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Article
Modifying Effect of Polyethylene Fractions of Different Molecular Weights on the Morphology and Properties of Reactor Polymer Compositions Based on Ultrahigh Molecular Weight Polyethylene
Reactor polymer compositions (RPCs) based on UHMWPE with Mw = 1000 kg mol–1 and low molecular weight HDPE (LMWPE) were studied. Two series of UHMWPE compositions were used to determine the influence of the molecu...
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Article
Immobilized organometallic catalysts in the catalytic polymerization of olefins
Studies in the field of supported Ziegler-Natta catalysts employed for the polymerization of olefins that were begun by works performed under the guidance of Prof. Chirkov are reviewed in brief. The developmen...
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Article
Modification of polyolefins as a modern strategy to designing polyolefin materials with a new complex of properties
Experimental data on multistage catalytic olefin polymerization processes are generalized. Such processes as the sequential homo-and copolymerization of ethylene and α-olefins; the copolymerization of ethylene...
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Article
Ethylene polymerization with catalysts on the base of Zr-cenes and methylaluminoxanes synthesized on zeolite support
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Article
Influence of the catalyst matrix structure of the supported Ziegler-Natta catalysts on the homo- and copolymerization of olefins
The vanadium catalytic complexes immobilized on the same support (aluminium hydroxide, AH) and distinguished by structure and composition have been compared for ethylene and propylene homo- and copolymerizatio...
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Article
Influence of the nature of monomers on the activity of supported titanium catalysts in the α-olefin polymerization
Ethylene and propylene co-polymerization and sequential polymerization with high activity supported titanium catalysts were studied. Specific rate of homopolymerization and copolymerization constants for ethyl...