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Nitration of Phenol with Water Activated by Pulsed Hot Plasma Radiation
AbstractThe nitration of phenol with plasma-activated water (PAW) generated by pulsed radiation of an electric spark discharge has been studied....
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Effect of Nickel Promoted Niobium Catalyst on Toluene Nitration Reaction
AbstractA series of Ni–Nb 2 O 5 /SiO 2 catalysts with varying Ni loadings (5–25 wt %) were prepared. The catalytic activity of the materials was...
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Highly surface-selective nitration of cellulose nanofibers under mildly acidic reaction conditions
Cellulose nitrate (CN) is used in numerous industrial materials, such as propellants, lacquers, and plastics, exploiting its highly flammable,...
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Accurate determination of the kinetics of toluene nitration in a liquid–liquid microflow system
The nitration of toluene with mixed acid is one of the most representative nitration reactions. Accurate kinetic study is essential for controlling...
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Nitration process of 2-(2,4-dichlorophenyl)-4-(difluoromethyl)-5-methyl-1,2,4-triazol-3-one in a microreactor
In a continuous flow microreactor system, a continuous nitration process of...
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Computational Fluid Dynamics for Microreactors Used in Nitration of Phenol
AbstractThe use of CFD for the development of hydrodynamic and kinetic models for the nitration of phenol in a microchannel is a necessary step for...
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3-Guanidino-6-R-1,2,4,5-tetrazines: azine ring transformation, nitration, and salt formation
The reaction of 3-azolyl-6-R-1,2,4,5-tetrazines with guanidine afforded a series of new 3-guanidino-6-R-1,2,4,5-tetrazines. When treated with...
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Assessment of Stability of Thermal Conditions of 2-Ethylhexanol Nitration
The stability of steady thermal conditions of 2-ethylhexanol nitration in a laboratory unit with a centrifugal mass-transfer device was analyzed. It...
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Nitration of chlorobenzene by ultrasonic-assisted synthesized sulfated ZrO2 catalyst with NO2
Different solid superacid sulfated zirconium dioxide (SO 4 2− /ZrO 2 ) samples were successfully prepared by conventional and ultrasonic-assisted chemical...
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The nitration and bromination of 2-(pentafluorosulfanyl)-1,3-benzothiazole and 2-(trifluoromethyl)-1,3-benzothiazole
The nitration and halogenation reactions of 2-(pentafluorosulfanyl)- and 2-(trifluoromethyl)-1,3-benzothiazoles were studied. Methods for the...
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Complete and selective nitration of tyrosine residue in peptides caused by ultraviolet matrix-assisted laser desorption/ionization
Complete and highly selective nitration of tyrosine (Tyr) as a residue-specific modification in peptides was found without side reactions, using...
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Kinetics and safeties of 2-Ethyl-1-hexanol nitration in a capillary-microreactor
The nitration reaction and purification process of 2-Ethyl-1-hexanol is highly hazardous and characterized by severe thermal instability. Therefore,...
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Nitration of Tyrosine by the Action of Pulsed Radiation of Spark-Discharge Hot Plasma
AbstractThe reaction mechanism of products formed in an aqueous solution by the action of pulsed radiation from hot electric discharge plasma has...
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Nitration of Petroleum Asphaltenes with Concentrated Nitric Acid under Various Conditions
The relationships of the reaction of the of tar asphaltenes with concentrated nitric acid were studied under various quantitative, temperature, and...
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Theoretical investigation of the mechanism and regioselectivity of the 3-isopropyl-1,6-dimethyl-naphthalene and ar-himachalene in nitration reaction: a MEDT study
In this work, we investigated the mechanism and the regioselectivity of the nitration reaction of 3-isopropyl-1,6-dimethyl-naphthalene,...
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Novel S2O82−/Fe-ZrO2 solid superacid catalyst combined with O2-Ac2O for highly efficient catalytic nitration of 1-nitronaphthalene with NO2 to 1,5-dinitronaphthalene
A mild, efficient, and green approach for highly selective synthesis of 1,5-dinitronaphthalene (1,5-DNN) has been devolved from catalytic nitration...
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Heterogeneous nitration reaction of BSA protein with urban air: improvements in experimental methodology
Gas-phase ozone (O 3 ) and nitrogen dioxide (NO 2 ) can react with environmentally exposed proteins to induce chemical modifications such as the...
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Design and scale-up of continuous di-nitration reaction using pinched tube flow reactor
Scale-up of the di-nitration reaction for synthesis of selective herbicide pendimethalin using only nitric acid in continuous flow is presented in...
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Nitration of N-(fluorodinitroethyl)pyrazoles
Conditions for the introduction of the nitro group at the position 4 of N -(fluorodinitroethyl)pyrazoles bearing an electron-withdrawing substituent...
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Nitration of Alkenes and Oxiranes with Nitrogen(IV) Oxide in Liquid and Supercritical Carbon Dioxide Media
AbstractFor the first time the reactions of radical nitration of alkenes and oxiranes with nitrogen dioxide in the liquid and supercritical carbon...