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Synthesis, Structure, and Property of Noncentrosymmetrical Coordination Polymer Based on Mixed Functional Ligands and Zinc Ions
AbstractOne 3 d -metal coordination polymer [Zn(Hspas)(Hpco)(H 2 O)] n ( 1 ) (NaH 2 spas = 5-sulfoisophthalic acid monosodium salt, Hpco =...
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Synthesis, structure, adsorption and electrochemical properties of the new two-dimensional cobalt coordination polymer based on bifunctional ligand
A novel two-dimensional coordination polymer {[Co(Htia) 2 (C 2 H 5 OH) 2 ]·H 2 O} n (1) (H 2 tia = 5-(1H-1,2,4-triazol-1-yl)isophthalic acid, C 10 N 3 O 4 H 7 ) was...
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Nickel(II) Coordination Polymer Using Pyrazine Linkers and Phthalate Counter-Anion: Synthesis, Crystal Structure, Hirshfeld Surface and Voids Analysis
AbstractHerein, a new Ni(II) carboxylate polymer, [Ni(Pyr)·4H 2 O]Phth, is synthesized by the reaction of NiSO 4 ·7H 2 O with equimolar amounts of...
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Exploring the Nanomechanical Properties of a Coordination-bond Based Supramolecular Polymer
Due to their dynamic nature and strength tunability, metallo-supramolecular polymers have been introduced into various materials. The mechanical...
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New Cobalt(II) Coordination Polymer Constructed with Nitrogen-Heterocyclic Tricarbolylate Ligands: Synthesis, Structure Analysis, and Magnetic Properties
AbstractNew 2D cobalt(II) coordination polymer {[Co 3 (μ 3 -dppa) 2 (4,4'-bipy) 2 (H 2 O) 4 ]·7H 2 O} n ( 1 ) was constructed hydrothermally using H 3 dppa, 4,4'-bipy...
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Hydrothermal Synthesis of a Novel One-dimensional Cadmium-based Coordination Polymer for Effective Detection of Hazardous Chemicals
A novel one-dimensional coordination polymer, named as {[Cd(ipa)(Hpzp)(H 2 O)]·2H 2 O} n ( Cd-CP ), (where ipa = isophthalic acid,...
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Highly stable Eu-coordination polymer exhibiting the highest quantum yield
Lanthanide luminescent materials with high quantum yield and thermal stability are of key importance for their practical application. Here we report...
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SYNTHESIS, STRUCTURE, AND OPTICAL PROPERTIES OF THE LANTHANUM(III) CATIONIC COORDINATION POLYMER WITH 1,4-DIAZABICYCLO[2.2.2]OCTANE N,N′-DIOXIDE
AbstractThe first example of a coordination polymer with a triply charged metal ion is obtained based on the conformationally mobile bridging ligand...
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Peroxidase-like oxidative activity of cobalt-based 1D coordination polymer; experimental and theoretical investigations
ContextThe present work describes the synthesis, structural characterization, and catalytic activity of a Co(II)-based one-dimensional coordination...
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Detecting phosphate using lysine-sensitized terbium coordination polymer nanoparticles as ratiometric luminescence probes
Probes for detecting phosphate ions (Pi) are required for environmental monitoring and to protect human health. Here, novel ratiometric luminescent...
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Combined separation-assay method for uranium in environmental water using a polyethylene-supported phosphonate coordination polymer membrane
The extraction and accurate analysis of U are of great significance for environmental monitoring. In this study, a novel polyethylene-supported...
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New Three-dimensional Supramolecular Cd(II)-Coordination Polymer as a Luminescent Sensor for Sulfamethazine Detection
A new luminescent three dimensional (3D) supramolecular coordination polymer (CP) with formula [Cd 2 (L) 2 (bib)(H 2 O) 2 ] ( 1 ) (H 2 L = 4,4′-(1,2-phenlenebis(m...
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High-efficiency fluorescent coordination polymer nanoparticles co-doped with Ce3+/Tb3+ ions for curcumin detection
Curcumin (Cur) possesses diverse biological and pharmacologic effects. It is widely used as a food additive and therapeutic medicine. A study to...
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A Zr-based coordination polymer for detection and adsorption of fluoride in water
Long-term excessive uptake of fluoride through potable water will cause adverse effects on human health. Therefore, it is of great significance to...
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Syntheses, Structure and Characterization of a New Pb(II) Coordination Polymer Based on 1,10-Phenanthroline Derivative and 5-Hydroxyisophthalic Acid
A new Pb(II) coordination polymer, namely, [Pb 2 (5-IPA) 2 (L) 2 ]⋅H 2 O ( 1 ) (L = 1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol and 5-H 2 IPA =...
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A Pentanuclear Cu(II)-based 2D Bilayer Coordination Polymer for CO2 Fixation Under Mild Conditions
The recovery of carbon dioxide (CO 2 ) through carbon capture and utilization (CCU) technology to produce valuable chemicals has good industrial...
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A THREE-DIMENSIONAL CADMIUM MIXED LIGANDS COORDINATION POLYMER WITH CO2 ADSORPTION ABILITY
AbstractCarbon dioxide (CO 2 ) is an important metabolite and biological signal gas, and the adsorption of the CO 2 is not only a challenge but also an...
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Hydrothermal synthesis, crystal structure, and visible light photocatalytic hydrogen evolution of a 3D cobalt (II) coordination polymer
In this paper, a 3D cobalt coordination polymer [Co 2 (Medpq) 2 •(H 2 BTC) 3 •OH] n (H 3 BTC = 1,3,5-Benzenetricarboxylic acid,...
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Smart Sensing Supramolecular Coordination Polymer Based on New Viologen Ligand Exhibiting Multiple Solid Detection and Inducing Apoptosis Properties
AbstractThrough the self-assembly of 1,1'-bis(3-cyanobenzyl)-[4,4'-bipyridine]-1,1'-diium (H 2 bcbpy·2Cl) and pyromellitic acid (H 4 BTC), a novel...
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Assembly of a 2D Cd(II) Coordination Polymer from a New Multidentate Ligand 2-((1H-Tetrazol-5-yl)methyl)-1H-imidazole-4,5-dicarboxylic acid
A new substituted imidazole-dicarboxylate compound, namely 2-((1 H -tetrazol-5-yl)methyl)-1 H -imidazole-4,5-dicarboxylic acid (H 4 tamIDC), has been...
