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A Bis(terpyridine)nickel(II)-Based Coordination Nanosheet: A Redox-Active Material with Flexibility and Transparency
We report a novel functional bis(terpyridine)metal(II) complex coordination nanosheet (CONASH) comprising a three-armed terpyridine ligand and Ni 2+ ...
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Effect of density functional approximations on the calculated Jahn–Teller distortion in bis(terpyridine)manganese(III) and related compounds
ContextBis(terpyridine)manganese(III) exhibits Jahn–Teller distortion due to the inequivalent occupation of the degenerate e g orbitals of this...
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Zinc(terpyridine)-Incorporated Metal–Organic Frameworks Enabled Photocatalytic Oxidative Coupling of Amines Under Visible Light in Atmospheric Air
Poor light absorption ability severely limit the photocatalytic efficiency of metal–organic frameworks (MOFs) for chemical transformations. Herein,...
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Terpyridine-Containing 5-(2-Pyridylmethylene)-2-thioimidazolones and Their Coordination Compounds with Copper(II) Chloride: Synthesis and Cytotoxicity
AbstractMethods for the synthesis of new ditopic organic ligands containing coordinating fragments of two types, terpyridine and thiohydantoin, have...
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Heteroligand Zn(II) Metal-Organic Frameworks Based on 4-Substituted 4,2':6',4"-Terpyridine Derivatives and Terephthalates
AbstractMetal-organic frameworks based on Zn(II) and 4-substiuted 4,2':6',4"-terpyridine, terephthalate (Bdc), and 2-iodoterephthalate (2-I-Bdc)...
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Luminescent terpyridine-based metallo-supramolecular systems: from design to applications
Luminescent metallo-supramolecules have received tremendous attention in recent years owing to their diverse yet well-defined structures, tunable...
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Syntheses, Crystal Structures, and Magnetic Properties of Two Cobalt(II) Coordination Complexes with 4'-Substituted 3,2':6',3''-Terpyridine Ligands
AbstractTwo new cobalt(II) coordination complexes [Co(Phtpy)(HBTC) 0.5 ] n · n H 2 O ( I ) and [Co(Meophtpy)(HBTC) 0.5 ] n · n H 2 O ( II ) (Phtpy =...
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Novel Terpyridine Derivatives of Benzothiazole and Copper(II) Complex: Synthesis and Spectral Studies
AbstractNovel terpyridine derivatives of benzothiazole were synthesised by simple multicomponent one-pot reaction of benzothiazole-2-carbaldehyde,...
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Novel Terpyridine Conjugated Nitrogen Mustard Derivatives: Synthesis, Spectral Properties, and Anticancer Activity
AbstractA series of 2,2′:6′,2′-terpyridine conjugated nitrogen mustard derivatives with structurally symmetrical character and rather small molecular...
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Synthesis, Spectral, and Single Crystal XRD Studies of Novel Terpyridine Derivatives of Benzofuran-2-carbaldehyde and their Cu(II) Complex
AbstractA series of novel terpyridine derivatives of benzofuran (NP1–NP3) were synthesised by simple multicomponent one pot reaction among...
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A Tris(terpyridine) Ligand-based Metal Coordination Nanosheet as Electrode Material with Good Supercapacitor Performance
In this work, through a facile liquid–liquid (L–L) interfacial-assisted synthesis at room temperature, a new two-dimensional (2D) metal coordination...
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New terpyridine W(VI) complex on magnetite as a recoverable catalyst in epoxidation of olefins
In this research, MnFe 2 O 4 nanoparticles were modified with a terpyridine based complex of oxo-diperoxo W(VI). The novel MFO@Phttpy-WO(O 2 ) 2 was...
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Synthesis and Stimuli-Responsive Properties of Metallo-Supramolecular Phosphazene Polymers Based on Terpyridine Metal Complexes
In this study, terpyridine functionalized phosphazene based metallo-supramolecular polymers were synthesized by three step reaction method. In the...
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Designing narcissistic self-sorting terpyridine moieties with high coordination selectivity for complex metallo-supramolecules
Coordination-driven self-assembly is a powerful approach for the construction of metallosupramolecules, but designing coordination moieties that can...
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Analytical Ultracentrifugation Studies on Terpyridine-end-functionalized Poly(ethylene oxide) and Polystyrene Systems Complexed via Ru(II) ions
In this paper we study the solution properties of several metallo-supramolecular assemblies containing polystyrene (PS) and poly(ethylene oxide)...
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Low-cost photo-switches based on stilbene-appended Zn(II)–terpyridine complexes
AbstractWe report herein the synthesis, characterization, photophysics, and photo-isomerization behaviors of three Zn(II)–terpyridine complexes of...
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Supramolecular Complexes Built of Octahedral [Ta6Cl12(CN)6]3−/4− Clusters and Terpyridine-Metal Complexes
The preparation and characterization of two supramolecular complexes from octahedral [Ta 6 Cl 12 (CN) 6 ] 4−/3− units and 2, 2′: 6′, 2″-terpyridine ( Terpy )...
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Kinetics of Base Hydrolysis of Bis(2,2' : 6',2''-Terpyridine)Iron(II) Complex in the Water Pools of CTAB Reverse Micelles
AbstractThe kinetics of base hydrolysis of bis(2,2′ : 6′,2′′- terpyridine)iron(II) has been carried out in water pools of CTAB/chloroform/hexane...
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Supramolecular Arrangement Built from Zinc and Cadmium Complexes with 4′-(4-Substituted)-2,2′:6′,2″-Terpyridine: Crystallographic Investigation, Luminescence and Thermal Properties
The reaction of Zn(NO 3 ) 2 ⋅6H 2 O with tpyOH or ftpy in the presence of KSCN affords the new zinc(II) complexes [Zn(tpyOH)(NCS) 2 ] ( 1 ) and [Zn(ftpy)(NCS) 2 ]...
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RE-Halobenzoic Acid-Terpyridine Complexes, Part V: Synthesis and Supramolecular Assembly of Rare-Earth-3,5-Dihalobenzoic Acid-Terpyridine Materials and Subsequent Comparison of Non-covalent Interactions
The synthesis and crystal structures of 48 new rare-earth (RE = La 3+ —Y 3+ )-3,5-dihalogenated benzoic acid (3,5-dibromobenzoic acid [3,5-dBrBA] and...
