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Article
Silylation effect on the catalytic properties of FeZSM-11 in benzene oxidation to phenol
The outer surface of FeZSM-11 zeolite was selectively silylated without affecting the inner system of its channels. SiO2 deposition suppressed both the acidity and catalytic activity of the outer surface in mesit...
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Article
Detoxication of nitrose gases formed in the production of adipic acid: The two-stage catalytic cleaning process
A two-stage process was developed for the catalytic cleaning of the nitrose gases formed in the production of adipic acid. The process involves the decomposition of N2O over a Co-ZSM-5-type catalyst and the reduc...
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Article
Role of α-Sites in the selective catalytic reduction of NO x with ammonia over Fe-ZSM-5 catalysts
The catalytic properties of Fe-ZSM-5 zeolites with different iron contents have been investigated in the selective catalytic reduction (SCR) of NO x with ammonia. The observed c...
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Article
Phenol oxidation by nitrous oxide: The role of zeolite catalyst acidity
Gas-phase phenol oxidation using nitrous oxide on zeolite catalysts is of great interest as an alternative method of dihydroxybenzene (DHB) synthesis. Catalysts for conducting this reaction with high selectivi...
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Article
Effect of boron on acid and catalytic properties of Pd-ZSM-23/Al2O3 catalysts in the reaction of diesel fuel hydroisomerization
Effect of the concentration and introduction method of boron on the acid characteristics and catalytic properties of Pd-ZSM-23/Al2O3 catalysts in hydroisomerization of diesel fuel was studied. It was found that r...
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Article
New methods for the preparation of high-octane components from catalytic cracking olefins
A new method has been suggested for the preparation of high-octane components from the butane–butylene fraction (BBF) in two stages. At the first stage, the BBF olefins are oxidized with N2O into carbonyl compoun...
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Article
Isomerization of Ethylene Oxide into Acetaldehyde on Zeolite with MTT (ZSM-23 Type) Structure
It was shown for the example of ZSM-23 zeolite with Si/Al = 50 that medium-porous zeolites with MTT structure are effective catalysts for gas-phase isomerization of ethylene into acetaldehyde. At 300–400°C, a ...
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Article
Influence of Topology and Chemical Composition of MTT and MFI Zeolites on Catalytic Properties in the Isomerization Reaction of Ethylene Oxide to Acetaldehyde
It has been shown by the example of zeolites with the MTT (Al-ZSM-23 and Fe-ZSM-23) and MFI (Al-ZSM-5 and Fe-ZSM-5) structures that mesoporous zeolites are efficient catalysts for the gas-phase isomerization o...
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Article
Isomerization of 1-Butene to 2-Butenes in the Presence of Acid-Base Catalysts
The possibility of reaching the equilibrium in structural isomerization of 1-butene on acid-base catalysts in the temperature interval 20–100°C was examined. This reaction can be used for increasing the 2-bute...
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Article
Synthesis of ZSM-22 and Testing Its Catalytic Properties in the Ethylene Oxide Isomerization Reaction
The influence of the key parameters of the synthesis of a TON-type zeolite (ZSM-22) with or without an organic structure-directing agent on its phase composition has been established. The optimal composition o...
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Article
Influence of Type of Organic Template on the Properties of Zeolites ZSM-23
The influence of the type of organic template from the series: pyrrolidine, dimethylformamide, N-methylpyrrolidone on the physicochemical properties of zeolite of MTT structure (ZSM-23) was studied. The optimal c...
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Article
Effect of the ZSM-23 Synthesis Method on the Properties of Pt/ZSM-23/Al2O3 Catalysts in n-Decane Conversion
Zeolites of the MTT framework type (Si/Al = 30) have been synthesized using dimethylformamide as a template and by a template-free method (Si/Al = 24). The morphology, textural, and acidic properties of the sy...