Metals, Organic Compounds, and Nutrients in Long Island Sound: Sources, Magnitudes, Trends, and Impacts

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Long Island Sound

Abstract

Long Island Sound (LIS) is a relatively shallow estuary with a mean depth of 20 m (maximum depth 49 m) and a unique hydrology and history of pollutant loading. These factors have contributed to a wide variety of contamination problems in its muddy sediments, aquatic life, and water column. The LIS sediments are contaminated with toxic compounds and elements related to past and present wastewater discharges and runoff. These include nonpoint and stormwater runoff and groundwater discharges, whose character has changed over the years along with the evolution of its watershed and industrial history. Major impacts have resulted from the copious amounts of nutrients discharged into LIS through atmospheric deposition, domestic and industrial waste water flows, fertilizer releases, and urban runoff. All these sources and their effects are in essence the result of human presence and activities in the watershed, and the severity of pollutant loading and their impacts generally scales with total population in the watersheds surrounding LIS. Environmental legislation passed since the mid-to-late 1900s (e.g., Clean Air Act, Clean Water Act) has had a beneficial effect, however, and contaminant loadings for many toxic organic and inorganic chemicals and nutrients have diminished over the last few decades (O’Shea and Brosnan 2000; Trench et al. 2012; O’Connor and Lauenstein 2006; USEPA 2007). Major strides have been made in reducing the inflow of nutrients into LIS, but cultural eutrophication is still an ongoing problem and nutrient control efforts will need to continue. Nonetheless, LIS is still a heavily human impacted estuary (an “Urban Estuary,” as described for San Francisco Bay by Conomos 1979), and severe changes in water quality and sediment toxicity as well as ecosystem shifts have occurred since the European colonization in the early 1600s (Koppelman et al., 1976). The Sound has seen the most severe environmental changes over the last 400 years during its 10,000 year history (Lewis, this volume), suggesting that human impacts have overwhelmed the natural forces at play.

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Notes

  1. 1.

    Any use of trade, firm, or product names is for descriptive purposes only and does not imply endorsement by the U.S. Government.

References

  • Aber JD, Goodale CL, Ollinger SV, Smith M-L, Magill AH, Martin ME, Stoddard JL (2003) Is nitrogen deposition altering the nitrogen status of northeastern forests? Bioscience 53:375–390

    Article  Google Scholar 

  • Adams D, Benyi S (2003) Final report: sediment quality of the NY/NJ harbor system: A 5-year revisit 1993/4–1998. EPA/902-R-002. USEPA-Region 2, Division of Environmental Science and Assessment. Edison, NJ

    Google Scholar 

  • Adams DA, O’Connor JS, Weisberg SB (1998) Final report: sediment quality of the NY/NJ Harbor system—an investigation under the regional environmental monitoring and assessment program (REMAP). EPA/902-R-98-001. USEPA-Region 2, Division of Environmental Science and Assessment. Edison, NJ

    Google Scholar 

  • Andersen T (2004) This fine piece of water. An environmental history of Long Island Sound. Yale University Press, New Haven 274

    Google Scholar 

  • Andersen N (2005) The history of eutrophication and hypoxia in Long Island Sound. Undergraduate thesis, Wesleyan University, Middletown CT, 159

    Google Scholar 

  • Anisfeld SC, Barnes RT, Altabet MA, Wu T (2007) Isotopic apportionment of atmospheric and sewage nitrogen sources in two Connecticut rivers. Env Sci Technol 41:6363–6369

    Article  CAS  Google Scholar 

  • Balcom PH, Fitzgerald WF, Vandal GM, Lamborg CH, Rolfhus KR, Langer CS, Hammerschmidt CH (2004) Mercury sources and cycling in the Connecticut River and Long Island Sound. Mar Chem 90:53–74

    Article  CAS  Google Scholar 

  • Benoit G, Rozan TF, Patton P, Arnold CL (1999) Trace metals and radionuclides reveal sediment sources and accumulation rates in Jordan Cove Connecticut. Estuaries Coasts 22(1):65–80

    Article  CAS  Google Scholar 

  • Bjerklie DM, Trombley TJ, Viger RJ (2011) Simulations of historical and future trends in snowfall and groundwater recharge for basins draining to Long Island Sound. Earth Interact 15:1–35

    Article  Google Scholar 

  • Boesch DF, Brinsfield RB, Magnien RE (2001) Chesapeake Bay eutrophication: Scientific understanding, ecosystem restoration, and challenges for agriculture. J Environ Qual 30(2):303–320

    Article  PubMed  CAS  Google Scholar 

  • Böhm F, Haase-Schramm A, Eisenhauer A, Dullo W-Chr, Joachimski MM, Lehnert H, Reitner J (2002) Evidence for preindustrial variations in the marine surface water carbonate system from coralline sponges. Geochem Geophys Geosys 3(3):10.1029/2001GC000264

