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Cadmium(II) Complexes with Redox-Active Indophenol Ligands: Synthesis and Structures
AbstractThe Сd(II) complexes with redox amphoteric 2,6-di-( tert -butyl)-4-((2-hydroxyphenyl)imino)cyclohexa-2,5-dienone ligands L 1 and L 2 (adducts I , II...
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Ni(II) and Co(II) Acetato Complexes of Pyrazole-Pyridine Based Ligand: Synthesis, Structure and Thermal Decomposition
AbstractTwo novel acetato complexes with NNN type planar bdmpp ligand, [Ni(OAc)(H 2 O) 2 (bdmpp)]OAc ( 1 ) and [Co(OAc)(H 2 O) 2 (bdmpp)]OAc ( 2 ) (bdmpp:...
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Enhancing photostability of poly(vinyl chloride) through additives: diorganotin (iv)-tyrosine complexes design
Poly(vinyl chloride) (PVC) undergoes deformation via decomposition and oxidation when exposed to heat and ultraviolet (UV) radiation. To counteract...
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Synthesis, Crystal Structures, and Magnetic Studies of Two Six-Coordinate Nickel(II) Complexes with Tripodal Benzimidazole Ligands
AbstractHerein, two nickel(II) complexes [Ni(ntb)(chdc)(CH 3 OH)]⋅CH 3 OH⋅3.5H 2 O ( 1 ) and [Ni 2 (ntb) 2 (btc)(CH 3 OH)R]⋅Cl⋅4CH 3 OH⋅H 2 O ( 2 ) (chdc is trans -1,4-cy...
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New potential Mn(II) mixed ligand complexes: synthesis, structural characterization, molecular docking, antibacterial activity and electrochemical studies
5,5-{(1E,1E′)-1,4-Phenylenebis(diazene-2,1-diyl)}bis(quinoline-8-ol) (H 2 L1) as a new bis-bidentate azo dye primary ligand and its Mn(II) complexes...
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1-Pyrroline-5-carboxylate inhibit T cell glycolysis in prostate cancer microenvironment by SHP1/PKM2/LDHB axis
BackgroundOur previous studies demonstrated that 1-Pyrroline-5-carboxylate (P5C) released by prostate cancer cells inhibits T cell proliferation and...
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Construction of poly-iodine aromatic carboxylate Mn/Co frameworks and iodine adsorption behavior
Two poly-iodine aromatic tricarboxylate complexes: {(Me 2 NH 2 )[Mn(TIBTC)(2, 2'-bipy)(H 2 O)]} n ( 1 ) and {(Me 2 NH 2 )[Co(TIBTC)(DMA)]} n ( 2 ) (DMA = N , N -dimethy...
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Constants of Stability of Cobalt(II) Complexes with Glycylglycinate Ions in Aqueous Acetone Solutions
AbstractPotentiometric titration is used to determine constants of stability of cobalt(II) glycylglycinate complexes at a temperature of 298 K and...
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Neutral lanthanide complexes based on 5,6′-diaryl-2,2′-bipyridine-6-carboxylic acids: synthesis and photophysical properties
New lanthanide complexes of the composition LnL 3 (Ln = Eu III , Tb III , Dy III , Sm III ) with 5,6′-diaryl-2,2′-bipyridine-6-carboxylate anions, including...
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Two binuclear copper(II) complexes incorporated with 3-phenylpentanedioic acid: crystal structure and bioactivity characteristics
Two complexes were synthesized utilizing Cu(II) ions as central building blocks and incorporating 3-phenylpentanedioic acid and a nitrogen-containing...
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Revealing the nuclearity of iron citrate complexes at biologically relevant conditions
Citric acid plays an ubiquitous role in the complexation of essential metals like iron and thus it has a key function making them biologically...
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Synthesis and structural characterization of nickel(II) coordination complexes with mixed-ligand systems: exploring π−π stacking and hydrogen bonding in supramolecular assemblies
Two coordination complexes [Ni(Hpydco) 2 (bpy)] (1) and [Ni(pydco)(phen)(H 2 O) 2 ]·4.5H 2 O 0.5CH 3 OH (2) have been synthesized using a mixed-ligand system...
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Organotin(IV) from Simple Complexes to Macromolecules: A Review Inspired by the Late Professor Charles Carraher
The coordination chemistry of the organotin(IV) compounds is dominated by nitrogen and oxygen donor ligands. Some of these complexes have found...
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Transition Metal (Zn(II), Co(II), Cu(II), Ni(II)) Complexes for the Removal of Acidic Sulfur Impurities from Hydrocarbon Fuel
AbstractThe review addresses the main approaches to desulfurization of hydrocarbon products by adsorption methods. Examples of the use of various...
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Retraction Note to: ZERO/ONE-DIMENSIONAL COORDINATION COMPLEXES BASED ON CARBOXYLATE AND MULTINITROGEN DONOR LIGANDS: STRUCTURAL DIVERSITY AND PHOTOCATALYTIC DEGRADATION OF ORGANIC DYE
This article has been retracted. Please see the Retraction Notice for more detail: https://doi.org/10.1134/S0022476624050184
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Synthesis, Structure, and Antimicrobial Activity of Complexes of Bivalent Metals with 1-Naphthylacetic Acid
1-Naphthylacetic acid (C 10 H 7 –CH 2 COOH; HL) is a synthetic commercial plant hormone widely used in agriculture as a plant growth regulator. Five...
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Effect of crystallization conditions and position of fluorine substituents on the composition and structure of {CdTb} tetrafluorobenzoate complexes
The reaction of the 2,3,4,5-tetrafluorobenzoate (6H-tfb) compounds [Cd(H 2 O) 4 -(6H-tfb)] n • n (6H-tfb) ( 1 ) and [Tb(H 2 O) 2 (6H-tfb) 3 ] n ( 2 ) with...
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Overview of Medical and Biological Applications of Indium(III) Complexes
Indium(III) complexes are versatile species that emit Auger electrons which made them a choice for a wide range of biological and medical...
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Inorganic Complexes and Metal-Based for Biomarkers Sensors
Modern coordination chemistry is a multidisciplinary and transversal science that makes a bridge between inorganic and bioanalytical chemistry. Due... -
Carbon dioxide capture and functionalization by bis(N-heterocyclic carbene)-borylene complexes
Derivatives of free monocoordinated borylenes have attracted considerable interest due to their ability to exhibit transition-metal-like reactivity,...