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Syntheses, Crystal Structures, and Magnetic Properties of Two Cobalt(II) Coordination Complexes with 4'-Substituted 3,2':6',3''-Terpyridine Ligands
AbstractTwo new cobalt(II) coordination complexes [Co(Phtpy)(HBTC) 0.5 ] n · n H 2 O ( I ) and [Co(Meophtpy)(HBTC) 0.5 ] n · n H 2 O ( II ) (Phtpy =...
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Zinc(terpyridine)-Incorporated Metal–Organic Frameworks Enabled Photocatalytic Oxidative Coupling of Amines Under Visible Light in Atmospheric Air
Poor light absorption ability severely limit the photocatalytic efficiency of metal–organic frameworks (MOFs) for chemical transformations. Herein,...
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Terpyridine-Containing 5-(2-Pyridylmethylene)-2-thioimidazolones and Their Coordination Compounds with Copper(II) Chloride: Synthesis and Cytotoxicity
AbstractMethods for the synthesis of new ditopic organic ligands containing coordinating fragments of two types, terpyridine and thiohydantoin, have...
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Effect of density functional approximations on the calculated Jahn–Teller distortion in bis(terpyridine)manganese(III) and related compounds
ContextBis(terpyridine)manganese(III) exhibits Jahn–Teller distortion due to the inequivalent occupation of the degenerate e g orbitals of this...
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A Bis(terpyridine)nickel(II)-Based Coordination Nanosheet: A Redox-Active Material with Flexibility and Transparency
We report a novel functional bis(terpyridine)metal(II) complex coordination nanosheet (CONASH) comprising a three-armed terpyridine ligand and Ni 2+ ...
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Luminescent terpyridine-based metallo-supramolecular systems: from design to applications
Luminescent metallo-supramolecules have received tremendous attention in recent years owing to their diverse yet well-defined structures, tunable...
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Heteroligand Zn(II) Metal-Organic Frameworks Based on 4-Substituted 4,2':6',4"-Terpyridine Derivatives and Terephthalates
AbstractMetal-organic frameworks based on Zn(II) and 4-substiuted 4,2':6',4"-terpyridine, terephthalate (Bdc), and 2-iodoterephthalate (2-I-Bdc)...
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Synthesis of Zirconium(IV) Oxyacrylate Complexes with Polypyridine Ligands and Their Application as Precursors of Nanomaterials with Antiwear Properties
AbstractIn the present study, complexes of zirconium(IV) oxyacrylate with polypyridine ligands 2,2'-bipyridine, 1,10-phenanthroline, and...
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Novel Terpyridine Derivatives of Benzothiazole and Copper(II) Complex: Synthesis and Spectral Studies
AbstractNovel terpyridine derivatives of benzothiazole were synthesised by simple multicomponent one-pot reaction of benzothiazole-2-carbaldehyde,...
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Designing narcissistic self-sorting terpyridine moieties with high coordination selectivity for complex metallo-supramolecules
Coordination-driven self-assembly is a powerful approach for the construction of metallosupramolecules, but designing coordination moieties that can...
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Titanium(IV) Oxoacrylate Complexes with Polypyridine Ligands as Precursors of Nanomaterials with Antiwear Properties
AbstractComplexes of titanium(IV) oxoacrylates with polypyridine ligands 2,2′-bipyridine, 1,10-phenanthroline, and 4′-phenyl-2,2′:6′,2′′-terpyridine,...
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Synthesis, Spectral, and Single Crystal XRD Studies of Novel Terpyridine Derivatives of Benzofuran-2-carbaldehyde and their Cu(II) Complex
AbstractA series of novel terpyridine derivatives of benzofuran (NP1–NP3) were synthesised by simple multicomponent one pot reaction among...
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A Tris(terpyridine) Ligand-based Metal Coordination Nanosheet as Electrode Material with Good Supercapacitor Performance
In this work, through a facile liquid–liquid (L–L) interfacial-assisted synthesis at room temperature, a new two-dimensional (2D) metal coordination...
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Synthesis and Stimuli-Responsive Properties of Metallo-Supramolecular Phosphazene Polymers Based on Terpyridine Metal Complexes
In this study, terpyridine functionalized phosphazene based metallo-supramolecular polymers were synthesized by three step reaction method. In the...
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Supramolecular Complexes Built of Octahedral [Ta6Cl12(CN)6]3−/4− Clusters and Terpyridine-Metal Complexes
The preparation and characterization of two supramolecular complexes from octahedral [Ta 6 Cl 12 (CN) 6 ] 4−/3− units and 2, 2′: 6′, 2″-terpyridine ( Terpy )...
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Metal Complexes with Redox-Active Ligands in the Indirect Electrosynthesis of Organic Sulfur Compounds
AbstractA possibility of using metal complexes with redox-active ligands in organic electrosynthesis is demonstrated on the basis of literature data...
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Tuning the reactivity of ruthenium(II) terpyridyl complexes using auxiliary ligands: kinetic and mechanistic studies
Substitution behavior of the labile aqua ligand in four mononuclear ruthenium(II) terpyridyl complexes with different auxiliary N (pyridine) ( Ru1 ),...
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Low-cost photo-switches based on stilbene-appended Zn(II)–terpyridine complexes
AbstractWe report herein the synthesis, characterization, photophysics, and photo-isomerization behaviors of three Zn(II)–terpyridine complexes of...
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Synthesis of azinyl azolyl pyrimidines as new hybrid N,N,N-tridentate ligands for coordination chemistry
Routes were proposed for the synthesis of new pyrimidine-derived polycyclic nitrogen heterocycles – 4-(1 H -pyrazol-1-yl)-2-(pyridin- 2-yl)pyrimidines...
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Organotin(IV) from Simple Complexes to Macromolecules: A Review Inspired by the Late Professor Charles Carraher
The coordination chemistry of the organotin(IV) compounds is dominated by nitrogen and oxygen donor ligands. Some of these complexes have found...
