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Ruthenium Complexes Based on C2B9-nido-Carborane and Tridentate Phosphorus- and Nitrogen-Containing Ligands
AbstractReaction of bis(2-(diphenylphosphino)ethyl)benzylamine (PNP) and bis(2-methylpyridyl)benzylamine (NNN) with known closo -ruthenacarborane...
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Iron(II) Spin Crossover Systems with Multidentate Ligands
This chapter focuses on the synthesis and characterization of iron(II) spin crossover compounds in which one of the ligands is multidentate. Here we...
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“Zwitterionic Phospholide Derivatives—New Ambiphilic Ligands”
Attachment of one or two phosphonio substituents converts a phospholide anion not only into a zwitterion or cation but induces as well a...
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New P-Chirogenic Phosphine Ligands and Their Use in Catalytic Asymmetric Reactions
This chapter is concerned with an update on the preparation and applications of optically active phosphine ligands which bear the chiral center at a...
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Mercury(II) Complexes with Thiacrowns and Related Macrocyclic Ligands
The complexation behavior of thiacrown ligands and related macrocycles towards the heavy metal ion mercury(II) is discussed. An important focus is...
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Kinetic of Synthesis Pincer Ligand Based on Thiol and Phosphorus: Thermodynamic Their Complexes
AbstractIn this article, the kinetics of aliphatic pincer ligand based on SNS (bis(2-(µ 1 -sulfanyl)ethyl)amine)and SNP N-(2-( l µ-phosphanyl)ethyl)-2-( l ...
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Synthesis of new π-stabilized organophosphorane bis-ylide ligands
The synthesis of a series of new organophosphorane bis-ylide ligands is described. Upon their deprotonation, the stabilization of the ylide α -carbanio...
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First P*-chiral bicyclophosphite-type ligands
New readily accessible aminodiol and diaminoalcohol were obtained using simple condensation and reduction reactions. On their basis, earlier unknown...
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Metal Complexes with Redox-Active Ligands in the Indirect Electrosynthesis of Organic Sulfur Compounds
AbstractA possibility of using metal complexes with redox-active ligands in organic electrosynthesis is demonstrated on the basis of literature data...
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Preparation of a novel flame retardant based on phosphorus/nitrogen modified lignin with metal–organic framework and its application in epoxy resin
To reduce the fire risk of epoxy (EP) resin, a renewable lignin-based flame retardant functionalized with a metal–organic framework (MOF) HKUST-1 (Cu 3 (BTC)...
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Synthesis and Extraction Properties of Tripodal Tetraphosphoryl Ligands on the Triphenylphosphine Oxide Platform
AbstractNew tetraphosphoryl tripodal ligands on the triphenylphosphine oxide platform [2-Ph 2 P(O)(CH 2 ) n OC 6 H 4 ] 3 PO with different linker length ( n = 3,...
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Assembly of air-stable copper(I) alkynide nanoclusters assisted by tripodal polydentate phosphoramide ligands
Copper(I) nanoclusters are attractive due to their potential applications, but their synthesis remains challenging due to susceptibility to oxidation...
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Structure and Thermal Properties of Silver Complexes with 2,2′-Bipyridine and Fluorinated β-Diketonate Ligands
AbstractNew silver complexes [Ag(bipy)(CH 3 COCHCO R )] x with 2,2′-bipyridine (bipy) and β-diketonate ligands (tfac: R = CF 3 , x = 2; hfbac: R = C 3 F 7 , x = ...
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Hydrolytically stable organometallic ruthenium complexes with glucose-based phosphite ligands
New organometallic ruthenium complexes with glucose-based phosphite ligands bearing uracil, thymine, and 5-fluorouracil units as well as the bromide...
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Synthesis and Application of Novel Chiral Cp Ligands in Transition Metal Catalysis
Chiral cyclopentadienyl groups and their respective metal complexes have been studied for several decades. However, it is only in the last decade...
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Modification of QuinoxP*-Type Bisphosphine Ligands for High-Performance Asymmetric Boryl Substitution of Racemic Allyl Electrophiles
Optically active organoboron compounds are important building blocks in organic synthesis, especially α-chiral allylic boronates because various...
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Rhenium and Technetium Complexes Anchored by Phosphines and Scorpionates for Radiopharmaceutical Applications
This review presents a comprehensive overview of the most significant developments in the chemistry of technetium and rhenium complexes anchored by...
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Use of N,N-Coordinating Ligands in Catalytic Asymmetric C--C Bond Formations: Example of Cyclopropanation, Diels--Alder Reaction, Nucleophilic Allylic Substitution
Chiral N,N-coordinating ligands have been particularly synthesized for their use as metal chelates catalyzing asymmetric C-C bond formations....
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Development of a Synthetic Method for Tridentate Phosphine Ligands
Tridentate phosphine compounds have been reported to be an effective ligand for various kinds of transition-metal-catalyzed reactions such as...
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Pd(II) and Pt(II) Mixed Ligand Complexes Containing 2,5-Dimercapto-1,3,4-Thiadizole and 1,2-Bis(diphenylphosphino)ethane Ligands, Synthesis, Characterization, Crystal Structure, Anticancer and Computational Studies
One pot reaction of K 2 MCl 4 with two equivalents of 2,5-dimercapto-1,3,4-thiadiazole (dmtzsH 2 ) and one equivalent of 1,2-bis(diphenylphosphino)ethane...
