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Structural and spectroscopic characterization, electronic properties, and biological activity of the 4-(3-methoxyphenyl)piperazin-1-ium 4-(3-methoxyphenyl)piperazine-1-carboxylate monohydrate
In this study, 4-(3-methoxyphenyl)piperazin-1-ium 4-(3-methoxyphenyl)piperazine-1-carboxylate monohydrate was synthesized and characterized by using...
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In Vitro Cytotoxicity of Zinc(II) Complexes: Synthesis, Characterization, and Biological Potential
Three new complexes, namely BP1, GP1, and FP1 were synthesized by interacting metal zinc with benzoic acid, gluconic acid, and folic acid (BL1, GL1,...
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Synthesis, crystal structure and antimicrobial activities of two silver(I) complexes based on bis(pyrazole) and carboxylic acid co-ligands
Two dinuclear and centrosymmetric silver-containing complexes, namely [Ag 2 (3,5-dmpz) 2 (3,5-dmpz methanol) 2 (tbtc)] ( 1 ) and [Ag 2 (3,5-dmpz) 2 (3,5-dmpz...
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Two Cd(II) Complexes Based on Carboxylate and Bis(imidazolyl) Ligands: Syntheses, Crystal Structures and Luminescence Properties
AbstractTwo new metal–organic coordination complexes, {[Cd 8 (tdc) 8 (bbi) 8 (H 2 O) 8 ]·4DMF]} n ( 1 ) and {[Cd(cbba) 2 (m-bix) 2 ]} n ( 2 ) (H 2 tdc = 2,5-thiophenedicar...
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Synthesis, Structural Characterization of Schiff Base Ligands and Their RuII‐p‐Cymene Complexes, and Catalytic Activity in the Transfer Hydrogenation of Ketones
In this study, two new Schiff base ligands, ( E )-ethyl...
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Synthesis and Fluorescent Characteristics Study of Two Novel Co(II) Complexes
In this work, two novel mixed-ligand CPs that has a compositions of [Co 2 (µ-Hdppa) 2 (phen) 2 (H 2 O) 2 ] ( 1 ) and {[Co(µ-Hdppa)(µ-4,4′-bipy)(H 2 O)]·H 2 O} n ( 2 )...
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Heteroleptic Cobalt Complexes with Abnormally Coordinated N-Heterocyclic Carbene
AbstractThe reaction of cobalt pivalate [Co(Piv) 2 ] n and in situ generated N‑heterocyclic carbene IPrPh...
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Complexes of Zinc, Nickel(II), and Cobalt(II) Cymantrenate Complexes with Pyrazole and 3,5-Dimethylpyrazole: Synthesis and Structural Features
AbstractThe reaction of cymantrenates M[(OOС 5 CH 4 )Mn(CO) 3 ] 2 (MeOH) 4 (M = Zn, Co(II), Ni(II)) with pyrazole (HPz) results in replacement of labile...
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Crystal structure, molecular docking with SARS-CoV-2 receptors, and potential drug property of tetrahedral Zn(II) complexes
The recent global pandemic by the outbreak of the SARS-CoV-2 virus caused about seven million deaths worldwide. The WHO approved the repurposing of...
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Effect of Fe(III) Complexes with Citric and Ethylenediaminedisuccinic Acids on the Photodegradation and Mineralization of the Herbicide Triclopyr in Aqueous Solution
AbstractUsing the method of stationary photolysis with HPLC detection and analysis for total organic carbon, it has been shown that the presence of...
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Green synthesis of a Schiff base ligand and its Co(II), Cu(II) and Zn(II) complexes: thermoanalytical and spectroscopic studies
Schiff bases are organic compounds that present a broad biological activity, which can be improved by the coordination with different metal ions....
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Luminescence properties of Eu3+ complexes based on macrocyclic ligands and its colorimetric analysis for white warm phosphor
The development of phosphors for warm white light plays a decisive role in the quest for energy-efficient and environmentally friendly lighting...
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New Nitrogen-, Sulfur- and Carboxylate Containing High Based Alkylphenolate Additive to Motor Oils and the Study of Their Properties
For the first time nitrogen-, sulfur- and carboxylate containing highly alkaline AKI-224 and AKI-223 additives for motor oils have been obtained by...
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New Zn(II) Complexes of Pyrazole-Based Ligands: Synthesis, Characterization, and Inhibition of the Activity of Isoenzymes of Carbonic Anhydrase
Two new Zn(II) complexes of (4-benzoyl-1-(3-nitrophenyl)-5-phenyl-1 H -pyrazole-3-carbonyl)(5-sulfamoyl- 1,3,4-thiadiazol-2-yl)amide ( L 1 ) and...
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Synthesis Methods, Structure, and Applications of Metal Dicyanoaurate, Tetracyanoaurate, and Dihalodicyanoaurate Complexes
AbstractCyanoaurate complexes represent a broad class of compounds with diverse structures. In particular, coordination polymers based on these...
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Molecular and Electronic Structures of Biologically Relevant Alkali and Alkali Earth Metal Mandelate Complexes in Aqueous Solution: Insights from Density Functional Theory
AbstractThe optimized geometries of mandelate complexes of biologically important alkali (Na + , K + ) and alkali earth (Mg 2+ , Ca 2+ ) metal ions in...
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Synthesis of Water-Soluble Calcium Complexes Based on (1-Hydroxyethylidene)diphosphonic, Nitrilotrimethylenephosphonic, Ethylenediaminetetraacetic Acids, and 2-Aminoethanol
AbstractWater insoluble calcium hydroxide Ca(OH) 2 or calcium carbonate CaCO 3 react with aqueous solution of (1-hydroxyethylidene)diphosphonic acid...
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Synthesis, Crystal Structure and Thermal Decomposition of Copper(II) and Manganese(II) Complexes Based on Bipyridine Dicarboxylate and 1,10-Phenanthroline
AbstractTwo novel transition metal complexes of the formulae [Cu(5,5′-bpdc)(phen)] n ( 1 ) and [Mn(6,6′-bpdc)(phen)(H 2 O)]·H 2 O ( 2 ) (where...
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Zinc Complexes Containing Substituted 1,10-Phenanthrolines as Ligands: Synthesis, Structure and Application as Initiators of ε-Caprolactone, Rac- and L-Lactides Polymerization
AbstractZinc complexes X 2 Zn(L) (X = Et, OAc, OC(O)CF 3 )) were synthesized in which 1,10-phenanthrolines containing substituents at positions 2, 4, 7,...
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Synthesis of nickel, calcium and magnesium naphthalene diimide complexes as supercapacitor materials
Three novel coordination complexes [Ni(H 2 L1)(DMF)] (Complex 1 ), [Ca(H 2 L2)(DMF)] (Complex 2 ), and [Mg(H 2 L2)] (Complex 3 ) have been synthesized...