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The Cage Molecules
Certain polycyclic hydrocarbons exhibiting fascinating, cage-like structures have been synthesised. These are generally given names indicating their...
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Thermal Decomposition of Synthetic Cage Hydrocarbons and Their Mixtures
AbstractThe kinetics of thermal decomposition of cage hydrocarbons, specifically exo -tricyclo[5.2.1.0 2.6 ]decane ( exo -TCD) and exo , endo -tetracyclo[5.3.1.0...
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Enantioselective fullerene functionalization through stereochemical information transfer from a self-assembled cage
The regioselective functionalization of C 60 remains challenging, while the enantioselective functionalization of C 60 is difficult to explore due to...
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A correction into “Theoretical prediction of the trigger linkage, cage strain and explosive sensitivity of CL-20 in the external electric fields”
In order to obtain the more reliable impact sensitivities of CL-20 in the external electric fields, the calculation scheme for the sensitivities...
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Preparation of Cage-Like Micellar Assemblies of Engineered Hemoproteins
Natural protein assemblies have encouraged scientists to create large supramolecular systems consisting of various protein motifs. In the case of...
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Theoretical prediction of the trigger linkage, cage strain, and explosive sensitivity of CL-20 in the external electric fields
In order to add safely external electric fields into the systems of the explosives with strong cage strain, the effects of the external electric...
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Aniline derivatives containing a cage monoterpenoid fragment at the nitrogen atom: synthesis and study of antibacterial properties
New camphor and fenchon anils, promising materials for the needs of medicine and industry, as well as some of their reduced forms, were synthesized...
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A Novel Approach for Delivery of Ergosterol Within Ferritin Cage: Stability, Slow-Release Property, and Cholesterol-Lowering Effect After Simulated Gastrointestinal Digestion
Ergosterol possesses a variety of physiological activities, however, its application is limited due to its poor water solubility and...
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Physiologically Active Compounds Based on Membranotropic Cage Carriers–Derivatives of Adamantane and Polyhedral Boron Clusters (Review)
AbstractData on compounds based on cage structures―boron clusters (polyhedral boron hydrides, carboranes, metallacarboranes) and compounds of the...
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Gas- and liquid-phase ozonolysis of ethylene, butadiene, and perfluoro-olefins: solvation and the cage effect
Quantum-chemical calculations were performed for the primary step of ozonolysis reaction of different olefins: ethylene, 1,3-butadiene,...
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Bonding analysis of the effect of strain on trigger bonds in organic-cage energetic materials
Wiberg bond index and natural bond orbital analyses were used to examine the effect of strain on trigger bonds for a series of organic-cage...
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1,3-Dehydroadamantane and Its Derivatives: A Versatile Synthetic Platform for the Preparation of Functional Compounds with a Cage Structure. A Review
AbstractA promising strategy in the synthesis of functional compounds with a cage structure is the use of 1,3-dehydroadamantane (tetracyclo[3.3.1.1. 3,7...
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Pyrroloquinoline quinone protects against murine hepatitis virus strain 3-induced fulminant hepatitis by inhibiting the Keap1/Nrf2 signaling
Fulminant hepatitis (FH) is a life-threatening clinical liver syndrome characterized by substantial hepatocyte necrosis and severe liver damage. FH...
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Facile construction of giant polymeric chains through strain-promoted azide-alkyne cycloaddition
Rational design of “giant” building blocks promotes the modular construction of polymeric counterparts at a large length scale. In this study, a...
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Structural Characteristics of Fullerenes
Fullerenes, exemplified by the famous C60, all feature alluring closed cage-shaped structures composed of pentagons and hexagons. They are pure...
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Structural Characteristics of Fullerenes
Fullerenes, exemplified by the famous C60, all feature alluring closed cage-shaped structures composed of pentagons and hexagons. They are pure...
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Artificial Protein Cages Assembled via Gold Coordination
Artificial protein cages made from multiple copies of a single protein can be produced such that they only assemble upon addition of a metal ion....
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Mechanism of biomolecular recognition of trimethyllysine by the fluorinated aromatic cage of KDM5A PHD3 finger
The understanding of biomolecular recognition of posttranslationally modified histone proteins is centrally important to the histone code hypothesis....
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Enhanced reactivity of twisted amides inside a molecular cage
When an amide group is distorted from its planar conformation, the conjugation between the nitrogen lone pair and the π * orbital of the carbonyl is...
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Enterocin M in Interaction in Broiler Rabbits with Autochthonous, Biofilm-Forming Enterococcus hirae Kr8 Strain
Young rabbits are susceptible to gastrointestinal diseases caused by bacteria. Enterococcus hirae can be associated with diseases. But enterocins...
