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Article
EPR of Gd3+ ion in mixed CeO2-Y2O3 nanocrystals
This paper reports on the results of EPR studies of mixed CeO2-Y2O3 crystals (including nanosized crystals) doped by gadolinium ions. It is revealed that the width of the line corresponding to the allowed transit...
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Article
A Q-band pulsed ENDOR spectrometer for the study of transition metal ion complexes in solids
We describe the design of a pulsed electron nuclear double resonance (ENDOR) spectrometer operating at Q-band frequencies (35 GHz) for studies of transition metal ion complexes in the temperature range between...
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Article
Analysis of correlation patterns in hyperfine sublevel correlation spectroscopy ofS=1/2,I=3/2 systems
The properties of two-dimensional four-pulse electron spin echo envelope modulation spectra of nuclei with nuclear spinI=3/2 in disordered systems are discussed by means of calculated lithium hyperfine sublevel c...
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Chapter
Local Ordering Processes in Ferroelectric, Glass-like and Modulated phases: An EPR Study
By means of two selected examples it will be shown that electron paramagnetic resonance (EPR) spectroscopy delivers unique microscopic information about crystals with ferroelectric, glass-like and modulated ph...
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Article
1H ENDOR investigations on gamma-irradiated betaine calcium chloride dihydrate in the incommensurate phase
The electron nuclear double resonance (ENDOR) technique is applied to study the influence of the incommensurate modulation on the proton hyperfine structure (hfs) tensors of the N(CH3)3 radical in betaine calcium...
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Article
Analysis of anisotropic hyperfine interaction distributions in two-dimensional four- and five-pulse electron spin echo envelope modulation spectra of protons in single crystals
The effect of the distribution of anisotropic hyperfine interaction on the cross peak line shape of protons in single crystal two-dimensional four-pulse electron spin echo envelope modulation spectra are discu...
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Article
1H-ENDOR investigations on gamma-irradiated betaine calcium chloride dihydrate at room temperature
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Article
1H-ENDOR investigations on gamma-irradiated betaine calcium chloride dihydrate at room temperature
The ENDOR technique is applied to study the structure of the free radical N(CH3)3, found in the high temperature phase in the incommensurate crystal BCCD after γ-irradiation. The radical possesses a planar struct...
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Chapter and Conference Paper
Structure Determination of Two Mn2+ Paramagnetic Centers in α - LiIO3 by the RFDS and ENDOR Methods
The superhyperfine interactions of two types of Mn 2+ paramagnetic centers have been investigated with the RFDS and ENDOR methods. It was determined that Mn2+ substitutes lithiu...