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A comparative study of interplay effects between the cation-π and intramolecular hydrogen bond interactions in the various complexes of methyl salicylate with Mn+, Fe2+, Co+, Ni2+, Cu+, and Zn2+ cations
The interplay among two important noncovalent interactions involving aromatic ring is studied by means of density functional theory (DFT)...
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Green deep eutectic solvent assisted liquid–liquid microextraction procedure for Sunset Yellow dye in effervescent vitamin C tablets
Extensive research has been carried out recently using green deep eutectic solvents (DESs). In this study, a simple, low-cost, and at the same time...
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Light-driven ammonia synthesis under mild conditions using lithium hydride
Photon-driven chemical processes are usually mediated by oxides, nitrides and sulfides whose photo-conversion efficiency is limited by charge carrier...
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Extraction and characterization of ultrasound assisted extraction: improved functional quality of pectin from jackfruit (Artocarpus heterophyllus Lam.) peel waste
Jackfruit peels are potential waste for valorization and extraction of pectin and quality of pectin is a function of extraction conditions. Present...
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SNHAr Reaction of Pyridines with Bis(polyfluoroalkyl)phosphonates Assisted by Electron-Deficient Acetylenes
AbstractThe S N H Ar reaction of pyridines with bis(polyfluoroalkyl)phosphonates assisted by benzoylphenylacetylene (equimolar reactants ratio,...
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Dissolving Chitin by Novel Deep Eutectic Solvents for Effectively Enzymatic Hydrolysis
Chitin is the most productive nitrogen-containing polysaccharide in nature with immense potential for transforming into a range of chemicals....
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Thermal and Nonthermal Assisted Drying of Fruits and Vegetables. Underlying Principles and Role in Physicochemical Properties and Product Quality
Fruits and vegetables are essential for overall human health and nutrition, and there is a high quest for fruits and vegetables of superior quality....
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Semi-coordination Cu–O bond on a copper complex featuring O,O-donor ligand as potential antibacterial agent: green synthesis, characterization, DFT, in-silico ADMET profiling and molecular docking studies
The synthesis of 2-((5-methyl-pyridin-2-yl)amino)acetic acid ( MPAA ) and its copper complex ( Cu-MPAA ) has been performed. The new ligand, MPAA , was...
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Ionic liquids/polyionic liquids assisted synthesis of CuO nanoparticles for CO2 reduction to formic acid
This study demonstrates the utilization of polyionic liquids (PILs) as a nanosynthetic template in the synthesis of CuO nanoparticles (CuO NPs). PILs...
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Recent Advances in Surface-Assisted Laser Desorption/Ionization Mass Spectrometry and Its Imaging for Small Molecules
Mass spectrometry imaging (MSI) has provided a new perspective on acquiring spatial information of multiple molecules in various samples. Among the...
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Electrochemiluminescence biosensor for determination of lead(II) ions using signal amplification by Au@SiO2 and tripropylamine-endonuclease assisted cycling process
MXene@Au as the base and Au@SiO 2 as signal amplification factor were used for constructing an ultrasensitive “on–off” electrochemiluminescence (ECL)...
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Natural Deep Eutectic Solvents and Microwave-Assisted Green Extraction for Efficient Recovery of Bioactive Compounds from By-Products of Date Fruit (Phoenix dactylifera L.) Processing: Modeling, Optimization, and Phenolic Characterization
In this study, eight different natural deep eutectic solvents (NADESs) were utilized in combination with microwave-assisted extraction (MAE) as a...
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Systematic Narrowing of ZIF-8 Apertures via Controlled 2-Ethylimidazole Do** for Hydrogen/Carbon Dioxide Separation
Sodalite (SOD) zeolitic-imidazolate frameworks (ZIFs) with uniform angstrom scale apertures can offer high gas sieving ability for separation...
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Heterogeneous Catalysis on Liquid Organic Hydrogen Carriers
Hydrogen is recognized as an ideal substitute for conventional energy sources due to its exceptional merits. However, the lack of inexpensive and...
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Highly selective epoxidation of styrene at ambient temperature under photo-assisted condition over bimetallic Eu and Ti-doped amino-functionalized mesoporous molecular sieve
Mesoporous molecular sieves silica materials had been functionalized employing 3-aminopropyltriethoxysilane as the surface decoration agent by a...
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Controlled masking and targeted release of redox-cycling ortho-quinones via a C–C bond-cleaving 1,6-elimination
Natural products that contain ortho -quinones show great potential as anticancer agents but have been largely discarded from clinical development...
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Mechanochemical bond scission for the activation of drugs
Pharmaceutical drug therapy is often hindered by issues caused by poor drug selectivity, including unwanted side effects and drug resistance. Spatial...
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A Natural Deep Eutectic Solvent–based Ultrasound-Vortex-assisted Dispersive Liquid–Liquid Microextraction Method for Ligand-less Pre-concentration and Determination of Traces of Cadmium Ions in Water and Some Food Samples
A very explicate and ligand-less ultrasound-vortex-assisted dispersive liquid–liquid microextraction (US-VA-DLLME) technique has been designed for...
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Novel Ternary CuO–CeO2/g-C3N4 Heterogeneous Catalyst for Removing Methyl Orange Dye via Photo-Assisted Fenton-like Reaction
AbstractIn this paper, a new ternary CuO–CeO 2 /g-C 3 N 4 composite catalyst was synthesized by an impregnation method. A photo-assisted Fenton-like...
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Effect of Zinc Do** on Structural, Optical, Magnetic, and Catalytic Behavior of Co3O4 Nanoparticles Synthesized by Microwave-Assisted Combustion Method
The microwave-assisted combustion process (MCP) was adapted to prepared Zinc doped Co 3 O 4 spinel nanoparticles. Scanning electron microscopy (SEM),...