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  1. Reversible isomerization of donor-acceptor Stenhouse adduct derivatives in water through dendritic confinement

    Modulating reversible isomerization of hydrophobic dyes in aqueous solutions is greatly desired. Here we report on reversible isomerization of...

    Jiaxing Zhang, Qingyun Zhao, ... Wen Li in Science China Chemistry
    Article 08 April 2024
  2. Isomerization of bioactive acylhydrazones triggered by light or thiols

    The acylhydrazone unit is well represented in screening databases used to find ligands for biological targets, and numerous bioactive acylhydrazones...

    Zhiwei Zhang, Giang N. T. Le, ... G. Andrew Woolley in Nature Chemistry
    Article 12 June 2023
  3. Multi-site programmable functionalization of alkenes via controllable alkene isomerization

    Direct and selective functionalization of hydrocarbon chains is a fundamental problem in synthetic chemistry. Conventional functionalization of C=C...

    Zhengxing Wu, **gjie Meng, ... Wanbin Zhang in Nature Chemistry
    Article 18 May 2023
  4. Isomerization of Hexane and Heptane Mixtures in the Presence of Platinum-Containing Tungstated Zirconia Catalysts

    Abstract

    The isomerization of heptane and hexane and their mixtures in the presence of Pt/WO 3 –ZrO 2 catalysts with a tungsten oxide content of 10–35...

    M. D. Smolikov, V. A. Shkurenok, ... A. V. Lavrenov in Catalysis in Industry
    Article 04 September 2023
  5. What dictates alkane isomerization? A combined density functional theory and information-theoretic approach study

    Alkanes are deceptively simple in their geometric structures, yet their electronic structures are a tough nut to crack. We employ two total energy...

    Chenyu Luo, **n He, ... Dongbo Zhao in Theoretical Chemistry Accounts
    Article 02 August 2023
  6. Silica- and Alumina-Supported Sulfated Zirconia Catalysts for Hexane Isomerization: Effect of the Support Nature

    Abstract

    The effect of the support nature on the hexane isomerization reaction parameters for SiO 2 - and Al 2 O 3 -supported sulfated zirconia catalysts...

    M. D. Smolikov, L. I. Bikmetova, ... A. V. Lavrenov in Catalysis in Industry
    Article 26 December 2023
  7. Synthesis of degradable polymers via 1,5-shift radical isomerization polymerization of vinyl ether derivatives with a cleavable bond

    We report a novel method for synthesizing degradable polymers based on 1,5-shift radical isomerization polymerizations of vinyl ethers with...

    Mineto Uchiyama, Masato Imai, Masami Kamigaito in Polymer Journal
    Article Open access 17 January 2024
  8. Porous Alumina-Supported Tungstated Zirconia Catalysts for Heptane Isomerization

    Abstract

    Novel WO 3 –ZrO 2 (WZ) catalysts with palladium as an active metal on porous alumina supports of various phase compositions have been...

    M. D. Smolikov, V. A. Shkurenok, ... A. V. Lavrenov in Catalysis in Industry
    Article 27 May 2024
  9. Cationic polymerization of butadiene with isomerization of the initiator structure

    Cationic polymerization of butadiene using AlEt 2 Cl–isobutyl chloride initiating system was studied for the first time. It was found using NMR...

    V. A. Rozentsvet, D. M. Ulyanova, ... M. G. Kuznetsova in Russian Chemical Bulletin
    Article 26 September 2023
  10. Specific Features of Positional Isomerization of α-Olefins in the Presence of Zeolite Catalysts

    Abstract

    The positional isomerization of the double bond in α-olefins of С 16 –С 18 fraction on Y-type zeolite with the faujasite-type crystal structure...

    O. S. Vdovina, K. V. Shirshin, ... E. N. Generalova in Russian Journal of Applied Chemistry
    Article 01 September 2023
  11. Isomerization pathway of a C–C sigma bond in a bis(octaazamacrocycle)dinickel(II) complex activated by deprotonation: a DFT study

    The anti ( a ) to syn ( s ) isomerization pathway of the deprotonated form of the dimer with two nickel(II) 15-membered octaazamacrocyclic units...

