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Synthesis, Structural Elucidation and DNA-Binding Studies of Centrosymmetric Paddlewheel Copper Carboxylate Complexes
Synthesis, characterization and structural relevance of four new copper carboxylate complexes ( 1 – 4 ) has been presented here. The complexes have been...
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Palladium carboxylate π-complexes with unsaturated hydrocarbons and the reactions catalyzed by them
This review summarizes the studies on the palladium carboxylate π-complexes with unsaturated hydrocarbons (alkenes, alkynes, and arenes) as well as...
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Characterization of New Pentanuclear Copper(II) and REE(III) Carboxylate Complexes
AbstractNew pentanuclear complexes [Cu 3 M 2 (CHF 2 COO) 12 (H 2 O) 8 ]·2H 2 O, where M = Er ( I ) and Nd ( II ), were synthesized by reacting individual copper...
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Synthesis and Structure of Cyclometallated Palladium Binuclear Complexes with Bridging Carboxylate Ligands
AbstractNew bimetallic pivalate Pd(II) complex [PdNi(OOC t Bu) 4 (HOOC t Bu)] ( I ) has been synthesized from [PdNi(OOCMe) 4 ] and used as a starting reagent...
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Intramolecular force field for carboxylate Pt(II)-complexes
Force-field parameters are required for classical molecular dynamics (MD) simulations. Generally, these force fields are well described for organic...
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Synthesis, Structure, and Biological Activity of New Metal Carboxylate Complexes Containing a Glycoluril Fragment
AbstractCu(II), Ni(II), Zn(II), Co(II), Fe(II), Mn(II) carboxylates containing a pharmacophoric glycoluril fragment were obtained for the first time....
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Polyelectrolyte Complexes
This chapter presents selected ideas concerning complexes that are formed either by oppositely charged polyelectrolytes or by polyelectrolytes and...
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Synthesis, Structural, DFT, and Antimicrobial Studies of Some Cefprozil Complexes
AbstractCefprozil complexes with Co(II), Ni(II), Zn(II), Mn(II), Cr(III), Fe(III) and Cu(II) were synthesized. Structure of the synthesized complexes...
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Self-assembled discrete and polymeric cobalt(II) complexes of a carboxylate appended tripodal tetradentate ligand: reactivity with aerial dioxygen or aqueous hydrogen peroxide
Three new cobalt(II) complexes [Co(µ 2 - L )] 3 (ClO 4 ) 3 . 2H 2 O, 1 , [Co( L )(NO 3 )], 2 and {[Co(µ 2 - L )(MeOH)](BPh 4 ) . (MeOH)} n , 3 are prepared where L stands for...
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Coordination of Hexahydro-1,3,5-trimethyl-1,3,5-triazine in Cadmium(II) and Cobalt(II) Carboxylate Complexes
AbstractThe effect of bulky tridentate ligands on the geometry of carboxylate complexes was studied in relation to...
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Desolvation of metal complexes to construct metal–organic framework glasses
Structural design is an important challenge in glassy materials, including metal–organic framework (MOF) glasses. The current approaches of thermal...
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Synthesis, crystal structure, and catechol oxidase activity of a di-nuclear paddle-wheel Cu (II) carboxylate complex
A dinuclear copper (II) complex, Cu 2 (RCOO) 4 (L) 2 (1) while [RCOO = benzoate, L = 2-amino-3-chloro-5-trifluoro methyl pyridine], with square pyramidal...
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Isomerization of Binuclear Cadmium Carboxylate Complexes [Cd2L2(O2CR)4]
AbstractThe binuclear cadmium complexes in which the metal atoms are linked by two chelate-bridging carboxylate anions, [Cd 2 L 2 (µ 2 -(Рiv) 2 (κ O ,κ O' -(Рiv)
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New catalysts based on carboxylate Sn(IV) complexes used in the oxidation reaction of 3,5-di-tert-butylcatechol to 3,5-di-tert-butyl-o-benzoquinone
Seven carboxylate Sn(IV) complexes C 1 –C 7 were synthesized by condensation between piperic acid with tri -phenylstannanol C 1 , piperic acidwith di -butyls...
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Structural effects of the carboxylate anion on Ru-catalyzed C—H arylation of (hetero)aromatic substrates containing N-donor directing group
Anions of carboxylic acids are widely used as the promoters of ruthenium-catalyzed reactions of C—H activation of substrates containing an N-donar...
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Triboluminescence of Lanthanide Complexes
The photoluminescence of lanthanide complexes originating from f–f transitions is generally sensitized through energy transfer from the ligand to...
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Anti-carcinoma and anti -microbial behavioral studies for octahedral synthesized Schiff base metal complexes
2,2′-((1Z-1′Z) (1,3-diphenylpropane-1,3-diylidene) bis (azanylylidene)) dibenzoic acid (H 2 L) Schiff base ligand, derived from condensation reaction...
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Benzothiadiazole-based rotation and possible antipolar order in carboxylate-based metal-organic frameworks
By modifying organic ligands of metal-organic framework with dipolar units, they turn suitable for various applications, e.g., in the field of sensor...
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New bioactive Co (II) coordination polymers with morphline and carboxylate ligands; Synthesis, structures, spectroscopic and thermal properties
Three new bioactive nanosized supramolecular cobalt coordination polymers; {[Co 2 (tyr) 2 (Morph) 2 (Cl) 2 (H 2 O) 2 ]} n (1), {[Co(Morph) 6 ] +2 [Co(bdc)(Morph) 2 (Cl) 2 ]...
