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Coordination Polymerization
Nearly half of all polymers produced worldwide (according to production volume) are produced by catalytic polymerization reactions carried out in the...
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Experimental study and kinetic modeling of radical-coordination styrene polymerization with participation of ferrocene
A kinetic model of styrene polymerization with participation of benzoyl peroxide and ferrocene was developed, based on the radical-coordination...
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Miniemulsion Polymerization
The subject of miniemulsion polymerization is reviewed. The approach taken is one that combines a review of the technology with historical and...
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Syndioselective coordination (Co)polymerization of triphenylamine-substituted styrenes via a scandium catalyst system
Coordination polymerization of the triphenylamine-substituted styrene derivatives N,N-diphenyl-4′-vinyl-[1,1′-biphenyl]-4-amine (FSt1) and...
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Metathesis Polymerization To and From Surfaces
Polymerization to and from surfaces using metathesis-based techniques – ring-opening metathesis polymerization (ROMP) and 1-alkyne polymerization –...
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Stereospecific Olefin Polymerization Catalyzed by Metallocene Complexes
Metallocene complexes that serve as stereoselective olefin polymerization catalysts are described. The polymerization of propylene, styrene, methyl...
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CpTiCl3/MAO-catalyzed polymerization and copolymerization with isoprene and [3]dendralene derivatives
Coordination polymerization of a series of 2-substituted-[3]dendralenes, i.e., phenyl- (P3D), hexyl- (H3D), and trimethylsilyl-substituted...
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Octahedral Zirconium Complexes as Polymerization Catalysts
The synthesis and X-ray structure of various octahedral zirconium complexes and their catalytic properties in the polymerization of α-olefins are...
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Synthesis, Structural Analysis, Theoretical Calculations, In Silico Prediction of Antibacterial Efficacy, Toxicity Assessment, In Vitro Antioxidant Evaluation and Polymerization Activity of Cobalt(II) Coordination Complexes of Para-biphenylol
In this study, we report synthesis of novel cobalt(II) para-biphenyloxides (complexes 1 and 2 ) by reacting cobalt(II) chloride...
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Chitosan-transition metal coordination biopolymer: a promising heterogeneous catalyst for radical ion polymerization of vinyl acetate at ambient temperature
The present study utilized chitosan obtained from crab shell and transition metal salts as precursors to synthesize chitosan-metal coordination...
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Late Transition Metals as Homo- and Co-Polymerization Catalysts
In the present account we address two aspects of the polymerization processes catalyzed by the late-transition-metal complexes: (i) influence of the...
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Anatomy of Catalytic Centers in Phillips Ethylene Polymerization Catalyst
A relevant fraction of the polyethylene produced in the world (about 30%) is obtained with the Phillips process. Many efforts in the last 30 years...
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Enzymatic Synthesis of Polyesters via Ring-Opening Polymerization
An enzyme can act as a powerful catalyst for the production and chemical recycling of green and sustainable polymers via a ring-opening...
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Rare earth–cobalt bimetallic catalysis mediates stereocontrolled living radical polymerization of acrylamides
The tacticity of polymers is one of the governing microstructural parameters that determines their material properties. Current methods to access...
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Regio- and Stereoselective Polymerization of Bio-based Ocimene by Rare-Earth Metal Catalysts
Coordination polymerization of renewable β -ocimene has been investigated using asymmetric diiminophosphinate lutetium complex 1 , β -diketiminate...
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Efficient ring-opening polymerization of epsilon-caprolactone catalyzed by iron(III) chloride under mild reaction conditions
As a biodegradable polyester, the commercialized synthesis protocol of poly(ε-caprolactone) (PCL) under mild conditions is of great significance and...
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Supramolecular Coordination Chemistry
If molecular chemistry is referred to as the chemistry of covalent bonds, then supramolecular chemistry deals with the chemistry beyond the molecule....
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Features of Polymerization of Methyl Methacrylate in the Presence of New Ruthenium(II) and Ruthenium(III) Carborane Complexes with Chelate P‒O‒P Ligands
AbstractThe radical polymerization of methyl methacrylate by the atom transfer radical polymerization (ATRP) mechanism under the action of systems...
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The Relationship between the Cure Rate of Methyl Methacrylate–Macroinitiator Adhesive Composition and the Macroinitiator Composition Obtained by Titanocene Dichloride-Involved Radical-Initiated Polymerization
AbstractBy means of kinetic simulation, we established how the cure rate of an acrylic adhesive composition, poly(methyl methacrylate) macroinitiator...
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Cobalt(II) Metallopolymers with 5-methyl-5-hexene-2,4-dione Immobilized on a Polystyrene Matrix as Initiators of Radical Polymerization of Metyl Methacrylate
Complexation of a copolymer of styrene and 5-methyl-5-hexene-2,4-dione with cobalt chloride in dimethylformamide occurs with the formation of...