  • Boon N (2008) Nutrient dynamics of Long Island Sound. Master’s thesis, Wesleyan University, Middletown CT, p 280

    Google Scholar 

  • Bowman MJ (1977) Nutrient distributions and transport in Long Island Sound. Est Coast Mar Sci 5:531–548

    Article  CAS  Google Scholar 

  • Breslin VT , Sañudo-Wilhelmy SA (1999) High spatial resolution sampling of metals in the sediment and water column in Port Jefferson Harbor. Estuaries 22(3A):669–680

    Google Scholar 

  • Breslin VT, Dart P, Clough D, Guancial S, Navarro J (2005) Sediment metal contamination in the Branford River and Harbor. Final Report CCMS-3-2005. Center for Coastal and Marine Studies, Southern Connecticut State University, 39 pp

    Google Scholar 

  • Bricker SB, Ferreira JG, Simas T (2003) An integrated methodology for assessment of estuarine trophic status. Ecol Modelling 169(2003):39–60

    Article  CAS  Google Scholar 

  • Brownawell BJ, Fisher NS, Naeher L (1991) Characterization of data based on toxic chemical contaminations in Long Island Sound. Final Report to LISS, 112 pp (plus appendices)

    Google Scholar 

  • Buchholtz ten Brink MR, Mecray EL, Galvin EL (2000) Clostridium perfringens in Long Island Sound sediments: an urban sedimentary record. J Coastal Res 16:591–612

    Google Scholar 

  • Carey JC, Fulweiler RW (2011) Human activities directly alter watershed dissolved silica fluxes. Biogeochem. doi:10.1007/s10533-011-9671-2

    Google Scholar 

  • Castro MS, Driscoll CT (2002) Atmospheric nitrogen deposition to estuaries in the mid-Atlantic and northeastern United States. Environ Sci Technol 36:3242–3249

    Article  PubMed  CAS  Google Scholar 

  • Church VME (2009) A comparative study of sediment metal Clinton and Milford Harbors, CT. Dissertation, Southern Connecticut State University, New Haven, 55 pp

    Google Scholar 

  • Cochran JK, Hirschberg DJ, Wang J, Dere C (1998) Atmospheric deposition of metals to coastal waters (Long Island Sound, New York U.S.A.): Evidence from salt marsh deposits. Estuarine Coastal Shelf Sci 46:503–522

    Article  CAS  Google Scholar 

  • Collier TK, Anulaction BF, Bill BD (1998) Hepatic CYP1A in winter flounder (Pleuronectes americanus) along the Northeast Coast: Results from the National Benthic Surveillance Project. Mar Poll Bull 37:86–91

    Google Scholar 

  • Colombo MJ, Trench ECT (2002) Trends in surface-water quality in Connecticut: US Geological Survey Water-Resources Investigations Report 02-4012, 39

    Google Scholar 

  • Conklin J (2008) Metal concentrations in the sediment of the Housatonic River. Undergraduate thesis, Southern Connecticut State University, New Haven CT, 58 pp

    Google Scholar 

  • CTDEEP (2011) Report of the nitrogen credit advisory board for calendar year 2010 to the Joint Standing Environment Committee of the General Assembly. CTDEEP, Hartford, 47 pp http://www.ct.gov/dep/lib/dep/water/municipal_wastewater/nitrogen_report_2010.pdf

  • Conomos TJ (1979) San Francisco Bay: the urbanized estuary, Pacific Division. American Association for the Advancement of Science, San Francisco, 493 pp

    Google Scholar 

  • Cooper S, Brush GS (1993) A 2,500-year history of anoxia and eutrophication in Chesapeake Bay. Estuaries 38:617–626

    Article  Google Scholar 

  • Cravotta III CA (2002) Use of isotope of carbon, nitrogen, and sulfur to identify sources of nitrogen in surface waters in the lower Susquehanna River Basin, Pennsylvania. USGS Water-Supply Paper, 2497, p. 99

    Google Scholar 

  • Cuomo C, Valente R, Dogru D (2005) Seasonal variations in sediment and bottom water chemistry of western Long Island Sound: implications for lobster mortality. J Shellfish Res 24(3):805–814

    Google Scholar 

  • Diaz RJ (2001) Overview of hypoxia around the world. J Environ Qual 30:275–281

    Article  PubMed  CAS  Google Scholar 

  • Denver JM, Cravotta III CA, Ator SW, Lindsey BD (2010) Contributions of phosphorus from groundwater to streams in the Piedmont, Blue Ridge, and Valley and Ridge Physiographic Provinces, Eastern United States. U.S. Geological Survey Scientific Investigations Report 2010–5176, New Cumberland

    Google Scholar 

  • DeWitt JC, Shnyra A, Badr MZ, Loveless SE, Hoban D, Frame SR, Cunard R, Anderson SE, Meade BJ, Peden-Adams MM, Luebke RW, Luster MI (2009) Immunotoxicity of perfluorooctanoic acid and perfluorooctane sulfonate and the role of peroxisome proliferator-activated receptor alpha. Crit Rev Toxicol 39:76–94

