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Article
New methods for the preparation of high-octane components from catalytic cracking olefins
A new method has been suggested for the preparation of high-octane components from the butane–butylene fraction (BBF) in two stages. At the first stage, the BBF olefins are oxidized with N2O into carbonyl compoun...
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Article
Phenol oxidation by nitrous oxide: The role of zeolite catalyst acidity
Gas-phase phenol oxidation using nitrous oxide on zeolite catalysts is of great interest as an alternative method of dihydroxybenzene (DHB) synthesis. Catalysts for conducting this reaction with high selectivi...
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Article
Role of α-Sites in the selective catalytic reduction of NO x with ammonia over Fe-ZSM-5 catalysts
The catalytic properties of Fe-ZSM-5 zeolites with different iron contents have been investigated in the selective catalytic reduction (SCR) of NO x with ammonia. The observed c...
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Article
Detoxication of nitrose gases formed in the production of adipic acid: The two-stage catalytic cleaning process
A two-stage process was developed for the catalytic cleaning of the nitrose gases formed in the production of adipic acid. The process involves the decomposition of N2O over a Co-ZSM-5-type catalyst and the reduc...
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Article
Silylation effect on the catalytic properties of FeZSM-11 in benzene oxidation to phenol
The outer surface of FeZSM-11 zeolite was selectively silylated without affecting the inner system of its channels. SiO2 deposition suppressed both the acidity and catalytic activity of the outer surface in mesit...