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Article
Heterometallic Coordination Assembly Catalysts RhIAgIL for Hydroformylation of Long-Chain Alkenes
An innovative bitopic phosphoramidite ligand L was proficiently synthesized and subsequently employed in coordination with two distinct metal species (AgI and RhI), leading to the construction of a heterometallic...
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Article
Highly Efficient and Linear-Selective Hydroformylation of Allyl Acetate Under Mild Conditions Regulated by Additives
1,4-Butanediol, an important chemical raw material, especially as the monomer of engineering plastic polyethylene terephthalate (PBT), plays a pivotal role in contemporary chemicals. A promising parallel appro...
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Article
A Novel Strategy of Homogeneous Catalysis and Highly Efficient Recycling of Aqueous Catalyst for the Hydroformylation of Higher Olefins Based on a Simple Methanol/Water Mixed Solvent
This paper describes the homogeneous catalysis and highly efficient recycling of aqueous catalyst for the hydroformylation of higher olefins in the methanol/water mixed solvent for the first time. When suffici...
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Article
Nonaqueous Biphasic Hydroformylation of Long Chain Alkenes Catalyzed by Water Soluble Phosphine Rhodium Catalyst with Polyethylene Glycol Instead of Water
The application of polyethylene glycol (donated as PEG), as an environmentally benign solvent instead of water, in rhodium catalyzed hydroformylation of long chain alkenes by using water soluble phosphine BISB...
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Article
Influence of crosslinker amount on swelling and gel properties of hectorite/poly(acrylamide/itaconic acid) nanocomposite hydrogels
A new hectorite/poly(acrylamide/itaconic acid) nanocomposite hydrogel was synthesized by inverse microemulsion polymerization. The effects of crosslinker amount on water absorbency and salt absorbency, swellab...
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Article
Synthesis and Solution Properties of Hydrophobically Associative Polyacrylamides by Microemulsion Polymerization
A series of hydrophobic associative copolymers using acrylamide (AM), sodium 4-styrenesulfonate (SSS) and hydrophobic stearyl methylacrylate (SMA) as co-monomers were prepared by microemulsion polymerization. ...
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Article
Synthesis, Characterization of N-Pyrrolylphosphanes Based on Heterocyclic Amine Backbones and Their Application in Hydroformylation of 1-Octene
A new class of N-pyrrolylphosphanes based on new heterocyclic amines have been synthesized, characterized and applied in homogeneous rhodium-catalyzed hydroformylation of 1-octene. These ligands possessing strong...
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Article
An Easily Prepared Tetraphosphine and Its Use in the Palladium-Catalyzed Suzuki–Miyaura Coupling of Aryl Chlorides
An air-stable tetraphosphine N,N,N′,N′-tetra(diphenylphosphinomethyl)-benzene-1,3-diamine (L3) was easily prepared in two steps from triphenylphosphine, which in combination with [Pd(η3-C3H5)Cl]2 affords an effic...
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Article
High Active and Regioselective Hydroformylation of 1-Dodecene Catalyzed by Rh-BISBIS in a Two-Phase System
The hydroformylation of 1-dodecene under aqueous/organic two-phase reaction conditions with rhodium catalysts derived from BISBIS (sodium salt of sulfonated 2,2′-bis (diphenylphosphinomethyl)-1,1′-biphenyl) in...