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Chapter
Anomalous Formation Properties of Nicotinamide Co-crystals
Co-crystals provide an opportunity to improve the properties of organic materials. We report that co-crystals containing nicotinamide (NIC) are anomalous as their formation generally decreases energy but expan...
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Article
A 2-D bimetallic assembly with bridging cyanide ions
A novel cyanide-bridged bimetallic assembly, [Cu(1,3-Pn)2]2[FeIII(CN)6]ClO4 · 2H2O (1,3-Pn = 1,3-diaminopropane), derived from [Fe(CN)6]3− building blocks and four-coordinated bisdiamine metal(II) ions [Cu(1,3-Pn...
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Article
Synthesis and magnetic properties of trinuclear nickel(II) complexes bridged by α-benzyldioximato groups
Four new NiII–NiII–NiII homotrinuclear complexes namely [Ni(α-BD)2{NiL2}](ClO4)2 [L = 1,10-phenanthroline (phen), 5-nitro-1,10-phenanthroline (5-NO2-phen), 2,2′-bipyridyl (bpy) or 4,4′-dimethyl-2,2′bipyridyl (...
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Article
Synthesis and magnetic properties of trinuclear chromium(III)palladium(II)-chromium(III) complexes bridged by extended dioximato groups
Heterotrinuclear CrIII-PdII-CrIII complexes of formulae [Cr(salen)-Pd(dmg)2-Cr(salen)]·H2O (1), [Cr(salen)-Pd(α-BD) 2-Cr(salen)]·H2O (2) and [Cr(salen)-Pd(α-FD) 2-Cr(salen)]·2H2O (3) [dmg2- =dimethyl-glyoximato, ...
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Article
Novel dioximato-bridged chromium(III)-copper(II)-chromium(III) trinuclear complexes with ferromagnetic exchange interactions
Two new dioximato-bridged trinuclear CrII-CuII-CrIII complexes, [Cr(salen)-Cu(α-BD)2-Cr(salen)] (1) and [Cr(salen)-Cu(α-FD)2-Cr(salen)]-H2O (2), have been prepared and characterized [salen2− = N,N′-ethylene- bis ...
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Article
Synthesis and magnetic properties of trinuclear copper(II) complexes bridged by dimethylglyoximate groups
New three CuII-CuII-CuII homotrinuclear complexes have been synthesized, namely [Cu(dmg)2{CuL}2](ClO4)2 [L = 5-nitro-1,10-phenanthroline (5-NO2-phen), 4,4′-dimethyl-2,2′-bipyridiine (DMbpy), tetramethylenediamine...