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Monooxygenase-mediated cascade oxidation of fatty acids for the production of biopolymer building blocks
This paper reviews the recent advances in the production of industrially valuable biopolymer building blocks, such as ω-hydroxy fatty acids, ω-amino...
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Theoretical study on the reaction mechanism of Dakin oxidation: influence of methoxy groups
The reaction mechanism of the Dakin reaction for three lignin model compounds was thoroughly investigated using density functional theory (DFT). A...
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Study of the Mechanism of Coenzyme Specificity of Phenylacetone Monooxygenase from Thermobifida fusca by Site-Directed Mutagenesis
AbstractPhenylacetone monooxygenase from Thermobifida fusca (EC 1.14.13.92, PAMO) belongs to the Baeyer–Villiger family of monooxygenases and...
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Synthesis of δ-Valerolactone Using Stable Hydrogen Peroxide Derivatives
AbstractThe efficiencies of hydrogen peroxide derivatives in the Baeyer–Villiger oxidation of cyclopentanone to δ-valerolactone have been compared....
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CuO impregnated SBA-15; an efficient catalyst for B–V oxidation of cyclohexanone to caprolactone
The development of efficient, cost-effective, and environmentally friendly catalysts is pivotal in fine chemical synthesis. In this study, an...
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Effect of Sn and Zr Content in ZrAl- and SnAl-BEA Hierarchical Zeolites on Their Acidic and Catalytic Properties in the Process of Cyclohexanone Oxidation with Hydrogen Peroxide
Series of ZrAl- and SnAl-silicate hierarchical zeolites of the BEA structural type have been synthesized by hydrothermall method, and their acidic...
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Baeyer–Villiger Oxidation of Cyclohexanone by Hydrogen Peroxide with Fe3O4@GO as Catalyst Under Solvent Free Conditions
AbstractAn efficient magnetic nanocomposite catalyst (Fe 3 O 4 @GO) was synthesized and utilized as a sustainable and convenient catalyst for...
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Continuous synthesis of ε-caprolactone in a microreactor and kinetics insights into its side reactions
Nowadays ε -caprolactone, the monomer of biodegradable polycaprolactone, is mainly produced via the strong exothermic Baeyer–Villiger oxidation of...
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Oxidative metabolisms catalyzed Earth’s oxygenation
The burial of organic carbon, which prevents its remineralization via oxygen-consuming processes, is considered one of the causes of Earth’s...
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Study on Synthesis of Acid-Washed Illite Supported Fe3O4 Nanometer Catalyst and Baeyer–Villiger Oxidation Reaction of Cyclohexanone
Baeyer–Villiger oxidation allows for effective control of the stereochemical structure of the product, which is a significant feature for functional...
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Recent advances in metal-mediated oxidations with mCPBA
Among the various peroxides that are available, meta -chloroperbenzoic acid ( m CPBA) is an effective oxidizing reagent that is used in a variety of...
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Removal of benzophenone-4 via chlorination and advanced oxidation processes in aqueous solution: kinetics, by-product identification, and mechanistic studies
Benzophenone-4 (BP-4) is one of the UV filters widely used in personal care products (PCPs). BP-4 has been identified as an emergent contaminant...
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Efficient Baeyer–Villiger Oxidation Catalysed by Silver Nanoparticles Stabilized on Modified Montmorillonite
AbstractSilver nanoparticles supported on modified montmorillonite clay (Ag-NPs@mont), were utilized as catalyst for the Baeyer–Villiger oxidation of...
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Metal-Free Synthesis of Sulfones and Sulfoxides through Aldehyde-Promoted Aerobic Oxidation of Sulfides
Metal-free aerobic oxidation of aryl sulfides to sulfoxides and sulfones has been developed in the presence of aliphatic aldehydes with excellent...
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The main differences in reactivity of mono- and diunsaturated fatty acid esters during aerobic oxidation
During the aerobic oxidation of esters of both mono- and diunsaturated fatty acids and their mixtures, epoxide compounds are first forming, as well...
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Rapid Synthesis of Boron-MWW Zeolite Through a Solvent-free Strategy
ERB-1 zeolite emerges as a key bridging material for crafting heteroatom-containing MWW for versatile catalytic applications. In this study, we...
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Oxidation of cyclohexanone and/or cyclohexanol catalyzed by Dawson-type polyoxometalates using hydrogen peroxide
The oxidation of cyclohexanone, cyclohexanol or cyclohexanone/cyclohexanol mixture using as catalyst, Dawson-type polyoxometalates (POMs) of...