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Peculiarities in the Radiolysis of β-Diketones
AbstractIntramolecular hydrogen bonding has a significant effect on the radiolytic transformations of β-diketones. Using the radiolysis of...
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Radiolysis of aerated aqueous ammonia solutions
The radiolytic behaviors of aqueous ammonia solutions under γ-ray irradiation were investigated, focusing on several factors, including initial...
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Nanosecond pulse radiolysis of aqueous N, N-diethylhydroxylamine solution
The reaction mechanisms and rate constants of N, N-diethylhydroxylamine (DEHA) with · OH, CO 3 − · , e aq − and · H were studied. Results show that · OH...
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Effect of Intramolecular Donor-Acceptor Interactions on the Radiolysis of Organic Compounds: Effects in Acetylacetone
AbstractIt has been shown for acetylacetone as an example that the intramolecular hydrogen bond significantly affects the radiolytic transformations...
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Protective Effects in the Radiolysis of Acidified Hydrocarbon Solutions of Tributyl Phosphate
AbstractThe effect of radiolysis and postradiation acid hydrolysis on the composition of the degradation products of tributyl phosphate (TBP, 30 wt...
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Study on the α-ray radiolysis product of hydroxysemicarbazide
Hydroxysemicarbazide (HSC) as a novel salt-free organic reductant has the ability to accomplish the reduction of Pu(IV) fast in the nuclear fuel...
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Influence of the regeneration method of irradiated mixture “30% TBP in Isopar-M” on the lower temperature limit of flame propagation
When a circulating extraction mixture of 30% TBP in Isopar-M, saturated with 3.4 mol L −1 nitric acid, is irradiated with a dose of up to 2000 kGy,...
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Degradation of the Chromophore Functions of Dyes in Irradiated Solutions
AbstractRadiolysis damages the system of conjugated bonds and thus leads to the degradation of the chromophore functions of dyes in aqueous...
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Radiation-induced effects during the extraction of Pu-239 nitrate with a solution of tributyl phosphate in octafluoropentanol formal
Extractive treatment of ≥ 0.2 M 239 Pu solution in an acidified mixture of tributyl phosphate and octafluoropentanol formal is accompanied by...
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Radiolytic Processes in Boiling Acetone
AbstractThe composition and yields of the radiolysis products of boiling acetone change significantly compared to those at room temperature. Boiling...
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Effect of Gamma-Irradiation Dose on the Yield and Acute Toxicity of Seed Potato Tubers of the Meteor Variety
AbstractThe influence of the dose of presowing γ-irradiation of tubers on the anatomical and morphological structure, yield, and tasting properties...
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Effect of Boiling on the Radiolysis of 1-Propanol
AbstractThe radiolysis of 1-propanol without heating and in a boiling state under the action of accelerated (8-MeV electrons) was investigated. At...
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Direct and Indirect Effects of an Electron Beam on N,N,N',N'-Tetra-n-Octyl Diglycolamide in Hydrocarbon–Alcohol Solutions
AbstractThe radiolysis of a radiochemical extraction system based on N,N,N',N' -tetra- n -octyl diglycolamide (TODGA) dissolved (0.15–0.2 M) in a...
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Contribution of nitric acid and alcohol to the radiolytic degradation of TODGA in Isopar-M
Radiolytic transformations of TODGA (N,N,N',N'-tetra-n-octylamide of diglycolic acid) in Isopar-M significantly depend both on the addition of...
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Formation of Positronium Atom in Molecular Media. Determination of Carcinogenic and Anticarcinogenic Properties of Chemical Compounds
AbstractChemical carcinogens are known to be one of the main causes of cancer. The review considers the biological and physicochemical methods for...
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Influence of electron irradiation on the properties of α-aluminum hydride polymorph
Changes in dielectric properties and thermal stability of the alpha-aluminum hydride polymorph (α-AlH 3 ) after irradiation with electrons with an...
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Gamma Radiation-Induced Synthesis and Characterization of Decahedron-Like Silver Nanostructure and Their Antimicrobial Application
In the current study, a decahedron-like silver nanostructure (D-AgNs) was successfully created in an aqueous solution in the presence of...
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Radiolytic behaviour of a TODGA based solvent under alpha irradiation
In this work the radiolytic stability of a TODGA based solvent has been investigated in alpha radiolysis measured by solvent extraction distribution...