

    Article  CAS  Google Scholar 

  • Richmond HH (1950) Preparation of cinnamaldehyde. United States Patent 2,529,186

    Google Scholar 

  • Roy J (2002) Pharmaceutical impurities—A mini-review. AAPS PharmSciTech 3(2):1–6

    Article  Google Scholar 

  • Royals EE, Horne SE (1951) Conversion of d-limonene to l-carvone. J Am Chem Soc 73(12):5856–5857

    Article  CAS  Google Scholar 

  • Sadgrove N, Jones G (2015) A contemporary introduction to essential oils: chemistry, bioactivity and prospects for Australian agriculture. Agriculture 5:48–102. https://doi.org/10.3390/agriculture5010048

    Article  CAS  Google Scholar 

  • Schipilliti L, Dugo P, Bonaccorsi I, Mondello L (2012) Authenticity control on lemon essential oils employing gas chromatography – combustion-isotope ratio mass spectrometry (GC – C-IRMS). Food Chem 131:1523–1530. https://doi.org/10.1016/j.foodchem.2011.09.119

    Article  CAS  Google Scholar 

  • Schmidt BM (2016) Regulatory and quality issues with the essential oils supply chain. In: Jeliazkov VD, Cantrell CL (eds) Medicinal and aromatic crops: production, phytochemistry, and utilization. American Chemical Society, Washington, DC, pp 27–48. https://doi.org/10.1021/bk-2016-1218.ch003

    Chapter  Google Scholar 

  • Schnaubelt K (1999) Medical aromatherapy: healing with essential oils. Frog Books, Berkeley

    Google Scholar 

  • Sell CS (2003) A fragrant introduction to terpenoid chemistry. Royal Society of Chemistry, Cambridge

    Google Scholar 

  • Shu CK, Lawrence BM (1997) Reasons for the variation in composition of some commercial essential oils. In: Risch SJ, Ho CT (eds) Spices. American Chemical Society, Washington, DC, pp 138–159. https://doi.org/10.1021/bk-1997-0660.ch012

    Chapter  Google Scholar 

  • Singh AG, Hamal JP (2013) Traditional phytotherapy of some medicinal plants used by Tharu and Magar communities of western Nepal against dermatological disorders. Sci World 11(11):81–89

    Article  Google Scholar 

  • Stipanovic RD, Puckhaber LS, Bell AA, Percival AE, Jacobs J (2005) Occurrence of (+)- and (−)-gossypol in wild species of cotton and in Gossypium hirsutum var. marie-galante (Watt). J Agric Food Chem 53:6266–6271

    Article  CAS  Google Scholar 

  • Stolle A, Ondruschka B, Hopf H (2009) Thermal rearrangements of monoterpenes and monoterpenoids. Helv Chim Acta 92:1673–1719

    Article  CAS  Google Scholar 

  • Suga T, Lee YS, Hirata T (1983) The hydroxylation of β-terpineol and its acetate with the cultured cells of Nicotiana tabacum. Bull Chem Soc Jpn 56(3):784–787

    Article  CAS  Google Scholar 

  • Sugawara Y, Hara C, Aoki T, Sugimoto N, Masujima T (2000) Odour distinctiveness between enantiomers of linalol: difference in perception and responses elicited by sensory test and forehead surface potential wave measurement. Chem Senses 25:77–84

    Article  CAS  Google Scholar 

  • Surburg H, Panten J (2006) Common fragrance and flavor materials, 5th edn. Wiley-VCH, Weinheim

    Book  Google Scholar 

  • Tang F, Zhang Q, Nie Z, Chen B, Yao S (2009) Sample preparation for analyzing traditional Chinese medicines. Trends Anal Chem 28(11):1253–1262. https://doi.org/10.1016/j.trac.2009.09.004

    Article  CAS  Google Scholar 

  • Tisserand R, Young R (2014) Essential oil safety, 2nd edn. Churchill Livingstone Elsevier, Edinburgh

    Google Scholar 

  • Tranchida PQ, Bonaccorsi I, Dugo P, Mondello L, Dugo G (2012) Analysis of Citrus essential oils: state of the art and future perspectives. A review. Flavour Fragr J 27:98–123. https://doi.org/10.1002/ffj.2089

    Article  CAS  Google Scholar 

  • Traynor S (2001) The musk dilemma. Perfumer Flavorist 26(5):28–39

    CAS  Google Scholar 

  • Turek C, Stintzing FC (2013) Stability of essential oils: a review. Compr Rev Food Sci Food Saf 12:40–53. https://doi.org/10.1111/1541-4337.12006

    Article  CAS  Google Scholar 

  • Wimmer P, Buysch HJ, Puppe L (1991) Process for the preparation of thymol. United States Patent 5,030,770

    Google Scholar 

  • World Health Organization, WHO (n.d.) Traditional and complementary medicine. http://who.int/medicines/areas/traditional/en/. Accessed 25 Sep 2017

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Author information

Authors and Affiliations

  1. Department of Chemistry, University of Alabama in Huntsville, Huntsville, AL, USA

    Prabodh Satyal & William N. Setzer

  2. Aromatic Plant Research Center, Lehi, Utah, USA

    Prabodh Satyal & William N. Setzer

Authors
  1. Prabodh Satyal
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  2. William N. Setzer
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Correspondence to William N. Setzer .

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Editors and Affiliations

  1. ARC Centre of Excellence in Plant Energy Biology and School of Agriculture, Food and Wine, University of Adelaide, Glen Osmond, SA, Australia, Graduate Program in Health Sciences, Biological and Health Sciences Center, Federal University of Maranhão, São Luís, Maranhão, Brazil

    Sonia Malik

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Satyal, P., Setzer, W.N. (2019). Adulteration Analysis in Essential Oils. In: Malik, S. (eds) Essential Oil Research. Springer, Cham. https://doi.org/10.1007/978-3-030-16546-8_9

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