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STUDY OF THE STRUCTURE AND PARAMAGNETIC PROPERTIES OF THE [Dy(H2O)
n (CyDTA)]– COMPLEX IN AN AQUEOUS SOLUTION USING NMR DATAAbstractThe structure and paramagnetic properties of the [Dy(H 2 O) n (CyDTA)] – complex are studied by 1 H NMR using the analysis of paramagnetic shifts...
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Microwave-Assisted Synthesis of Functionalized Chitosan Adsorbents for Cerium Adsorption from Aqueous Solutions
AbstractThe microwave method was introduced as an alternative energy source (other than thermal or photochemical methods) in the synthesis of...
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Conformational Dynamics and Thermosensory Properties of [Ln(H2O)n(EDTA)]– (Ln = Pr, Eu, Tb, Ho, Er, Tm) Complexes in Aqueous Solutions according to NMR Data
AbstractThe paramagnetic, thermosensory, and molecular dynamic properties of the [Ln(H 2 O) n (EDTA)] – (Ln = Pr, Eu, Tb, Ho, Er, Tm) complexes were...
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Radio Brightness Contrasts of Aqueous Solutions of Alkali Metal Hydroxides in the Millimeter Spectral Range
AbstractUsing a high-sensitivity radiometer at a frequency of 61.2 GHz (millimeter spectral range), the radio brightness characteristics of aqueous...
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Generation of Long-Lived Phenoxyl Radical in the Binuclear Copper(II) Pivalate Complex with 2,6-Di-tert-butyl-4-(3,5-bis(4-pyridyl)pyridyl)phenol
AbstractA new binuclear copper(II) complex Cu 2 (Piv) 4 (L) 2 , where Piv – = pivalate, L = 2,6-di- tert -butyl-4-(3,5-bis(4-pyridyl)pyridyl)phenol, was...
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Conformation and Counterion Distribution of Polyelectrolyte in Solution as Viewed from Dielectric Approach
Polyelectrolyte solutions are more variable than uncharged macromolecule due to electrical interaction between charged molecules and surrounding...
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Radio Brightness Contrasts of Aqueous Solutions of Alkali Metal Nitrates in the Millimeter Spectral Range
AbstractUsing a high-sensitivity radiometer at a frequency of 61.2 GHz (millimeter spectral range), the radio brightness characteristics of aqueous...
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Electrochemical Modification of the Aluminum Surface by Cathodic Treatment in Chitosan-Containing Aqueous Phosphate-Molybdate Solutions
AbstractThe state the morphology of the surface of the aluminum electrode, the elemental composition of the surface layer before and after cathodic...
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Natural Radiation of Aqueous Solutions of Strong Acids in the Millimeter Region of the Spectrum
AbstractExperimental and computational ways of determining the brightness contrast of aqueous solutions in the millimeter spectral region are...
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Nuclear magnetic resonance study of the temperature dependence of paramagnetic chemical shifts of [Co(EDTA)]2− complexes in gelatin gel
NMR spectroscopy was applied to study the temperature dependences of paramagnetic chemical shifts of the [Co(EDTA)] 2− complex ( 1 ) in D 2 O solution and...
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Preparation and Electron Conductivity of DNA-Aligned Cast and LB Films from DNA-Lipid Complexes
We describe here a simple preparation of a DNA-lipid complex that is soluble in organic media, and preparations of DNA-aligned thin films from the...
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An Overview on the Dynamics in Aqueous Mixtures of Lower Alcohols
In this chapter, we present a comparative study of dynamics in three types of alcohol–water mixtures: methanol–water, ethanol–water, and...
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Radiation of Aqueous Solutions of Non-Electrolytes in the Millimeter Range of the Spectrum and Their Dielectric Properties
AbstractA highly sensitive radiometer is used at a frequency of 61.2 GHz to study the brightness characteristics of aqueous solutions of...
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Counter-ion adsorption and electrostatic potential in sodium and choline dodecyl sulfate micelles — a molecular dynamics simulation study
ContextCholine-based surfactants are interesting both from the practical point of view to obtaining environmental-friendly surfactants as well as...
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Molecular reactions at aqueous interfaces
This Review aims to critically analyse the emerging field of chemical reactivity at aqueous interfaces. The subject has evolved rapidly since the...
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The role of water molecular structuring in the formation of the inclusion compounds based on cucurbit[8]uril and trans-[Co(en)2Cl2]+, trans-[Ru(en)2Cl2]+ complexes: a DFT examination
This paper presents the results of studying the structural features of inclusion compounds based on the cucurbit[8]uril macrocycle and the...
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Rotational Correlation Times of Tris(acetylacetonato)cobalt(III) in Various Organic Solvents by NMR Relaxation Measurements
NMR relaxation times of the dual-specific nuclei of metal cobalt-59 and ligand methine carbon-13 for tris(2,4-pentanedionato)cobalt(III), which is...
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Aqueous spray-drying synthesis of alluaudite Na2+2xFe2−x(SO4)3 sodium insertion material: studies of electrochemical activity, thermodynamic stability, and humidity-induced phase transition
In pursuit of high-energy density sodium insertion materials, polyanionic frameworks can be designed with tuneable high-voltage operation stemming...
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Proton, thermal and mechanical relaxation characteristics of a complex biomaterial (de-fatted date-pits) as a function of temperature
Thermal (differential scanning calorimetry, DSC), proton (low-frequency nuclear magnetic resonance, LF-NMR), and mechanical (differential mechanical...
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Motile behaviour of droplets in lipid systems
Motility is the capacity for living organisms to move autonomously and with purpose, and is essential to life. The transition from abiotic chemistry...
