Search
Search Results
-
Hydrophobic Sn–Ti submicrospheres for cyclohexanone Baeyer–Villiger efficient oxidation
In this paper, hydrophobic treatment by hexadecetyltrimethoxysilane (HDTMS) on the surface of Sn–Ti submicrospheres with regular morphology and...
-
Al-containing Ge-rich IWV: rapid synthesis via interzeolite transformation and application in Baeyer-Villiger oxidation
Ge-containing Lewis acidic zeolites are typically synthesized using a conventional hydrothermal strategy from amorphous silica sources, through a...
-
Features of the Baeyer—Villiger reaction in the case of a complex variously functionalized substrate
The reactions of (3 S ,4 RS )-1,3-dideoxy-3-[(2 Z )-4-methoxy-3-methyl-4-oxobut-2-en1-yl]-4- C -methyl-4,5- O -(1-methylethylidene)pent-2-ulose with MCPBA and...
-
Mechanism and dynamics of Baeyer–Villiger oxidation of furfural to maleic anhydride in presence of H2O2 and Au clusters
ContextThe increasing demand for fuels and chemicals in the world has prompted the exploration of various forms of renewable energy resources. Using...
-
Rhenium-containing compound(PyHReO4): synthesis, characterization and catalytic application in olefin epoxidation and baeyer-villiger oxidation
A novel compound based on catalytic functional metal rhenium, pyridinium perrhenate(PyHReO 4 ) was synthesized and characterized. The pyridinium...
-
Baeyer–Villiger Oxidation
General scheme: -
Oxidation of Cage Derivatives of Quinopimaric Acid
AbstractThe oxidation of cage compounds derived from quinopimaric acid, namely γ-diketone, oxa-“bird cage,” 18-chloro-15-oxa-“bird cage,” and...
-
Formation of Formic Acid and Its Esters in Oxidation of Fatty Acid Methyl Esters
AbstractPathways of formation of low-boiling products in the course of oxidation of fatty acid methyl esters with atmospheric oxygen in a bubbling...
-
Dakin Oxidation
Oxidation of aryl aldehydes or aryl ketones to phenols using basic hydrogen peroxide conditions. Cf. A variant of the Baeyer–Villiger oxidation. -
Baeyer-Villiger Oxidation of Cyclic Ketones Catalyzed by Amino Acid Ionic Liquids
A series of amino-acid-based ionic liquids was synthesized via one-step protonation of the corresponding L -amino acid by utilizing an array of proton...
-
Chemoenzymatic total synthesis of alchivemycin A
Alchivemycin A belongs to a unique class of polyketide natural products isolated from plant-derived actinomycete Streptomyces . It shows potent...
-
Baeyer–Villiger Oxidation of Diastereomeric Michael Adducts of Levoglucosenone into Dilactones
AbstractThe oxidation of diastereomeric Michael adducts of levoglucosenone and cyclohexanone with 5 equiv of H 2 O 2 in isopropanol at 60°C results in...
-
Oxidation und Reduktion
Oxidationen und Reduktionen befassen sich hauptsächlich mit der Transformation von C-O-Bindungen, also der Bildung und Umsetzung von Alkoholen und... -
Study of the Mechanism of Coenzyme Specificity of Phenylacetone Monooxygenase from Thermobifida fusca by Site-Directed Mutagenesis
AbstractPhenylacetone monooxygenase from Thermobifida fusca (EC 1.14.13.92, PAMO) belongs to the Baeyer–Villiger family of monooxygenases and...
-
Synthesis of δ-Valerolactone Using Stable Hydrogen Peroxide Derivatives
AbstractThe efficiencies of hydrogen peroxide derivatives in the Baeyer–Villiger oxidation of cyclopentanone to δ-valerolactone have been compared....
-
CuO impregnated SBA-15; an efficient catalyst for B–V oxidation of cyclohexanone to caprolactone
The development of efficient, cost-effective, and environmentally friendly catalysts is pivotal in fine chemical synthesis. In this study, an...
-
Baeyer–Villiger Oxidation of Cyclohexanone by Hydrogen Peroxide with Fe3O4@GO as Catalyst Under Solvent Free Conditions
AbstractAn efficient magnetic nanocomposite catalyst (Fe 3 O 4 @GO) was synthesized and utilized as a sustainable and convenient catalyst for...
-
Effect of Sn and Zr Content in ZrAl- and SnAl-BEA Hierarchical Zeolites on Their Acidic and Catalytic Properties in the Process of Cyclohexanone Oxidation with Hydrogen Peroxide
Series of ZrAl- and SnAl-silicate hierarchical zeolites of the BEA structural type have been synthesized by hydrothermall method, and their acidic...
-
Continuous synthesis of ε-caprolactone in a microreactor and kinetics insights into its side reactions
Nowadays ε -caprolactone, the monomer of biodegradable polycaprolactone, is mainly produced via the strong exothermic Baeyer–Villiger oxidation of...
-