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Radical Polymerization
This chapter introduces the fundamental concepts of radical polymerization. Typical monomers, initiators, and transfer and termination reagents are...
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Controlled Radical Polymerization of Lauryl Methacrylate in the Synthetic Polyalphaolefin Base Oil
AbstractControlled radical polymerization of lauryl methacrylate in polyalphaolefin base oil has been performed for the first time in the presence of...
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From controlled radical polymerization of vinyl ether to polymerization-induced self-assembly
Vinyl ether (VE) was long believed to be among the monomers that could not be radically homopolymerized. Therefore, to synthesize block copolymers...
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A visible-light photoinduced controlled radical polymerization using recyclable MIL-100 (Fe) metal–organic frameworks
Controlled polymer techniques have significantly advanced thanks to using the energy of light to control radical polymerizations. Although many...
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Salts of Organic Acids as Reducing Agents in Atom Transfer Controlled Radical Polymerization
AbstractNovel catalytic systems based on complexes of copper(II) bromide with polydentate nitrogen-containing ligands, tris[(2-pyridyl)methyl]amine...
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Methods of controlled radical polymerization in the synthesis of functional polymers and macromolecular structures
In a brief review, the main trends in the modern development of the concept of controlled radical polymerization were considered and illustrated by...
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Acid-triggered radical polymerization of vinyl monomers
Reversible addition–fragmentation chain-transfer (RAFT) polymerization is one of the most versatile and robust controlled radical polymerization...
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Dispersity Regulation in Photo-controlled Radical Polymerization by Merging Aryl Sulfonyl Chloride Initiators and Mixed Disulfide Agents
O n-demand regulation of molecular weight distribution (MWD) is crucial to influence the properties of polymers. In this work, we reported an...
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Research progress in highly efficient reversible deactivation radical polymerization of vinylidene fluoride
Polyvinylidene fluoride (PVDF)-based polymers are extensively utilized in various fields such as building and large bridge coatings, lithium battery...
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Evolutions of precision radical polymerizations from metal-catalyzed radical addition: living polymerization, step-growth polymerization, and monomer sequence control
Metal-catalyzed Kharasch addition or atom transfer radical addition (ATRA) is one of the most efficient radical reactions for controlled syntheses of...
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Nitroxide-mediated living radical polymerization in dispersed systems
Living/controlled radical styrene miniemulsion polymerizations mediated by the nitroxide TEMPO were run at 135 °C. A coordinated experimental and...
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A comparison of RAFT and ATRP methods for controlled radical polymerization
Reversible addition–fragmentation chain-transfer (RAFT) polymerization and atom transfer radical polymerization (ATRP) are the two most common...
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2,4,5,6-Substituted 4,5-dihydro-1,2,4,5-tetrazin-3(2H)-ones as non-classical initiators of controlled radical polymerization of styrene
A series of 2,4,5,6-substituted 4,5-dihydro-1,2,4,5-terazin-3(2 H )-ones are studied as initiators of controlled radical polymerization of styrene at...
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Rare earth–cobalt bimetallic catalysis mediates stereocontrolled living radical polymerization of acrylamides
The tacticity of polymers is one of the governing microstructural parameters that determines their material properties. Current methods to access...
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Toward an understanding of the effects of nanocellulose during the free-radical polymerization reactions. Kinetic aspects of suspension-free radical polymerization of methyl methacrylate (MMA) in the presence and absence of nanocellulose
The aim of the present study is to examine the evolution of monomer conversion during suspension free radical polymerization of methyl methacrylate...
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Persistent radical anion of perylene dianhydride: an emerging metal-free photocatalyst for near-infrared photocontrolled RAFT polymerization
Develo** a new type of photocatalyst (PC) and catalytic mechanism for near-infrared (NIR) photocontrolled reversible-deactivation radical...
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One-pot and One-step Cu(0)-mediated Reversible-Deactivation Radical Polymerization of N-Isopropylacrylamide (NIPAM) in Water
Copper(0)-mediated reversible-deactivation radical polymerization (Cu(0)-mediated RDRP) of the water-soluble monomer N -isopropylacrylamide (NIPAM)...
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Controlled Radical Polymerization: from Oxygen Inhibition and Tolerance to Oxygen Initiation
Molecular oxygen is a radical scavenger in both conventional and controlled radical polymerization (CRP), resulting in many time-consuming methods...
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Miniemulsion Polymerization
The subject of miniemulsion polymerization is reviewed. The approach taken is one that combines a review of the technology with historical and...
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Ionic Polymerization
Ionic polymerization, similar to radical polymerization, involves a chain mechanism in which either cations (cationic polymerization) or anions...