    Article  PubMed  CAS  Google Scholar 

  • Dortch Q, Rabalais NN, Turner RE, Qureshi NA (2001) Impacts of changing Si/N ratios and phytoplankton species composition, in Coastal Hypoxia-consequences for living resources and ecosystems. Am Geophys Union, Washington, pp 37–48

    Book  Google Scholar 

  • Duffy TA, McElroy AE, Conover DO (2009) Variable susceptibility and response to estrogenic chemicals in Menidia menidia. Mar Ecol Prog Ser 380:245–254

    Article  CAS  Google Scholar 

  • Ficke JF, Hawkinson RO (1975) The national stream quality accounting network (NASQAN)-some questions and answers: U.S. Geol Surv Circ 719:23

    Google Scholar 

  • Fitzgerald WF, Vandal GM, Rolfhus KR, Lamborg CH, Langer CS (2000) Mercury emissions and cycling in the coastal zone. J Environ Sci 12:92–101

    Google Scholar 

  • Fitzgerald WF, Lamborg CH, Hammerschmidt CR (2007) Marine biogeochemical cycling of mercury. Chem Revs 107(2):641–662

    Article  CAS  Google Scholar 

  • Flegal AR, River-Duarte I, Ritson PI, Scelfo GM, Smith GJ, Gordon MR, Sañudo-Wilhelmy SA (1996) Metal contamination in San Francisco Bay waters: Historic perturbations, contemporary concentrations, and future considerations, in San Francisco Bay: the ecosystem, Pacific Division, American Association for the Advancement of Science, San Francisco, pp 173–188

    Google Scholar 

  • Fredette TJ, Germano JD, Kullberg PG, Carey DA, Murray P (1992) Chemical stability of capped dredged material disposal mounds in Long Island Sound USA. Chem Ecol 7:173–194

    Article  CAS  Google Scholar 

  • Fredette TF, French GT (2004) Understanding the physical and environmental consequences of dredged material disposal: History in New England and current perspectives. Mar Poll Bull 49(1–2):93–102

    Article  CAS  Google Scholar 

  • Gilliom RJ, Alley WM, Gurtz ME (1995) Design of the National Water-Quality Assessment Program—Occurrence and distribution of water-quality conditions: U.S. Geol Surv Circ 1112:33

    Google Scholar 

  • Gobler CJ, Nathan J, Buck NJ, Sieracki ME, Sañudo-Wilhelmy SA (2006) Nitrogen and silicon limitation of phytoplankton communities across an urban estuary: The East River-Long Island Sound system. Estuar Coast Shelf Sci 68:127–138

    Article  CAS  Google Scholar 

  • Grady SJ, Mullaney JR (1998) Natural and human factors affecting shallow water quality in surficial aquifers in the Connecticut, Housatonic, and Thames River basins: U.S. Geological Survey Water-Resources investigations Report 98-4042, p 81

    Google Scholar 

  • Greig RA, Reid RN, Wenzloff DR (1977) Trace metal concentrations in sediments from Long Island Sound. Mar Poll Bull 8:183–188

    Article  CAS  Google Scholar 

  • Gronlund WD, Chan S-L, McCain BB, Clark Jr. RC, Myers, MS, Stein JE, Brown DW, Landahl JT, Krahn MM, Varanasi U (1991) Multidisciplinary assessment of pollution at three sites in Long Island Sound. Estuaries 14:299–305

    Google Scholar 

  • Hammerschmidt CR, Fitzgerald WF (2006) Bioaccumulation and trophic transfer of methylmercury in Long Island Sound. Arch Environ Contam Toxicol 51:416–424

    Article  PubMed  CAS  Google Scholar 

  • Hammerschmidt CR, Fitzgerald WF, Balcom PH, Visscher PT (2008) Organic matter and sulfide inhibit methylmercury production in sediments of New York/New Jersey Harbor. Mar Chem 109:165–182

    Article  CAS  Google Scholar 

  • Hem JD (1985) Study and interpretation of the chemical characteristics of natural water (third edition): U.S. Geological Survey Water-Supply Paper 2254, 263 pp

    Google Scholar 

  • Hodgkiss IJ, Ho KC (1998) Are changes in N:P ratios in coastal waters the key to increased red tide blooms? In: Asia-Pacific Conference on Science and Management of Coastal Environment Developments in Hydrobiology, vol 123:141–147

    Google Scholar 

  • Houde M, De Silva AO, Muir DCG, Letcher RJ (2011) Monitoring of perfluorinated compound sin aquatic biota: an updated review. Environ Sci Technol 45:7962–7973

    Article  PubMed  CAS  Google Scholar 

  • Humborg C, Conley DJ, Rahm L, Wulff F, Cociasu A, Ittekkot V (2000) Silicon retention in river basins: Far-reaching effects on biogeochemistry and aquatic food webs in coastal marine environments. Ambio 29(1):45–50

