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Oxidative Phenolic Coupling Reaction/Aza-Michael Reaction Strategy for the Synthesis of Complex Polycyclic Alkaloids
The synthesis of alkaloids featuring fused polycyclic frameworks has long attracted the interest of synthetic organic communities, owing to their...
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Synthesis of Polycyclic Systems Based on Sulfolenes
AbstractThe review analyzes and summarizes methods for the synthesis of polycyclic derivatives of sulfolane (sulfolene). The reactions of...
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o-Benzoquinone Cobalt Complexes Bearing Organosilicon Radicals: Quantum-Chemical Study
AbstractA computer modeling (DFT UTPSSh/6-311++G(d,p)) of electronic structures, geometric parameters, energy characteristics, and magnetic...
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Precise heteroatom do** determines aqueous solubility and self-assembly behaviors for polycyclic aromatic skeletons
Develo** effective strategies to improve the hydrophilicity or aqueous solubility of hydrophobic molecular scaffolds is meaningful for both...
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Radical Chemistry on Solid Support
This review covers recent advances in the field of radical chemistry on solid phase. Intermolecular processes using both immobilized radicals with...
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Practical and modular construction of benzo[c]phenanthridine compounds
Here, we describe a general and modular strategy for the rapid assembly of benzo[ c ]phenanthridine (BCP) derivatives using homogeneous gold catalysis....
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Eco-friendly synthesis of substituted tetrahydroquinolines as potential ecdysone receptor agonists
New eco-friendly approaches were proposed for the synthesis of cis -cyclopentene-annulated heterocyclic compounds containing a tetrahydroquinoline...
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Recent progress in carbene-catalyzed fluoroalkylation
The fluoroalkyl fragment plays a vital role in various fields such as pharmaceuticals and materials science, and has a significant impact on human...
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Acceptorless dehydrogenative amination of alkenes for the synthesis of N-heterocycles
Catalytic amination of alkenes is one of the most attractive reactions for the construction of complex heterocycles with nitrogen centers. Herein, we...
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Heterocycles from Donor and Donor/Donor Carbenes
This chapter reviews the recent advances of donor and donor–donor carbenes for the synthesis of heterocycles. Since new sources of donor-type...
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Directed Synthesis of Biologically Interesting Heterocycles with Squaric Acid (3,4-Dihydroxy-3-cyclobutene-1,2-dione) Based Technology
A variety of methods for organic transformation starting from squaric acid have been developed in this decade. These are based on conversion of...
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Catalytic desymmetrization reactions to synthesize all-carbon quaternary stereocentres
The term all-carbon quaternary stereocentre refers to a chiral carbon atom featuring four different carbon substituents. Such structural motifs are...
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Target-oriented synthesis of functionalized pyrazolo-fused medium-sized N,S-heterocycles via Friedel–Crafts ring closure approach
Efficient and concise synthetic protocol to benzo- and pyrazolo-fused medium-sized N,S-heterocycles (e.g, . thiazocinones, thiazoninones,...
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Recent advances in radical-mediated [2+2+m] annulation of 1,n-enynes
1, n -Enynes are a versatile class of unsaturated hydrocarbons that find broad applications in the synthetic community of natural products,...
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Modeling (Prediction) of the Structure of Possible Transition States of Aromatic Hydrocarbons
AbstractBased on the properties of a conjugate p -electron system, a method is proposed for predicting possible spatial structures of aromatic...
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Cutting-Edge Organic Synthesis and Chemical Biology of Bioactive Molecules The Shape of Organic Synthesis to Come
This book describes cutting-edge organic syntheses of biologically active compounds, isolation of pharmaceutically promising compounds from...
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Recent developments in the synthesis of Se-heterocycles applying elemental selenium (microreview)
Se-containing heterocycles are an important class of organic molecules widely used in various fields of chemistry. This microreview summarizes the...
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Total synthesis of terpenes via palladium-catalysed cyclization strategy
Nature’s synthetic plans to construct molecules have been developed over millions of years of evolution and frequently prove to be among the most...
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Synthesis of New Derivatives Benzo[4′,5′]imidazo[2′,1′:6,1]pyrido[2,3-d]pyrimidine
The reactions of 4-methyl- and ( RS )-4,6-dimethyl-2-phenyl-5,6-dihydrobenzo[4′,5′]imidazo-[2′,1′:6,1]pyrido[2,3- d ]pyrimidines and...