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Deciphering the recent trends in pesticide bioremediation using genome editing and multi-omics approaches: a review
Pesticide pollution in recent times has emerged as a grave environmental problem contaminating both aquatic and terrestrial ecosystems owing to their...
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Effect of Multi-walled Carbon Nanotubes on the Toxicity of Triphenyltin to the Marine Copepod Tigriopus japonicus
Marine organisms are often exposed to a mixture of various pollutants in marine environment (i.e., nanoparticles, organic pollutants). The present...
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Worldwide Occurrence of Organotins from Antifouling Paints and Effects in the Aquatic Environment
Organotins belong to the most toxic pollutants for aquatic life known so far. Widespread contamination of harbors and areas with high ship**...
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Effects of exposure to triphenyltin (TPT) contaminant on sperm activity in adulthood of Calomys laucha exposed through breastfeeding
Triphenyltin (TPT) is an organotin compound (OT), primarily used in agriculture and in the composition of antifouling paints for ships worldwide....
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Synthesis, Crystal Structures, In Vitro Cytostatic Activity and DFT Studies of Four Organotin(IV) Complexes Derived From Schiff-Base Carboxylic Acid
Four triorganotin(IV) complexes, [(Ph 3 Sn) 2 L] ( 1 ), [(Et 3 Sn) 2 L] n ( 2 ), [(Me 3 Sn) 2 L] n ( 3 ), [(Me 3 Sn) 3 L( µ 2 -OH)] n ( 4 ) [H 2 L = 5-[(9-anthracenylmethylene)amin...
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A triorganotin(IV) cocrystal with pyridinic phosphoramide: crystal structure and DFT calculations
Herein, a two-component cocrystal [Ph 3 SnCl(4-PCAPh) 1 ] encompassing 4-PCAPh = N -isonicotinyl, N′,N″ -bis(hexamethylenyl) phosphoric triamide and...
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Accumulation and degradation of organotin compounds in cultivated sporophytes of the brown alga Undaria pinnatifida
Seaweeds could play a significant role in alleviating coastal chemical pollution through accumulation and degradation. In the present study, the...
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Palladium immobilized onto 1,4-bis(pyrid-4-yl)benzene grafted to n-propyl-functionalized Fe3O4@MCM-41 nanoparticles (PBPBPMF) as a novel, green, reusable, and versatile catalyst for preparing bis(pyrazolyl)methane and biphenyl derivatives
In this research, a novel and efficient nanocatalyst, namely, palladium immobilized onto 1,4-bis(pyrid-4-yl)benzene grafted to n -propyl-functionalized...
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Palladium anchored to BisPyP@bilayer-SiO2@NMP organic–inorganic hybrid as an efficient and recoverable novel nanocatalyst in suzuki and stille C–C coupling reactions
The palladium anchored to BisPyP@bilayer-SiO 2 @NMP organic–inorganic hybrid was employed as an effective and recyclable organometallic catalyst in...
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Resistance to fungicides in entomopathogenic fungi: Underlying mechanisms, consequences, and opportunities for progress
Although chemical agents are currently the standard in pest control, entomopathogenic fungi (EPF) are a commercially important biocontrol agent (BCA)...
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Insights into the Regulation on Proliferation and Differentiation of Stem Leydig Cells
Male hypogonadism is a clinical syndrome caused by testosterone deficiency. Hypogonadism can be caused by testicular disease (primary hypogonadism)...
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Exploring Imidazole Binding Flexibility in 2D and 3D Frameworks Using Hypercoordinated Triorganotin Carboxylates Featuring a Nitrogen-Rich Ligand with Benzoic Acid, Diazenyl, and Imidazole Functionalities: Insights into Sn − N, N → Sn, and N − H⋅⋅⋅X (X = N, O) Interactions†
The multitopic heterofunctional pro-ligand 4-[( E )-(1 H -imidazol-2-yl)diazenyl]benzoic acid (H′HL) was synthesized by diazotization of 4-aminobenzoic...
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New catalysts based on carboxylate Sn(IV) complexes used in the oxidation reaction of 3,5-di-tert-butylcatechol to 3,5-di-tert-butyl-o-benzoquinone
Seven carboxylate Sn(IV) complexes C 1 –C 7 were synthesized by condensation between piperic acid with tri -phenylstannanol C 1 , piperic acidwith di -butyls...
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Toxicity and Preliminary Risk Assessment of Alternative Antifouling Biocides to Aquatic Organisms
Published literature has been reviewed regarding the toxicity of representative alternative antifouling biocides (Chlorothalonil, Dichlofluanid,...
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S‐Benzylisothiourea Complex of Palladium Supported on Modified Mesoporous Magnetic Nanoparticles (Pd-SBTU@Fe3O4@SBA-3) as Sustainable Environmental Catalyst for Suzuki and Stille Reactions
AbstractA new and efficient magnetic mesoporous material has been designed and prepared via immobilization of S‐benzylisothiourea complex of...
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Microplastics – Pollutants’ Interactions, Mechanisms, and Potential Toxicity
Microplastics are small plastic fragments, flakes, or beads of size less than 5 mm diameter. Due to the anthropogenic activities, these persist...
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Chemistry and Fate of Organotin Antifouling Biocides in the Environment
Organotin antifouling paints are degraded relatively rapidly in seawater mainly by microorganisms, but they have high affinities to sediment and...
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Influence of Endocrine Disruptors on Male Reproductive Tract
A wide variety of chemical compounds with endocrine disruptor (EDC) activity have been recognized for environmental control agencies worldwide,...
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Samarium and ytterbium complexes based on sterically hindered 1,2-bis(imino)acenaphthene*
Reactions of the samarium complex [(Ar BIG -bian) 2− Sm 2+ ] ( 1 ) (Ar BIG -bian is the 1,2-bis-[(2,6-dibenzhydryl-4-methylphenyl)imino]acenaphthene dianion)...