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SYNTHESES, STRUCTURAL INSIGHT AND HIRSHFELD SURFACE ANALYSIS OF TWO HETEROLEPTIC COORDINATION POLYMER OF Cu(II)
AbstractUsing a solvothermal method, we have synthesized two coordination polymers of Cu(II). One is a 1D polymer {[Cu(bpy)(NDC)(H 2 O)]·2H 2 O} n ( 1 ,...
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Perrhenate anion encapsulation in a uranyl ion–zwitterionic dicarboxylate coordination polymer
The zwitterionic dicarboxylate 1,1′-[(2,3,5,6-tetramethylbenzene-1,4-diyl)bis(methylene)]bis(pyridin-1-ium-4-carboxylate) (L) has been reacted with...
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Cadmium(II)-Organic Coordination Polymer Containing Carboxyl Groups: Solvothermal Synthesis, Structure, and Properties
AbstractNew metal-organic coordination polymer Cd[H 2 L] ( I ) (where H 4 L is 4,4'-([2,2'-bipyridine]-6,6'-diylbis(oxy))diphthalic acid) is synthesized...
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Coordination Polymer or Cluster: Zinc Bis(3,5-di-tert-octyl-semiquinolate) with Pyrazine
AbstractNew zinc bis- o- semiquinolate complexes based on 3,5-di- tert -octyl- o -benzoquinone bearing the N-donor ligand (pyrazine) coordinated to the...
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Selective Detection of Phosphate Ion in Aqueous Medium by a Cobalt(II) Based Coordination Polymer
In the present study, we have designed a new water soluble cobalt(II) based one-dimensional (1D) coordination polymer ( CP1 ) for the detection of...
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One-dimensional europium coordination polymer with redox-active ligands
The one-dimensional (1D) coordination polymer [(dpp-bian) − Eu 2+ (4,4-bipy) − -(THF) 2 ·4THF] n (1) (dpp-bian is...
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Stabilize and Reinforce Hydrogen-Bonded Polymer Complex Elastic Fiber by Catechol Chemistry and Coordination
Hydrogen-bonded polymer complex fiber of poly(ethylene oxide) (PEO) and poly(acrylic acid) (PAA) shows rubber elasticity in ambient environment, but...
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Synthesis and structure of two-dimensional coordination polymer based on 2,2′-bithiophene-5,5′-dicarboxylic acid
A new metal-organic framework (MOF) [Co 3 (btdc) 3 (5,5′-dmbpy) 2 ] • 5DMF ( 1 ) (H 2 btdc is 2,2′-bithiophene-5,5′-dicarboxylic acid and 5,5′-dmbpy is...
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Honeycomb 3D Coordination Barium Polymer with 2-Furancarboxylic Acid Anions: Effect of Thermal Stability
AbstractA coordination polymer with the [Ba 5 (fur) 10 (H 2 O) 4 ] n composition ( 1 ) is prepared by the reaction of barium(II) acetate and 2-furancarboxylic...
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SYNTHESIS, CRYSTAL STRUCTURE, AND LUMINESCENCE OF THE ONE-DIMENSIONAL LANTHANUM(III) COORDINATION POLYMER WITH 2,6-BIS (3,5-DICARBOXYPHENOXY)PYRIDINE
AbstractBy the interaction of 2,6-bis(3,5-dicarboxyphenoxy)pyridine (H 4 L) with lanthanum(III) nitrate in a 1:1 acetonitrile–water mixture a...
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A new coordination polymer of Cd(II) with 4-methyl-1,2,4-triazole-3-thiol ligand: synthesis, characterization, crystal structure, photoluminescence and DFT calculation
A new Cadmiun(II) coordination polymer, {[Cd(µ-mptrz) 2 ].0.5((CH 3 ) 2 SO)} n was prepared from the reaction of CdBr 2 with 4-methyl-4 H -1,2,4-triazole-3-thio...
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Asymmetric reversible structural switching of a diene coordination polymer promoted by UV-visible light
In natural and artificial systems, reversible reactions are commonly asymmetric with respect to the time scale and nature of the stimuli which drive...
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Synthesis, Structure, and Biological Properties of a 1D Silver(I) Coordination Polymer Based on 10-(4-Etoxyphenyl)phenoxarsine
Abstract1D coordination silver(I) polymer [L 2 AgONO 2 ] n has been obtained via the reaction of 10-(4-ethoxyphenyl)phenoxarsine with silver(I) nitrate...
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A coordination polymer of Na-Fe(III) with EDTA: synthesis, characterization, electrical conductivity, adsorption properties and Hirshfeld surface analysis
In this work, we report Na-Fe(III) coordination polymer, Na[Fe(C 10 H 12 N 2 O 8 )(H 2 O)]·2H 2 O ( 1 ), derived from Ethylenediaminetetraacetic acid (EDTA) and...
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One-Dimensional Copper(II) Coordination Polymer Based on 1,2-bis-(4-Pyridyl) Ethane and 1,10-Phenathroline
AbstractThe one dimensional copper(II) coordination polymer {[Cu(phen)(bpe)(NO 3 )(H 2 O)](NO 3 )(H 2 O)} n ( 1 ) has been synthesized using [Cu(phen) 2 (NO 3 ) 2 ]...
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A PYRIMIDINE-DERIVED DIPHOSPHINE P-MONOXIDE AND A Ag(I) COORDINATION POLYMER THEREOF: SYNTHESIS, STRUCTURE, AND LUMINESCENCE
Abstract(4-(Diphenylphosphino)pyrimidin-2-yl)diphenylphosphine oxide is unexpectedly formed in 24% yield in the reaction of 2,4-dichloropyrimidine...
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Synthesis, Structural Characterization and Fluorescent Property of Cd(II) Coordination Polymer Containing Pyridinium Zwitterionic Ligand
A novel Cd(II) Coordination Polymer, [Cd(L) 2 (SO 4 ) 2 (H 2 O) 2 ][Cd(H 2 O) 6 ]·4H 2 O (CP 1 )...
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Two-dimensional ZnII coordination polymer based on 5-iodoisophthalate: synthesis, crystal and electronic structure
The reaction of zinc(II) nitrate with 5-iodoisophthalic acid (5-I-IPAH) in N,N -dimethylformamide afforded the layered coordination polymer...
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A Zn(II)-based 1D Coordination Polymer with Adsorption Properties and Hirshfeld Surface Analysis
A polymeric coordination compound [Zn 2( PABA) 2 (H 2 O) 2 Cl 2 ] n ( 1 ) (where PABA is para-aminobenzoic acid) has been synthesized and characterized. We...
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Photocatalytic nitrogen fixation under an ambient atmosphere using a porous coordination polymer with bridging dinitrogen anions
The design of highly electron-active and stable heterogeneous catalysts for the ambient nitrogen reduction reaction is challenging due to the...
