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Romp and Related Chemistry: Past, Present and Fututre
The history of the development of ring-opening metathesis polymerization (ROMP), and the related reactions of olefin metathesis (OM), ring-closing metathesis (RCM), asymmetric ring-closing metathesis (ARCM), a...
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Chapter
The Metathesis Polymerization of Norbornene and Its Derivatives Initiated By Tungsten-Carbene Complexes: Relative Stability of the Intermediate Tungstenacyclo-Butane Complexes
The early stages of the metathesis polymerization of norbomene and some of its endo derivatives, initiated by tungsten-carbene complexes of the type W(CR1R2)(OR3)2Br2.GaBr3, were followed in CD2Cl2 at 200–260 K b...