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Engineering di-iron enzymes
A dramatic switch of reactivity — from hydroquinone oxidation to N-hydroxylation — can be achieved through the rational engineering of a de novo-designed di-iron protein. Four specific amino-acid mutations spread...
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Probing Mercury Complex Speciation with Multinuclear NMR
Investigation of the solution-state coordination chemistry of mercury presents unique challenges. Multinuclear NMR methods are particularly appropriate for the characterization of mercury complexes in so...