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648 Result(s)
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Chapter
Corey-Kim oxidation
Oxidation of alcohol to the corresponding aldehyde or ketone using NCS/DMF, followed by treatment with a base.
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Chapter
Ring-closing metathesis (RCM) using Grubbs and Schrock catalysts
A selenium dioxide oxidation of activated methylenes into ketones.
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Chapter
Herz reaction
Treatment of anilines with sulfur monochloride to produce thiazothionium chlorides, which upon treatment with base give α-aminothiophenols.
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Chapter
Williamson ether synthesis
Ether from the alkylation of alkoxides by alkyl halides.
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Chapter
Hodges-Vedejs metallation of oxazoles
Metallation of an oxazole followed by treatment with benzaldehyde results in a 4-substituted oxazole as the major product [1]:
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Chapter
Wohl-Ziegler reaction
Radical-initiated allylic bromination using NBS, and catalytic AIBN as initiator or NBS under photolysis.
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Chapter
Stieglitz rearrangement
Rearrangement of trityl N-haloamines.
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Chapter
Stobbe condensation
Condensation of diethyl succinate and its derivatives with carbonyl compounds in the presence of a base.
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Chapter
Boord reaction
Olefin from the treatment of β-halo-alkoxide with zinc.
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Chapter
Noyori asymmetric hydrogenation
Asymmetric reduction of carbonyl via hydrogenation catalyzed by ruthenium(II) BINAP complex.
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Chapter
Luche reduction
1,2-Reduction of enones using NaBH4-CeCl3.
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Chapter
Madelung indole synthesis
Indoles from the intramolecular cyclization of 2-(acylamino)-toluenes using strong bases.
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Chapter
Aldol condensation
Condensation of a carbonyl with an enolate or an enol. A simple case is addition of an enolate to an aldehyde to afford an alcohol, thus the name aldol.
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Chapter
Fischer-Hepp rearrangement
Transformation of N-nitroso-anilines to the corresponding para-nitroso anilines. Cf. Orton rearrangement.
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Chapter
Forster reaction
α-Diazoketone formation from α-oximinoketones.
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Chapter
Reissert reaction (aldehyde synthesis)
Aldehyde synthesis from the corresponding acid chloride, quinoline, and KCN.
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Chapter
Cornforth rearrangement
Thermal rearrangement of keto-oxazoles.
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Chapter
Robinson annulation
Michael addition of cyclohexanones to methyl vinyl ketone followed by intramolecular aldol condensation to afford six-membered α,β-unsaturated ketones.
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Chapter
Hofmann-Löffler-Freytag reaction
Formation of pyrrolidines or piperidines by thermal or photochemical decomposition of protonated N-haloamines.
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Chapter
Wolff-Kishner reduction
Carbonyl reduction to methylene using basic hydrazine.