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Luminescence Properties of the Iridium(III) Complexes
AbstractThis review summarizes the results of the synthesis, photoluminescence, and electroluminescence of the main classes of cyclometallated...
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Nonequilibrium Nuclear Spin States of Ethylene during Acetylene Hydrogenation with Parahydrogen over Immobilized Iridium Complexes
AbstractImmobilized rhodium and iridium complexes have been prepared and characterized by X-ray photoelectron spectroscopy. For the first time,...
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Electron beam-induced white emission from iridium complexes-doped polymer dots
Radiation detection plays an important role in diverse applications, including medical imaging, security, and display technologies. Scintillators,...
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Selective N-alkylation catalyzed by polymer gels with crosslinked domains containing iridium complexes
Polymer gel catalysts are attractive due not only to their recyclability but also to the unique reaction environment in the internal space of the...
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Cationic Iridium(III) Complexes Bearing Different Bulky N,N′-Chelating Ligands
Six cationic iridium(III) complexes bearing different bulky N,N′-chelating ligands were successfully synthesized and characterized by spectroscopic,...
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Synthesis, Structures, Optical, and Electrochemical Properties of Bis-Cyclometallated Iridium(III) Complexes with N-Benzylbenzimidazoles
AbstractA series of bis-cyclometallated iridium(III) complexes with various 2-aryl-1-benzylbenzimidazoles (aryl is 4-chlorophenyl, 4- tert -butylphenyl...
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Electroluminescent Polymers with Cationic Iridium-Containing Fragments
AbstractTwo new cyclometalated cationic iridium(III) complexes containing norbornene-substituted pyridylbenzimidazole ancillary ligands were...
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The Effect of the Ancillary Ligand on Optical and Redox Properties of Cyclometalated Iridium(III) 2,5-Diphenyloxazole Complexes
AbstractTwo series of bis-2,5-diphenyloxazolato cyclometalated iridium(III) complexes with substituted 2,2′-bipyridine or dipyridophenazine as the...
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Synthesis of thermoresponsive polymer gels with crosslinked domains containing iridium complexes for ammonia sensing and N-alkylation catalysis
Incorporating organometallic complexes into nanodomains in polymer networks would broaden the scopes of gel material design and applicability. In...
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Inhibition of cell proliferation of iridium(III) polypyridyl complexes on osteosarcoma U2OS cells through PI3K/AKT/mTOR pathway
In this article, three iridium(III) complexes [Ir(bzq) 2 (NPIP)](PF 6 ) (NPIP = 2-nitrophenyl-1 H -imidazo[4,5-f][1,10]phenanthroline) ( Ir1), [Ir(bzq) 2 (MNPIP)](PF...
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Generation and Spectral Properties of Oxidized Forms of Iridium and Rhenium Porphyrin Complexes
AbstractWe make a brief overview of the results of studies into the reactivity of iridium and rhenium complexes in various oxidation states with...
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Post-complexation Functionalization of Cyclometalated Iridium(III) Complexes and Applications to Biomedical and Material Sciences
Cyclometalated iridium(III) (Ir(III)) complexes exhibit excellent photophysical properties that include large Stokes shift, high emission quantum... -
Post-complexation Functionalization of Cyclometalated Iridium(III) Complexes and Applications to Biomedical and Material Sciences
Cyclometalated iridium(III) (Ir(III)) complexes exhibit excellent photophysical properties that include large Stokes shift, high emission quantum...
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Red-emitting heteroleptic iridium(III) complexes: photophysical and cell labeling study
Two red-emitting heteroleptic iridium(III) complexes (Ir-p and Ir-q) were synthesized and their photophysical and biological properties were...
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Circularly polarized phosphorescence and photon transport of micro/nanocrystals of ruthenium and iridium complexes with chiral anions
Materials with efficient circularly polarized phosphorescences (CPPs) are of potential use in advanced data encryption and anti-counterfeiting,...
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COMPARATIVE XPS STUDY OF THE COMPOSITION AND ELECTRONIC STATE OF IRIDIUM IN BULK AND IMMOBILIZED BINUCLEAR [Ir(COD)Cl]2 COMPLEXES
AbstractChanges in the composition and electronic state of iridium in the [Ir(COD)Cl] 2 complex, which are induced by X-ray radiation and oxidation...
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Synthesis and luminescence monitoring of iridium(III) complex-functionalized gold nanoparticles and their application for determination of gold(III) ions
A new method is presented for the one-step synthesis and real-time monitoring of iridium(III) complex-functionalized AuNPs from the precursor...
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Supramolecular Phosphorescent Polymer Based on Cationic Iridium Complexes for Polymer Light-Emitting Diodes
Three novel orange emission supramolecular phosphorescent polymers (SPPs) with cationic iridium complex have been developed for polymer...
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Chiral Diaminocarbene Complexes, Synthesis and Application in Asymmetric Catalysis
The synthetic routes to optically pure N-heterocyclic carbene (NHC) complexes and their application in asymmetric catalysis is reviewed. Chiral... -
Thermodynamic Study of Iridium(I) Complexes as a Basis for Chemical Gas-Phase Deposition Technology
AbstractExperimental data on the saturated vapor pressure and melting of dicarbonyl(hexafluoroacetylacetonato)iridium [Ir(CO) 2 (hfac)] were obtained....