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Reactivity of Phosphorus Centered Radicals
The recent literature devoted to the chemical reactivity of the main families of phosphorus centered radicals is surveyed. Various tin-free radical...
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Electron–Nuclear Alignment in Radicals Formed by Photochemical Decomposition of Molecules
AbstractCalculations of electron–nuclear alignment (CIDEP multiplet effect) in radicals formed as a result of the photochemical decomposition of...
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An N-Acetyl-L-Cysteine Impedance Sensor for Assessing Antioxidant Activity against Hydroxyl Radicals
AbstractThe hydroxyl radical is the most aggressive and dangerous product of incomplete oxygen reduction in a body, making its determination and the...
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In-situ UV-Vis Spectroscopy of Trisulfur Radicals in Lithium-Sulfur Batteries
Here we employ in-situ UV-Vis spectroscopy to monitor the sulfur redox reaction with oxygen-containing molecules as an additive, for example,...
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Phosphorus-Centered Radicals: Synthesis, Properties, and Applications. A Review
AbstractPhosphorus-containing compounds have a huge synthetic potential because of their wide application in pharmaceuticals, biology, agrochemistry,...
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Reactions of Benzyl- and Hydroxyethyl Radicals with Nitric Oxide
AbstractBenzyl and hydroxyethyl radicals play an important role in the combustion and oxidation of toluene and ethanol. As a result of their...
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Reaction Kinetics and Secondary Organic Aerosol Composition Analysis of 2-Cyclohexen-1-one with NO3 Radicals
Unsaturated ketones are typical oxygenated volatile organic compounds (OVOCs) with high reactivity, and are important precursors in air pollution....
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Investigation of resonance-stabilized radicals associated with soot particle inception using advanced electron paramagnetic resonance techniques
In order to tackle the climate emergency, it is imperative to advance cleaner technologies to reduce pollutant emission as soot particles. However,...
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NHC-derived carbon-centered luminescent radicals with short-wavelength emission via suppression of Kasha’s rule
Luminescent organic radicals have garnered increasing attention owing to their versatile applications in sensing, imaging, and organic light-emitting...
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Breaking free from free radicals: harnessing the power of natural antioxidants for health and disease prevention
Massive production of the free radicals disrupts the system of antioxidant defense in the animal body thereby causing damage to cellular molecules...
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Photophysical oxidation of HCHO produces HO2 radicals
Formaldehyde, HCHO, is the highest-volume carbonyl in the atmosphere. It absorbs sunlight at wavelengths shorter than 330 nm and photolyses to form H...
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Regulation of radicals by hydrogen-donor solvent in direct coal liquefaction
Radicals are important intermediates in direct coal liquefaction. Certain radicals can cause the cleavage of chemical bonds. At high temperatures,...
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Utilizing a Sensitive Micro-balance (QCM) for Assessing the Antioxidant Response of Date Kernel Activated Carbon Nanomaterials Against Free Radicals
In this research, a relatively simple and inexpensive, real-time and high-resolution mass sensing technique is proposed for the first time in order...
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Hydropersulfides inhibit lipid peroxidation and ferroptosis by scavenging radicals
Ferroptosis is a type of cell death caused by radical-driven lipid peroxidation, leading to membrane damage and rupture. Here we show that...
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Kinetic analysis of the reactivity of peroxyl radicals in chain oxidation of unsaturated compounds
The array of rate constants (323 K) for the addition of peroxyl radicals of different structures to the π-bonds of unsaturated compounds was...
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Mechanism of methylene blue degradation by three-dimensional particle electrodes: contribution of surface-bound radicals and direct electron transfer
In this study, Ti-Sn-Sb/γ-Al 2 O 3 particle electrodes were prepared by sol–gel method and a three-dimensional electrocatalytic system was constructed...
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General relationships between the kinetic characteristics of bulk and geminate recombination of radicals in solutions
Based on the (differential) Encounter theory developed in the literature, which describes the change in the internal quantum states of particles...
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Effects of Azomethine Derivatives of 4,6-Di-tert-Butyl-2,3-Dihydroxybezaldehyde on Radiation-Induced Reactions Involving Alkyl and Alpha-Hydroxyalkyl Radicals
AbstractThe effects of azomethine derivatives of 4,6-di- tert -butyl-2,3-dihydroxybenzaldehyde on the formation of radiolysis products of deaerated n -h...
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Study of the Potential Energy Surface of Reactions in a System Containing I-Propyl and N-Propyl Radicals
AbstractThe energy pathways of possible decomposition and isomerization reactions of iso -propyl ( i -C 3 H 7 ) and n -propyl ( n -C 3 H 7 ) radicals are studied...
