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Article
Spectroscopic study of phosphine selenide complexes of Au(I) and X-ray structure of [(cyclohexyl)3PSeAuBr]
The X-ray structure determination of the complex, [(cyclohexyl)3PSe-AuBr], revealed a triclinic space group P-1, with a = 9.7654(7), b = 10.9441(9), c = 11.2064(9) Å, α = 117.076(6)°, β = 99.076(6)° γ = 95.417(6)...
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Article
The crystal and molecular structure of trans-dimethyl 2α-methyl(3αH) perhydro [1,2]oxazolo-[2,3-a]azepine-2α,3α-dicarboxylate: A 7/5-fused ring system
The title compound crystallizes in the monoclinic space group P21/n, with a = 6.225(1), b = 14.612 (1), c = 15.520 (1) Å, β = 96.6(3)°, Z = 4 and V = 1402.4Å3. The stereochemistry of the 7/5-fused ring system is
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Article
Intramolecular short hydrogen bond: the structure of benzenesulphonylhydrazone derivative of salicylaldehyde
The title compound crystallizes in the monoclinic space group P21/c, witha=10.449(2),b=11.555(1),c=10.854(2) Å, β=90.46(2)° andV=1310.3 Å3. ForZ=4 and F.W.=274.32 the calculated density is 1.39 g/cm3. The structu...
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Article
X-ray photoelectron spectroscopy and Fourier transform-infrared studies of transition metal phosphate glasses
X-ray photoelectron spectroscopy and Fourier transform-infrared studies were carried out on phosphate glasses containing oxides of iron, cobalt, nickel, copper and zinc. The results suggest that the glasses co...
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Article
The structure of 2-phenylperhydro-1,2-oxazolo[3,2-c] [1,4]oxazine
The title compound crystallizes in the monoclinic space group P21/n, witha=9.590(6),b=11.574(2),c=9.609(2) Å, β=105.72(3)o andZ=4. The structure was solved by direct methods and refined by full matrix least squar...
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Article
Crystal and molecular structure of (E)-2-t-butyl-3(3′-t-butyldimethylsiloxy)propyl-2-cyanocyclobutanone
The title compound crystallizes in the monoclinic space group P21/a, witha+12.906(9).b+11.604(2).c+14.631(9) Å, β=108.70(3)° andZ+4. The structure was solved by direct methods from diffractometer data and refined...
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Article
Superconducting ceramics: preparation, XRD, SEM and EPR measurements to study the influence of compositional variations on superconductivity of La-(Ba/Sr/Ca)-CuO ceramic systems
A systematic substitution of strontium ions by barium and/or calcium ions in the 21-structure ternary oxide La1.85Sr0.15CuO4−y, considered as the host system in this study, was carried out to produce four- and fi...
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Article
Tetrahedral complexes of 1,2-dimorpholinoethane and 1,3-dimorpholinopropane: Crystal and molecular structure of dichloro(1,2-dimorpholinoethane)cobalt(II)
The ligands 1,2-dimorpholinoethane (DME) and 1,3-dimorpholinopropane (DMP) have been used to prepare Cu(II), Ni(II), Co(II), Hg(II), Zn(II), and Cd(II) complexes having the general formulationMLX 2 (L=DME and DMP...
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Article
Cobaloxime derivatives: synthesis and spectroscopic studies of alpha-furilglyoximate of cobalt (III), X-ray structure of bis(thiourea)bis(alpha-furilglyoximato)cobalt(III) nitrate
α-Furilglyoxime (H2afdo) complexes of cobalt(III) were used to synthesize H2afdo-cobaloximes with thiourea, triphenylphosphine, and aniline astrans-axial ligands. Encapsulation of the H-bonded species with BF3∶O...
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Article
Crystal and molecular structure of [(4-picolineN-oxide)2H]+ [AuCl4]−: A diadduct revealing a short hydrogen bond
The crystal structure of the [AuCl4]−-stabilized hydronium ion diadduct of 4-picolineN-oxide has been determined using 1388 reflections collected on a CAD4 diffractometer. The structure was refined to anR value o...
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Article
Spectroscopic, electrical and EPR studies of binary semiconducting oxide glasses containing 50 mol% V2O5
Recent measurements on the V2O5-GeO2 glass system consisting of an equimolar mixture of V2O5 and GeO2 revealed that increase in electrical conductivity of these glasses upon annealing could be attributed to the i...
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Article
Gold(I)-selenium bond: synthesis and x-ray structure of chloro(triphenylphosphine selenide)gold(I)
The crystal and molecular structures of chloro(triphenylphosphineselenide)gold(I), [(C6H5)3PSe]AuCl, have been determined from three-dimensional X-ray intensity data collected on a CAD4 diffractometer. The compou...