    Google Scholar 

  • Jackson JBC, Kirby MX, Berger WH, Bjorndal KA, Botsford LW, Bourque BJ, Bradbury RH, Cooke R, Erlandson J, Estes JA, Hughes TP, Kidwell S, Lange CB, Lenihan HS, Pandolfi JM, Peterson CH, Steneck RS, Tegner MJ, Warner RW (2002) Historical overfishing and the recent collapse of coastal ecosystems. Science 293:629–638

    Google Scholar 

  • Keeling CD, Piper SC, Bacastow RB, Wahlen M, Whorf TP, Heimann M, HA Meijer (2005) Atmospheric CO2 and 13CO2 exchange with the terrestrial biosphere and oceans from 1978 to 2000: Observations and carbon cycle implications. In: Ehleringer JR, Cerling TE, Dearing MD (eds) A history of atmospheric CO2 and its effects on plants, animals, and ecosystems. Springer, New York

    Google Scholar 

  • Kemp WM, Boynton WR, Adolf JE, Boesch DF, Boicourt WC, Brush G, Cornwell JC, Fisher TR, Glibert PM, Hagy JD, Harding LW, Houde ED, Kimmel DG, Miller WD, Newell RIE, Roman MR, Smith EM, Stevenson JC (2005) Eutrophication of Chesapeake Bay: Historical trends and ecological interactions. Mar Ecol Prog Ser 303:1–29

    Article  Google Scholar 

  • Kimbrough KL, Johnson WE, Lauenstein GG, Christensen JD, Apeti DA (2009) An assessment of polybrominated diphenyl ethers (PBDEs) in sediments and bivalves of the U.S. coastal zone. Silver Spring, MD. NOAA Technical Memorandum NOS NCCOS, vol 94, 87 pp

    Google Scholar 

  • Knebel HJ, Lewis RS, Varekamp JC (eds) (2000) Regional processes, conditions and characteristics of the Long Island Sound sea floor. J Coast Res 16(3):519–662

    Google Scholar 

  • Kolpin DW, Furong ET, Meyer MT, Thurman EM, Zaugg SD, Barber LB, Buxton HT (2002) Pharmaceuticals, hormones, and other organic wastewater contaminants in U.S. streams, 1999–2000: a national reconnaissance. Environ Sci Technol 36:1202–1211

    Article  PubMed  CAS  Google Scholar 

  • Koppelman LE, Weyl PK, Grant GM, Davies DS (1976) The urban sea: Long Island Sound. Praeger Publishers, New York 223 pp

    Google Scholar 

  • Kuivila KM, Foe CG (1995) Concentrations, transport, and biological effects of dormant spray pesticides in the San Francisco Estuary California. Environ Toxicol Chem 14(7):1141–1150

    Article  CAS  Google Scholar 

  • Kuwabara JS, Arai Y, Top** BR, Pickering IJ, George GN (2007) Mercury speciation in piscivorous fish from mining-impacted reservoirs. Environ Sci Tech 41(8):2745–2749

    Article  CAS  Google Scholar 

  • Langer CS, Fitzgerald WF, Visscher PT, Vandal GM (2001) Biogeochemical cycling of methylmercury at Barn Island Salt Marsh, Stonington, CT, USA. Wetlands Ecol Manag 9:295–310

    Article  CAS  Google Scholar 

  • Latimer JS, Boothman WS, Pesch CE, Chmura GL, Pospelova V, Jayaramen S (2003) Environmental stress and recovery: the geochemical record of human disturbance in New Bedford Harbor and Apponagansett Bay, Massachusetts. Sci Total Environ 313:153–176

    Article  PubMed  CAS  Google Scholar 

  • Lee A (2010) Metal concentrations in the sediment of the Thames River and New London Harbor. Dissertation, Southern Connecticut State University, New Haven, CT, 64 pp

    Google Scholar 

  • Lee X, Benoit G, Hu X (2000) Total gaseous mercury concentration and flux at a coastal salt marsh in Connecticut, USA. Atmos Environ 34:4205–4213

    Article  CAS  Google Scholar 

  • Lee YJ, Lwiza KMM (2008) Characteristics of bottom dissolved oxygen in Long Island Sound, New York. Est Coast Shelf Sci 76:187–200

    Article  Google Scholar 

  • Litke DW (1999) Review of phosphorus control measures in the United States and their effects on water quality: U.S. Geological Survey Water-Resources Investigations Report 99-4007, 38 pp

    Google Scholar 

  • Long Island Sound Study (LISS) (1993) Toxic substance contamination-assessment of conditions and management recommendations: The Long Island Sound Study comprehensive conservation and management plan support document, Draft, 68 pp

