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First Pentanuclear Molybdenum Iodide Cluster (Bu4N)[Mo5OI13]: Synthesis and Structure
AbstractThe first iodide cluster of molybdenum with the metal cage in the form of a tetragonal pyramid (Bu 4 N)[Mo 5 OI 13 ]·THF ( I ) and cocrystallizate...
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Construction of two new photoluminescent 3D heterometallic complexes and their nursing application values on ICU infection
Two new heterometallic structures of [Zn 2 Ba(TCA) 2 (H 2 O) 2 ]·2n(H 2 O) ( 1 ) and [Cd 2 Ba(TCA) 2 (DMA) 2 (H 2 O) 3 ]·2n(DMA) ( 2 ) were successfully prepared via the...
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Iron-only Fe-nitrogenase underscores common catalytic principles in biological nitrogen fixation
Nitrogenases uniquely reduce atmospheric N 2 to bioavailable ammonium. They group into three isoforms that primarily differ in the architecture of...
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Synthesis of nickel-doped titanium-oxo clusters with enhanced visible-light photocatalytic activity
Two new Ni-doped titanium-oxo clusters of the formula [Ni 2 Ti 4 ( μ 3 -O) 2 ( μ 2 -O) 2 (BA) 12 (CH 3 CN)(H 2 O)]∙CH 3 CN ( Ti 4 Ni 2 BA 12 ; BA = benzoate) and [Ni 2 Ti 4 ( μ 3 -O) 2 ( μ 2 -O)...
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Photoluminescence of the Au38(SR)26 nanocluster comprises three radiative processes
Photoluminescence of ultrasmall, atomically precise gold nanoclusters constitutes an area of significant interest in recent years for both...
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Electrochemical synthesis of ZnO-WO3 nanocomposites and their photocatalytic activity
AbstractHeterometal oxide nanoparticles of ZnO-WO 3 (ZWO) were synthesized using a facile dual step hybrid electrochemical–thermal technique. The...
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Polyoxometalate-based boron dipyrromethene (BODIPY) conjugates: syntheses, characterization and photophysical properties
AbstractBis-azido containing Anderson-type inorganic POM was functionalized with organic mono- and di-styryl BODIPY dyes for the first time, and two...
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Germanium-enriched double-four-membered-ring units inducing zeolite-confined subnanometric Pt clusters for efficient propane dehydrogenation
It is a great challenge to regulate the precise placement of confined metal species and assemble specific structures at the atomic level. Here we...
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Syntheses and properties of Cu(II), Al(III), and Ti(IV) coordination polymers using an acetylacetonato-terminated polyhedral oligomeric silsesquioxane
Synthesis of coordination polymers based on polyhedral oligomeric silsesquioxane (POSS) has attracted attention as an important research direction...
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Main Approaches to the Synthesis of Heterometallic Metal-Organic Frameworks
AbstractThe chemistry of metal-organic frameworks (MOF) is intensively developed during the recent years. Such compounds form unique porous...
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Solvent-Dependent Assembly of Two New 3d–4f Heterometal-Organic Frameworks Based on a Bifunctional Ligand
In this study, we show the solvent-induced formation of two new analogic six-connected 3 d –4 f heterometal-organic frameworks, formulated as [Dy 4 Cu
... 
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Crystal Structure of Layered Cyano-Bridged Coordination Polymers [M(NH3)6]4[{M(NH3)2} {Re3Mo3Se8(CN)6}2]·15H2O (M = Co, Ni)
Two isostructural compounds of the composition [M(NH 3 ) 6 ] 4 [{M(NH 3 ) 2 }{Re 3 Mo 3 Se 8 (CN) 6 } 2 ]·15H 2 O (M = Co, Ni) are obtained by a reaction of a salt of...
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Emerging Atomically Precise Metal Nanoclusters and Ultrasmall Nanoparticles for Efficient Electrochemical Energy Catalysis: Synthesis Strategies and Surface/Interface Engineering
Atomically precise metal nanocluster and ultrasmall nanoparticle catalysts have garnered significant interest in electrocatalysis applications due to...
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Mechanism of Chromium Electrodeposition as a Particular Case of Mechanism of Induced Codeposition of Metals
AbstractThe chromium reduction from standard worked-out chromium-plating electrolyte containing compounds of trivalent and hexavalent chromium and...
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Future Directions
As metal clusters provide complementary active sites for surface catalysis and reactions, there is future promising potential to create unique...
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Atomic control of active-site ensembles in ordered alloys to enhance hydrogenation selectivity
Intermetallic compounds offer unique opportunities for atom-by-atom manipulation of catalytic ensembles through precise stoichiometric control. The...
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Novel Tocopherol Succinate-Polyoxomolybdate Bioconjugate as Potential Anti-Cancer Agent
Despite the promising anti-cancer properties of the polyoxometalates (POMs) compound, they have not yet been reported for clinical use due to their...
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Single-Chain Magnets:Theoretical Approach and Experimental Systems
Recently, a new class of nano-magnets has been discovered and called single-chain magnets (SCMs) by analogy to the single-molecule magnets (SMMs)....
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Introduction
In this chapter, the structural and catalytic properties of metal oxide clusters [MxOy]n− (M: metal), called polyoxometalates (POMs), are summarized....
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Photochemistry of Metal-Organic Frameworks
Metal-organic Frameworks (MOFs) are hybrid materials constructed from inorganic and organic components, which can be combined in a rational, modular...