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Harnessing nanotechnology to expand the toolbox of chemical biology
Although nanotechnology often addresses biomedical needs, nanoscale tools can also facilitate broad biological discovery. Nanoscale delivery,...
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Cracking the intestinal lymphatic system window utilizing oral delivery vehicles for precise therapy
Oral administration is preferred over other drug delivery methods due to its safety, high patient compliance, ease of ingestion without discomfort,...
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Reactions of selenium dihalides with vinylbenzenes
Alkoxyselenation of vinylbenzenes with selenium dihalides was accomplished for the first time. The reaction with selenium dibromide was the most...
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Complexes of Group III Metals based on o-Iminoquinone Ligands
AbstractThe currently available published data on the synthesis, structure, and chemical properties of Group III metal complexes based on bi-, tri-,...
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Element-Blocks π-Conjugated Polymers by Post-element-Transformation Technique
The synthesis of a new class of π-conjugated polymers possessing versatile element-blocks is described. That is, regioregular organotitanium polymers...
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Covalent and Non-covalent Functionalized Nanomaterials for Environmental Restoration
Nanotechnology has emerged as an extraordinary and rapidly develo** discipline of science. It has remolded the fate of the whole world by providing...
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A Quest for Understanding
We explore the nature of atoms and their interaction by looking at the history that led us to know what atoms are and how they interact. Atoms...
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Regiospecific allyl chlorination of betulin and diacetylbetulin
For the first time it was established that in the reaction of selenium dichloride with betulin and diacetylbetulin it is realized regiospecific...
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Organoselenium Compounds as Reagents and Catalysts to Develop New Green Protocols
This chapter offers a comprehensive and updated overview on the use of organoselenium compounds as catalysts in organic synthesis. Around 150...
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Study of Inorganic and Coordination Compounds by the Static Tensimetric Method from Mendeleev to the Present Day
The review presents the evolution of the static tensimetric method from Mendeleev to the present day. A description of a new-generation automatic...
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A Periodic Table for Life and Medicines
Mendeleev’s periodic table of 63 elements, now extended to 118 elements, provides a basis for asking rational questions about which elements are...
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Reaction mechanism of organoselenium-catalyzed syn-dichlorination of alkenes: a DFT study
A new method for the syn -dichlorination of alkenes at room temperature has been proposed by Denmark et al. The method uses diselenide (PhSeSePh) as...
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Bis(1,3-dioxolan-2-ylmethyl)selenide
The reaction of selenium dihalides with 2-vinyloxyethanol has been performed for the first time, and the method of preparation of...
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Oxidation and halogenation of divinyl selenide. first synthesis of divinyl selenoxide
Efficient procedure was developed for the preparation of divinyl selenoxide in 92% yield by oxidation of divinyl selenide with sodium periodate. At...
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Mercury derivatives of polyhedral boranes, carboranes, and metallacarboranes
The review concerns the synthesis, structure, and chemical transformations of mercury derivatives of various polyhedral boron hydrides (carboranes,...
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Synthesis of new functionalized organoselenium compounds by heterocyclization of selenium dihalides with pent-4-en-1-ol
The reaction of selenium dihalides with pent-4-en-1-ol has been carried out for the first time. Efficient procedures for the synthesis of previously...
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An unusually stable pyridine-2-selenenyl chloride: structure and reactivity
According to an X-ray diffraction study, pyridine-2-selenenyl chloride ( 1 ) characterized by unusually high stability both in solutions and in the...
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Extraction and concentration of palladium(II) from simulated refining process solutions using 1Н-1,2,4-triazole derivatives
A procedure was developed for recovery and concentration of residual palladium(II) from a “lean” refining solution by extraction with 1 Н -1,2,4-triazol...
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Physicochemical aspects of the preparation of high-purity arsenic-containing substances from various raw materials
We have developed physicochemical principles of the preparation of high-purity arsenic-containing substances from conventional (As 2 S 3 , As 4 S 4 , and...