    Google Scholar 

  • Long Island Sound Study (LISS) (1994) The comprehensive conservation and management plan, 205 pp, http://longislandsoundstudy.net/wp-content/uploads/2011/10/management_plan.pdf

  • Long ER, Wolfe DA, Carr RS, Scott KJ, Thursby GB (1995) Magnitude and extent of sediment toxicity in the Hudson-Raritan Estuary. NOAA Technical Memorandum NOS ORCA XX Silver Spring, New York

    Book  Google Scholar 

  • Long ER, Morgan LG (1990) The potential for biological effects of sediment-sorbed contaminants tested in the National Status and Trends Program. NOAA Technical Memorandum NOS OMA 52. National Oceanic and Atmospheric Administration, Seattle

    Google Scholar 

  • Loucaides S, Cahoon LB, Henry EJ (2007) Effects of watershed impervious cover on dissolved silica loading in storm flow. J Am Water Resources Assn 43(4):841–849

    Article  CAS  Google Scholar 

  • Lugolobi F (2003) Environmental issues in Long Island Sound. MA thesis, Wesleyan University, Middletown CT 210 pp

    Google Scholar 

  • Lugolobi F, Varekamp JC, Thomas E, Buchholtz ten Brink MR (2004) The use of Carbon isotopes in foraminiferal calcite to trace changes in biological oxygen demand in Long Island Sound. In: Proceeding of the sixth Biennual LIS research conference, pp 47–51

    Google Scholar 

  • Luo Y, Yang X, Carley RJ, Perkins C (2002) Atmospheric deposition of nitrogen along the Connecticut coastline of Long Island Sound: a decade of measurements. Atmos Environ 36(28):4517–4528

    Article  CAS  Google Scholar 

  • Luoma SN, Phillips DJH (1988) Distribution, variability, and impacts of trace elements in San Francisco Bay. Mar Poll Bull 19(9):413–425

    Article  CAS  Google Scholar 

  • Mazzaferro DL, Handman EH, Thomas, MP (1979) Water resources inventory of Connecticut, part 8, Quinnipiac River basin. Connecticut Water Resources Bulletin 27, 88 p

    Google Scholar 

  • McElroy AE, Barron G, Beckvar N, Kane Driscoll SB, Meador JP, Parkerton TF, Preuss TG, Steevens JA (2011) A review of the tissue residue approach for organic and organometallic compounds in aquatic organisms. Int Environ Assess Manag 7:50–74

    Google Scholar 

  • Meador J (2006) Rationale and procedures for using the tissue-residue approach for toxicity assessment and determination of tissue, water and sediment quality guidelines for aquatic organisms. Hum Ecol Risk Assess 12:1018–1073

    Article  CAS  Google Scholar 

  • Mecray EL, Buchholtz ten Brink MR (2000) Contaminant distribution and accumulation in the surface sediments of Long Island Sound. J Coastal Res 16(3):575–590

    Google Scholar 

  • Mecray EL, Reid JM, Hastings ME, Buchholtz ten Brink MR (2003) Contaminated sediments database for Long Island Sound and the New York Bight. U.S. Geological Survey open-file report no. 03-241, Available at http://pubs.usgs.gov/of/2003/of03-241

  • Meyers PA (1997) Organic geochemical proxies of paleoceanographic, paleolimnologic, and paleoclimatic processes. Org Geochem 27:213–250

    Article  CAS  Google Scholar 

  • Mitch AA, Anisfeld SC (2010) Contaminants in Long Island Sound: data synthesis and analysis. Est Coasts 33:609–628

    Article  CAS  Google Scholar 

  • Monosson E, Stegeman JJ (1994) Induced cytochrome P45011A in winter flounder, Pleuronectes americanus, from offshore and coastal sites. Can J Fish Aquat Sci 51:933–941

    Article  CAS  Google Scholar 

  • Mullaney JR (2007) Nutrient loads and ground-water residence times in an agricultural basin in north-central Connecticut. U.S. Geological Survey Scientific Investigations Report 2006–5278, 45 pp

    Google Scholar 

  • Mullaney JR, Schwarz GE, Trench ECT (2002) Estimation of nitrogen yields and loads from basins draining to Long Island Sound, 1988-98. U.S. Geological Survey Water-Resources Investigations Report 02–4044, 84 pp

    Google Scholar 

  • Mullaney JR, Lorenz DL, Arntson AD (2009) Chloride in groundwater and surface water in areas underlain by the glacial aquifer system, northern United States. U.S. Geological Survey Scientific Investigations Report 2009–5086, 41 pp

    Google Scholar 

  • National Research Council (1985) Oil in the sea: inputs, fates, and effects. National Academy Press, Washington

    Google Scholar 

  • National Research Council (2003) Oil in the sea III: Inputs, fates, and effects. National Academy Press, Washington

    Google Scholar 

  • National Atmospheric Deposition Program (NRSP-3) (2009) NADP Program Office, Illinois State Water Survey, 2204 Griffith Dr, Champaign, p 61820

