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Chemical Reactivity and Addition Pattern on C60 and C70
Fullerenes are a class of three-dimensional all-carbon hollow molecules incorporating conjugated π systems. The important principle to determine the... -
Chemical Reactivity and Addition Pattern on C60 and C70
Fullerenes are a class of three-dimensional all-carbon hollow molecules incorporating conjugated π systems. The important principle to determine the... -
Complexation with Transition Metals
The electron-deficiency fullerenes that resemble olefins are facile to react with nucleophilic transition metals to form related complexes with novel... -
Complexation with Transition Metals
The electron-deficiency fullerenes that resemble olefins are facile to react with nucleophilic transition metals to form related complexes with novel... -
Quantum Chemical Study of X@BikPbm, BikPbm∙X, X@SbkSnm, and SbkSnm∙X Clusters
AbstractClusters ( I h )-(Cd, Hg, Yb)@(Pb 12 , Sn 12 ), ( C 5 v )-(Ag, Au)@BiPb 11 , ( C 5 v )-Ag@SbSn 11 , ( D 5 d )(Ni, Pd, Pt)@Bi 2 Pb 10 , ( D 5 d )-Pd@Sb 2 Sn 10 , ( C 3 v )-(Pb 12 , Sn...
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Recent Advances of Functionalized Carbon Nanotubes for Biomedical and Device Applications (A Review)
AbstractRecently, the field of nanotechnology has remarkably progressed. Nanomaterials, the backbone of nanotechnology, are at the forefront of...
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[60]Fullerene-Based Pd(0) Complexes of Phosphorus Ylides as Efficient Nanocatalyst for Homo- and Heterogeneous Mizoroki–Heck Coupling Reactions
AbstractThis work reports the synthesis and catalytic properties of new mono- and bidentate palladium(0)-[60]fullerene complexes, prepared by...
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Molecular Engineering of Metal-Organic Cycles/Cages for Drug Delivery
The assembly of nanoscale materials with well-defined size and shape is an intriguing approach to aid in drug design and delivery. Of the various...
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Self-assembled nanospheres with multiple endohedral binding sites pre-organize catalysts and substrates for highly efficient reactions
Tuning reagent and catalyst concentrations is crucial in the development of efficient catalytic transformations. In enzyme-catalysed reactions the...
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Buckyballs
Buckyballs represent a new and fascinating molecular allotropic form of carbon that has received a lot of attention by the chemical community during... -
Electrochemical properties of transition metal complexes with C60 and C70 fullerne ligands (review)
t-The electrochemical properties of exohedral complexes of transition metals with metallofragments coordinated to C 60 and C 70 fullerene ligands in...
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Preparation and Characterization of Polyhedral Oligosilsesquioxanes
Polyhedral OligoSilSesquioxanes are often abbreviated by the acronym POS or POSS® and are compounds of the general formula Sin O3n/2Rn (often denoted... -
Comparison of electrochemical behavior of exohedral palladium complexes with [60]- and [70]-fullerenes and metallocene ligands
Electronic structures of exohedral palladium complexes of [60]- and [70]-fullerenes with diphenylphosphinoferrocenyl, diphenylphosphinoruthenocenyl,...
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Advances in fullerene chemistry
The review outlines the key results obtained in experimental and theoretical studies on fullerene chemistry in the Russian Federation and, in...
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Metallation of fullerenes: electrochemical synthesis and voltammetric study of heterometallic C60 and C70 complexes
Electrochemical synthesis and voltammetric study of new heterotrimetallic exohedral derivatives of [60]- and [70]fullerenes containing palladium and...
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Cycloaddition to buckminsterfullerene C60: advancements and future prospects
Investigations on mono-[2+1]-, -[2+2]-, -[2+3]-, -[2+4]-, and polycycloaddition to [60]fullerene are reviewed. The main reagents used in...
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Fullerene compounds with transition metals MnC60: Preparation, structure, and properties
This review summarizes the results of studies on complexation of fullerene C 60 with transition metals. The structural background for metal-fullerene...
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Electrochemical and Structural Aspects of Metallofullerenes
The presence of a metal inside or a metal fragment outside the cage of fullerenes should increase the attention towards these spectacular molecules...