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Cluster complexes [Mo3O2S2(Acac)3(Amine)3]PF6
New mixed-ligand cluster complexes [Mo 3 O 2 S 2 (Acac) 3 (Amine) 3 ]PF 6 (Amine = morpholine (Mor), 4-cyanopyridine (PyCN), pyrazine (Pz)) have been...
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MOFs of Uranium and the Actinides
Although the transition d- or 4f-block elements are the most used metals for the construction of metal–organic frameworks (MOFs), actinide cations...
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Crystallographic and structural characterization of heterometallic platinum complexes Part VI. Heterohexanuclear complexes
This review classifies and analyzes heterohexanuclear platinum clusters into seven types of metal combinations:Pt 5 M, Pt 4 M 2 , Pt 3 M 3 , Pt 2 M 4 , PtM 5 , Pt 2 M 3 M...
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Applications of nuclear magnetic resonance to study the structure of platinum-group metal complexes in aqueous solutions
The review includes comprehensive NMR data on platinum metals ( 99,101 Ru, 103 Rh, 105 Pd, 187 Os, 195 Pt) and ligand donor atoms ( 1 H, 13 C, 14,15 N, 17 O, 19 F...
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Coordination of lanthanide cation to an Anderson type polyoxometalate anion leads to isomorphous metal-oxide based one-dimensional inorganic solids: Synthesis, crystal structure and spectroscopy
One-dimensional isomorphous inorganic polymers containing Anderson type heteropoly anion as a basic building unit, namely [La(H 2 O) 7 Cr(OH) 6 Mo 6 O 18 ] n ⋅4nH
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Electronic structure and molecular properties of [Re6−x Os x Se8Cl6](4−x)− (x = 0–3) clusters: A study based on time-dependent density functional theory including spin-orbit and solvent effects
Relativistic time-dependent density functional (TDDFT) calculations including spin-orbit interactions via the zero order regular approximation (ZORA)...
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Synthesis and structures of new octahedral heterometal rhenium-osmium cluster complexes
New octahedral anionic heterometal rhenium-osmium cluster complexes [Re 5 OsSe 8 (OH) 6 ] 3− and [Re 4 Os 2 Se 8 (OH) 6 ] 2− were synthesized starting from [Re 5 OsSe 8 Cl...
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CO oxidation on supported platinum group metal (PGM) based nanoalloys
The oxidation of carbon monoxide is widely investigated for realistic and potential uses in energy production and environmental processes. As a probe...
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Molybdenum Bisphosphonates with Cr(III) or Mn(III) Ions
The synthesis of Mo VI bisphosphonates (BPs) complexes in the presence of a heterometallic element has been studied. Two different BPs have been used,...
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Nanostructured and/or Nanoscale Lanthanide Metal-Organic Frameworks
The research on metal-organic framework (MOF) compounds has developed rapidly, stimulated by not only their aesthetically pleasing structures but...
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Crystalographic and structural characterization of heterometallic platinum compounds. Part III: heterotrinuclear compounds
This review article includes over three hundred and sixty heterotrinuclear platinum complexes of the composition Pt 2 M (205 examples), PtM 2 (132...
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Cuboidal cluster aqua complexes with {M3M′Q4} cores (M = Mo, W; M′ = Ni, Pd; Q = S, Se) and their derivatives
The results of the studies on the synthesis, structure, and reactivity of heterometal cuboidal clusters of Mo and W, {M 3 M′(μ −3 Q) 4 } 4+ (M = Mo, W; Q =...
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Metal exchange in cadmium porphyrins with spatially shielded coordination centers
Shielding of coordination centers in metalloporphyrins (MPs, M = Cd) through covering it with a covalently bonded “lid” or by an endocyclic N -substitu...
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Crystallographic and structural characterization of heterometallic platinum complexes Part V. Heteropentanuclear complexes
This review classifies and analyzes over eighty heteropentanuclear Pt complexes. There are eight types of metal combinations: Pt 4 M, Pt 3 M 2 , Pt 2 M 3 , PtM 4 ...
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Polydentate-ligand-supported self-assembly of heterometallic T-shaped Co4Dy cluster showing slow magnetic relaxation
A novel mixed-valent heterometallic pentanuclear Co III 3 Co II Dy III cluster has been rationally assembled taking advantage of a bifunctional ligand...
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Crystallographic and structural characterization of heterometallic platinum compounds part IV: heterotetranuclear clusters
This review includes over two hundred heterotetranuclear platinum clusters. The clusters are of the compositions Pt 3 M, Pt 3 M 2 , PtM 3 , Pt′ 2 MM′, PtM 2 M′...
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Luminescent Properties and Applications of Metal-Organic Frameworks
Metal-organic frameworks (MOFs) are very promising multifunctional luminescent materials because of their inherent advantages of both organic linkers...
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Crystallographic and structural characterization of heterometallic platinum compounds. Part II. Heterobinuclear Pt compounds with Pt⋯M (M = transition or lantanide metal) > 3.0 Å
This review covers almost two hundred and twenty heterobinuclear platinum compounds in which Pt⋯M separation is over 3.0 Å. The M is a transition...
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Cyanide-bridged complexes based on dinuclear Cu(II)-M(II) [M = Pb and Cu] building blocks: Synthesis, crystal structures and magnetic properties
Four cyanide-bridged heterometallic complexes {[CuPb(L 1 )][Fe III (bpb)(CN) 2 ]} 2 ·(ClO 4 ) 2 ·2H 2 O·2CH 3 CN ( 1 ), {[CuPb(L 1 )] 2 [Fe II (CN) 6 ](H 2 O) 2 }·10H 2 O ( 2 ), {[Cu 2 (L...
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Structural diversity of yttrium(III) halide complexes
X-ray crystallographic data on yttrium(III) compounds containing halide (pseudohalide) ligands in the coordination sphere have been summarized and...