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Article
Crystal Structure of Layered Cyano-Bridged Coordination Polymers [M(NH3)6]4[{M(NH3)2} {Re3Mo3Se8(CN)6}2]·15H2O (M = Co, Ni)
Two isostructural compounds of the composition [M(NH3)6]4[{M(NH3)2}{Re3Mo3Se8(CN)6}2]·15H2O (M = Co, Ni) are obtained by a reaction of a salt of heterometal cluster [Re3Mo3Se8(CN)6]5− anion with cobalt or nickel ...
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Article
Photothermoelectric (PTE) characterization of CuCrO2 and Cu4Sn7S16 thermoelectric materials
The recently developed photothermoelectric (PTE) calorimetry was applied to measure the thermal parameters of CuCrO2 and Cu4Sn7S16 thermoelectric materials. Both back and front PTE detection configurations were ...
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Article
Decomposition thermique du bis (η-cyclopentadienyle dicarbonyle fer)
The thermal decomposition of bis(η-cyclopentadienyl dicarbonyl iron) in an inert atmosphere at 165° leads to the intermediate cluster (η-C5H5)4 Fe4(CO)4 which is decomposed above 210° into ferrocene. The cluster ...
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Article
Decomposition Thermique du Dimanganese Decacarbonyle et du Dirhenium Decacarbonyle
The thermal behaviours of dimanganese decacarbonyl and dirhenium decacarbonyl were studied by TG, DTG and DTA. The decomposition products in different media were identified by X ray diffraction. In an inert me...