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Article
Size Dependences of the Thermal Physical Properties of Nanoparticles: Entropy and Heat of Melting
In the thermodynamic theory of phase equilibria in disperse systems, the size dependences of jumps in entropy and the heat of fusion of particles (including those in the nanometer range) are obtained with stri...
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Article
The Dimensional Dependences of the Thermophysical Properties of Nanoparticles: Surface Tension
Within the framework of the thermodynamics of a two-phase system with a curved surface, an equation is obtained for the size dependence of the surface tension of a spherical particle at the boundary with vapor...
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Article
Surface Tension and Parameters of Interatomic Interaction on Surfaces of Binary Solutions
An approach is proposed and used to describe the dependence of surface tension on the composition and temperature of a binary solution without using the traditional approximation of the ratio of coordination n...