    Ingrid Jelemenska, Michal Zalibera, ... Lukas Bucinsky in Theoretical Chemistry Accounts
    Article Open access 13 March 2024
  12. Counteranion-induced structural isomerization of phosphine-protected PdAu8 and PtAu8 clusters

    Controlling the geometric structures of metal clusters through structural isomerization allows for tuning of their electronic state. In this study,...

    Yu Fujiki, Tomoki Matsuyama, ... Seiji Yamazoe in Communications Chemistry
    Article Open access 20 June 2023
  13. Highly regioselective synthesis of branched saturated aldehydes by tandem hydroformylation/isomerization/hydrogenation of 1-arylbutadienes

    Rh-catalyzed tandem hydroformylation/isomerization/hydrogenation of various 1-arylbutadienes toward the corresponding branched saturated aldehydes...

    Huibing Shi, Peng Wang, ... Haigang Wu in Monatshefte für Chemie - Chemical Monthly
    Article 13 June 2024
  14. Silica Functionalized with Propylsulfonic Acid as an Efficient Metal-free Catalyst for Isomerization of Longifolene to Iso-longifolene

    Abstract

    The silica functionalized with propylsulfonic acid (SFS) was found to be an efficient solid acid catalyst for the solvent-free isomerization...

    Abhay M. Agola, Sagnik Mukherjee, ... Manish Kumar Mishra in Catalysis Letters
    Article 14 October 2023
  15. Effects of Zr, Al, and mordenite on Pt-MCM-48 catalyst in n-heptane isomerization: preparation, characterization and catalytic performance

    Herein, platinum-loaded MCM-48-Mordenite, Al-MCM-48, Al-MCM-48-Mordenite, Zr-MCM-48, and Zr-MCM-48-Mordenite catalysts were synthesized and studied...

    Z. Ghaderi, M. H. Peyrovi, N. Parsafard in Journal of Porous Materials
    Article 02 May 2023
  16. Optimized kinetic study of the isomerization reaction over composite catalysts by applying response surface methodology

    The Pt/HZSM-5-(KCC-1, KIT-6, and SBA-3) catalysts were successfully used for the isomerization reaction of n -heptane. These catalysts were used to...

    Nastaran Parsafard, Behnam Derakhshan in Journal of the Iranian Chemical Society
    Article 25 May 2024
  17. Allylcopper(I) Isomerization-Enabled Copper(I)-Catalyzed Intramolecular Alkylboration of Terminal Allenes

    A cyclobutane ring is one of the important skeletons in pharmaceutical molecules. However, the construction is challenging due to the strain of the...
    Chapter 2023
  18. Low-valent tungsten redox catalysis enables controlled isomerization and carbonylative functionalization of alkenes

    The controlled isomerization and functionalization of alkenes is a cornerstone achievement in organometallic catalysis that is now widely used...

    Tanner C. Jankins, William C. Bell, ... Keary M. Engle in Nature Chemistry
    Article 02 June 2022
  19. Isomerization of Xylenes (a Review)

    Abstract

    The review deals with catalysts for isomerization of the C-8 aromatic fraction with the aim of obtaining valuable petrochemical products: o -...

    N. R. Demikhova, M. I. Rubtsova, ... A. P. Glotov in Petroleum Chemistry
    Article 02 November 2021
  20. Integrated Processes of the Reforming and Isomerization of Gasoline Fractions for the Production of Environmentally Friendly Motor Gasolines

    Abstract

    The data on the development and study of new catalysts for the reforming and isomerization of gasoline fractions from the Center of New...

    M. D. Smolikov, D. I. Kir’yanov, ... A. V. Kleimenov in Catalysis in Industry
    Article 12 September 2022
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