    Google Scholar 

  • National Oceanic and Atmospheric Administration (NOAA) (1999) Sediment quality guidelines developed for the National Status and Trends Program http://response.restoration.noaa.gov/book_shelf/121_sedi_qual_guide.pdf

  • National Oceanic and Atmospheric Administration (1994) Biological effects of toxic contaminants in sediments from Long Island Sound and environs. NOAA Technical Memorandum NOS ORCA 80. National Ocean Survey, Office of Ocean Resources Conservation and Assessment, Silver Spring, New York

    Google Scholar 

  • Nelson DA, Miller JE, Rusanowksy D, Greig RA, Sennefelder GR, Mercaldo-Allen R, Kuropat C, Gould E, Thurberg FP, Calabrese A (1991) Comparative reproductive success of winter flounder in Long Island Sound: A three-year study (biology, biochemistry, and chemistry). Estuaries 14:318–331

    Article  CAS  Google Scholar 

  • Neurath R (2009) Atmospheric mercury deposition in an isolated environment: A 150-year record at Block Island, RI. Senior thesis, Smith College, Northampton, 103 pp

    Google Scholar 

  • NYSDEC and CTDEP (2000) A total maximum daily load analysis to achieve water quality standards for dissolved oxygen in Long Island Sound. Report for LISS; http://www.dec.ny.gov/docs/water_pdf/tmdllis.pdf

  • O’Connor TP (1996) Trends in chemical concentrations in mussels and oysters collected from the US coast from 1986 to 1993. Mar Environ Res 41(2):183–200

    Article  Google Scholar 

  • O’Connor TP, Lauenstein GG (2006) Trends in chemical concentrations in mussels and oysters collected along the US coast: update to 2003. Mar Environ Res 62:261–285

    Article  PubMed  Google Scholar 

  • O’Shea ML, Brosnan TM (2000) Trends in indicators of eutrophication in Western Long Island Sound and the Hudson-Raritan Estuary. Estuaries 23:877–901

    Article  Google Scholar 

  • Parker CA, O’Reilly JE (1991) Oxygen depletion in Long Island Sound: a historical perspective. Estuaries 14:248–264

    Article  CAS  Google Scholar 

  • Paul JF, Gentile JH, Scott KJ, Schimmel SC, Campbell DE, Latimer RW (1999) EMAP-virginian province four-year Assessment (1990-93). US EPA NHEERL, Narragansett, EPA/6320/R-99/004, 199 pp

    Google Scholar 

  • Perdue EM, Koprivnjak J-F (2007) Using the C/N ratio to estimate terrigenous inputs of organic matter to aquatic environments. Est Coast Shelf Sci 73:65–72

    Article  Google Scholar 

  • Perry ER, Norton SA, Kamman NC, Lorey PM, Haines T, Driscoll CT (2005) Mercury accumulation in lake sediments in the northeastern United States during the last 150 years. Ecotox 14:113–124

    Article  Google Scholar 

  • Perry DM, Hughes JB, Hebert AT (1991) Sublethal abnormalities in embryos of winter flounder, Pseudopleuronectes Americanus. Estuaries 14:306–317

    Article  Google Scholar 

  • Pinder RW, Appel KW, Dennis RL (2011) Trends in atmospheric reactive nitrogen for the Eastern United States. Environ Poll 159:3138–3141

    Article  CAS  Google Scholar 

  • Robertson A, Gottholm BW, Turgeon DD, Wolfe DA (1991) A comparative study of contaminant levels in Long Island Sound. Estuaries 14:290–298

    Article  CAS  Google Scholar 

  • Rodenburg, LA, Valle SN, Panero MA, Munoz GR, Shore LM (2010) Mass balances on selected polycyclic aromatic hydrocarbons in the New York-New Jersey Harbor. J Environ Qual 39(2):642

    Google Scholar 

  • Rolfhus KR, Fitzgerald WF (2001) The evasion and spatial/temporal distributions of mercury species in Long Island Sound, CT-NY. Geochim Cosmochim Acta 65:407–418

    Article  CAS  Google Scholar 

  • Romany JS (2010) Measures of immune system status in young-of-the-year winter flounder (Pseudopleuronectes americanus) from Long Island coastal bays. Dissertation, Stony Brook University, Stony Brook, 47 pp

    Google Scholar 

  • Rozan TF, Benoit G (2001) Mass balance of heavy metals in New Haven Harbor, Connecticut Preponderance of nonpoint sources. Limnol Oceanogr 46(8):2032–2049

    Article  CAS  Google Scholar 

  • Runkel RL, Crawford CG, Cohn TA (2004) Load estimator (LOADEST)—A FORTRAN program for estimating constituent loads in streams and rivers: U.S. Geol Sur Tech Methods 4(A5): 69 pp

