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Octahedral Zirconium Complexes as Polymerization Catalysts
The synthesis and X-ray structure of various octahedral zirconium complexes and their catalytic properties in the polymerization of α-olefins are... -
The Rise of Organophosphorus Derivatives in π-Conjugated Materials Chemistry
This chapter concerns the synthesis and properties of π-conjugated oligomers and polymers containing phosphorus moieties, an area of increasing... -
Carboselenothioic and Carbodiselenoic Acid Derivatives and Related Compounds
In this chapter we consider derivatives of carboselenothioic and carbodiselenoic acids, and compounds related to them. Ammonium salts and inner salts... -
Biologically Produced Sulfur
Sulfur compound oxidizing bacteria Sulfur compound oxidizing bacteria produce sulfur as an intermediate in the... -
Hydrozirconation and Its Applications
Next to hydroboration and hydrostannylation, hydrozirconation is among the few general methods available for the stoichiometric conversion of readily... -
Ligand Field Theoretical Considerations
The phenomenon of the thermal spin transition, as observed for octahedral transition metal complexes having a d... -
Special Classes of Iron(II) Azole Spin Crossover Compounds
In this chapter, selected results obtained so far on Fe(II) spin crossover compounds of 1,2,4-triazole, isoxazole and tetrazole derivatives are... -
Progress in the Asymmetric Synthesis of 1,2-Diamines from Azomethine Compounds
Recent advances in the preparation of optically pure 1,2-diamines by stereoselective addition reactions to azomethine compounds (imines, iminium... -
Intraband Spectroscopy and Semiconductor Nanocrystals
This chapter reviews intraband spectroscopy as it has been applied to semiconductor nanocrystals synthesized by colloid methods. -
Application of Evolutionary Algorithms to Global Cluster Geometry Optimization
This contribution focuses upon the application of evolutionary algorithms to the nondeterministic polynomial hard problem of global cluster geometry... -
DNA Electron Transfer Processes: Some Theoretical Notions
Charge motion within DNA stacks, probed by measurements of electric conductivity and by time-resolved and steady-state damage yield measurements, is... -
Valence Tautomeric Transition Metal Complexes
Valence d-orbital energies of the first row transition metals are close to the frontier π-orbital energies of o-benzoquinones. Complexes prepared... -
Structural Aspects of Spin Crossover. Example of the [FeIILn(NCS)2] Complexes
The interplay between the spin crossover and the structural properties of the complexes in the solid state is still under investigation. In... -
Cycloaddition Reactions of Group 6 Fischer Carbene Complexes
Group 6 heteroatom-stabilised carbene complexes (Fischer carbene complexes) offer many interesting possibilities to build rings (carbocycles and... -
Intra-Solid and Inter-Solid Reactions of Molecular Crystals: a Green Route to Crystal Engineering
The thesis developed in this chapter is that reactions taking place between molecular solids or within molecular solids, or involving a molecular... -
Two-Component Scenarios for Non-Conventional (Exotic) Superconductors
The possibility of superconductivity is analyzed within models where two components are present. Here both components may be non-superconducting on... -
Thio-, Seleno-, and Telluro-Carboxylic Acid Esters
This chapter reviews studies into the preparation of thio-, seleno-, and telluro-carboxylic acid esters (referred to thiol, selenol, and tellurol... -
Nanoscale Lattice Fluctuations in Cuprates and Manganites
Local lattice displacements giving a nanoscale inhomogeneous pattern due to mesoscopic phase separation in the correlated transition metal... -
Asymmetric Induction in Organic Photochemistry via the Solid-State Ionic Chiral Auxiliary Approach
After a brief introduction and summary of various methods of asymmetric induction in organic photochemistry, the main part of the review covers the... -
Essential Heterogeneities in Hole-Doped Cuprate Superconductors
An expanded review of recent pertinent experiments in hole-doped cuprates is presented [1]. These include photoemission, inelastic neutron...