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Synthesis and Structure of Novel Cuprates in the Ba-Y/Ca-Cu-O Systems
Two new compounds in the Ba-Y/Ca-Cu-O systems have been grown as single crystals from a Ba(OH)2H2O flux. The compounds Ba3(Y/Ca, Cu)2O7−δ and Ba(Ca, Cu)O3−δ have the Sr3Ti2O7 and the perovskite structure, respect...
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Article
Synthesis of New Chalcogenide Materials. The Novel One-Dimensional Semiconductor K4Ti3S14
The use of A2 Q/Q melts (A - alkali metal, Q - S or Se) for the synthesis of new one-dimensional solid-state materials is found to be of general utility and is illustrated here for the synthesis of K4 Ti3 SI4. Re...