    Google Scholar 

  • Sañudo-Wilhelmy SA, Flegal AR (1992) Anthropogenic silver in the Southern California Bight: a new tracer of sewage in coastal waters. Environ Sci Tech 26:2147–2151

    Article  Google Scholar 

  • Scancar J, Milacic R, Strazar M, Burica O (2000) Total metal concentrations and partitioning of Cd, Cr, Cu, Fe, Ni and Zn in sewage sludge. Sci Total Environ 250(1–3):9–19

    Article  PubMed  CAS  Google Scholar 

  • Schuster PF, Krabbenhoft DP, Naftz DI, Dewayne Cecil I, Olson ML, Dewild JF, Susong DD, Green JR, Abbott MI (2002) Atmospheric mercury deposition during the last 270 years: a glacial ice core record of natural and anthropogenic sources. Environ Sci Technol 36:2303–2310

    Google Scholar 

  • Scorca MP, Monti Jr J (2001) Estimates of nitrogen loads entering Long Island Sound from ground water and streams on Long Island, New York, 1985-96. U.S. Geological Survey Water-Resources Investigations Report 00-4196, 29 pp

    Google Scholar 

  • Skinner LC, Kane MW, Gottschall K, Simpson DA (2009) Chemical residue concentrations in four species of fish and the American lobsters from Long Island Sound, Connecticut and New York 2006 and 2007. Report to the Environmental Protection Agency

    Google Scholar 

  • Smith VH (2003) Eutrophication of freshwater and coastal marine ecosystems: a global problem. Environ Sci Pollut Res Int 10(2):126–139

    Article  PubMed  CAS  Google Scholar 

  • Sommer U (1994) Are marine diatoms favoured by high Si:N ratios? Mar Ecol-Prog Ser 115:309–315

    Article  CAS  Google Scholar 

  • Sprague LA, Mueller DK, Schwarz GE, Lorenz DL (2009) Nutrient trends in streams and rivers of the United States, 1993–2003. U.S. Geological Survey Scientific Investigations Report 2008–5202, 196 pp

    Google Scholar 

  • Thomas E, Abramson I, Varekamp JC, Buchholtz ten Brink MR (2004) Eutrophication of Long Island Sound as traced by benthic foraminifera. In: Proceedings of the sixth Biennual LIS research conference pp 87–91

    Google Scholar 

  • Thomas E, Gapotchenko T, Varekamp JC, Mecray EL, Buchholtz ten Brink MR (2000) Benthic foraminifera and environmental changes in Long Island Sound. J Coast Res 6:641–655

    Google Scholar 

  • Titus T (2003) Trace metal contents and physical characteristics of sediment in Bridgeport Harbor. Undergraduate thesis, Southern Connecticut State University, New Haven, CT, 74 pp

    Google Scholar 

  • Trench ECT, Moore RB, Ahearn EA, Mullaney JR, Hickman RE, Schwarz GE (2012) Nutrient concentrations and loads in the northeastern United States—Status and trends, 1975–2003. U.S. Geological Survey Scientific Investigations Report, East Hartford

    Google Scholar 

  • Trench ECT, Vecchia AV (2002) Water-quality trend analysis and sampling design for streams in Connecticut, 1968–98. U.S. Geological Survey Water-Resources Investigations Report 02–4011, East Hartford

    Google Scholar 

  • Trench ECT (1996) Trends in surface-water quality in Connecticut, 1969-88: U.S. Geological Survey Water-Resources Investigations Report 96-4161, 176 pp

    Google Scholar 

  • Trench ECT (2000) Nutrient sources and loads in the Connecticut, Housatonic, and Thames River Basins: U.S. Geological Survey Water-Resources Investigations Report 99-4236, 66 pp

    Google Scholar 

  • Triplett LD, Engstrom DR, Conley DJ, Schellhaass SM (2008) Silica fluxes and trap** in two contrasting natural impoundments of the upper Mississippi River. Biogeochem 87:217–230

    Article  CAS  Google Scholar 

  • Tseng CM, Balcom PH, Lamborg CH, Fitzgerald WF (2003) Dissolved elemental mercury investigations in Long Island Sound using online Au amalgamation-flow injection analysis. Environ Sci Tech 37:1183–1188

    Article  CAS  Google Scholar 

  • Turgeon DD, O’Connor TP (1991) Long Island Sound: distribution, trends, and effects of chemical contamination. Estuaries 14:279–289

    Article  CAS  Google Scholar 

  • USEPA (2001) 2001 National land cover data: Multi-resolution land characteristics consortium, accessed 1 February 2010 at http://www.epa.gov/mrlc/nlcd-2001.html

  • USEPA (2000) TMDL report for nitrogen, http://longislandsoundstudy.net/wp-content/uploads/2010/03/Tmdl.pdf

  • USEPA (2001) Water quality criterion for the protection of human health: Methylmercury. EPA-823-R-01-001, Washington

    Google Scholar 

  • USEPA (2007) National Estuary program coastal condition report. Chapter 3: Northeast National Estuary program coastal condition, Long Island Sound Study http://water.epa.gov/type/oceb/nep/upload/2007_05_09_oceans_nepccr_pdf_nepccr_nepccr_ne_partg.pdf

  • USEPA (2008) National coastal condition report III. Chapter 3. Northeast coast coastal condition. http://water.epa.gov/type/oceb/assessmonitor/upload/2008_12_09_oceans_nccr3_chapter3_northeast-a.pdf

  • Varekamp JC (1991) Trace element geochemistry and pollution history of mudflat and marsh sediments from the Connecticut coastline. J Coastal Res 11:105–123

    Google Scholar 

  • Varekamp JC (2011) Wethersfield cove, a 300 year urban pollution record. GSA annual meeting, Minneapolis, (Abstract 188–10)

    Google Scholar 

  • Varekamp JC, Buchholtz ten Brink MR, Mecray EL, Kreulen B (2000) Mercury in Long Island Sound sediments. J Coastal Res 16:613–626

    Google Scholar 

  • Varekamp JC, Kreulen B, Buchholtz ten Brink MF, Mecray E (2003) Mercury contamination chronologies from Connecticut wetlands and Long Island Sound Sediments. Environ Geol 43:268–282

    Google Scholar 

  • Varekamp JC, Thomas E, Lugolobi F, Buchholtz ten Brink MR (2004) The paleo-environmental history of Long Island Sound as traced by organic carbon, biogenic silica and isotope/trace element studies in sediment cores. In: Proceedings of sixth Biennual LIS research conference, pp. 109–113

    Google Scholar 

  • Varekamp JC, Mecray EL, Zierzow T (2005) Once spilled, still found: Metal contamination in Connecticut wetlands and Long Island Sound sediment from historic industries. In: Whitelaw, DM and Visiglione, GR (eds), America’s changing coasts-private rights and public trust. E. Elgar Publishing, Northampton, vol 9, pp. 122–147

    Google Scholar 

  • Varekamp JC (2006) The historic fur trade and climate change. EOS Trans Am Geophys Union 87:596–597

    Article  Google Scholar 

  • Varekamp JC, Altabet M, Thomas E, Buchholtz Ten Brink M, Andersen N, Mecray E (2009) Carbon cycling in LIS: nutrient fluxes and landscape development over the last 1000 years. In: Proceedings of the ninth Biennual LIS research conference

    Google Scholar 

  • Varekamp JC, Thomas E (2010) Report to CTDEP on paleoenvironmental research in Long Island Sound. http://www.wesleyan.edu/ees/JCV/varekamp.html (LIS Report)

  • Ward DM, Nislow KH, Chen CY, Folt CC (2010) Rapid, efficient growth reduces mercury concentrations in stream-dwelling Atlantic salmon. Trans Am Fisheries Soc 139:1–10

    Article  CAS  Google Scholar 

  • Welsh BL, Eller FC (1991) Mechanisms controlling summertime oxygen depletion in Western Long Island Sound. Estuaries 14:265–278

    Article  CAS  Google Scholar 

  • Whalin L, Kim EH, Mason R (2007) Factors influencing the oxidation, reduction, methylation and demethylation of mercury species in coastal waters. Mar Chem 107(3):278–294

    Article  CAS  Google Scholar 

  • Windom HLS, Schroop SJ, Calder FD, Ryan JD, Smith Jr., RG, Burney LC, Lewis FG, Rawlinson CH (1989) Natural trace metal concentrations in estuarine and coastal marine sediments of the southwestern Unites States. Environ Sci Tech 23:314–320

    Google Scholar 

  • Wolfe DA, Monahan R, Stacey PE, Farrow DRG, Robertson A (1991) Environmental quality of Long Island Sound: assessment and management issues. Estuaries 14:224–236

    Article  CAS  Google Scholar 

  • Wolfe DA, Bricker SB, Long ER, Scott KJ, Thursby GB (1994) Biological effects of toxic contaminants in sediments from Long Island Sound and environs. NOAA Technical Memorandum, NOS ORCA 80

    Google Scholar 

  • Yang L, Li X, Crusius J, Jans U, Melcer ME, Zhang P (2007) Persistent chlordane concentrations in Long Island South sediment; implications from chlordane, 210Pb, and 137Cs profiles. Environ Sci Technol 41:7723–7729

    Article  PubMed  CAS  Google Scholar 

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Varekamp, J.C., McElroy, A.E., Mullaney, J.R., Breslin, V.T. (2014). Metals, Organic Compounds, and Nutrients in Long Island Sound: Sources, Magnitudes, Trends, and Impacts. In: Latimer, J., Tedesco, M., Swanson, R., Yarish, C., Stacey, P., Garza, C. (eds) Long Island Sound. Springer Series on Environmental Management. Springer, New York, NY. https://doi.org/10.1007/978-1-4614-6126-5_5

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