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A directive Ni catalyst overrides conventional site selectivity in pyridine C–H alkenylation

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  1. Article

    Open Access

    Ni-catalyzed benzylic β-C(sp3)–H bond activation of formamides

    The development of transition metal-catalyzed β-C–H bond activation via highly-strained 4-membered metallacycles has been a formidable task. So far, only scarce examples have been reported to undergo β-C–H bond a...

    Rong-Hua Wang, Wei-Wei Xu, Hongli Wu, Yue Li, Jiang-Fei Li… in Nature Communications (2022)

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  2. Article

    Open Access

    Construction 7-membered ring via Ni–Al bimetal-enabled C–H cyclization for synthesis of tricyclic imidazoles

    The construction of 7-membered ring via direct C7–H cyclization of benzoimidazoles with alkenes would provide a more atom- and step-economical route to tricyclic imidazoles and derivatives that widely exist in...

    Jiang-Fei Li, Wei-Wei Xu, Rong-Hua Wang, Yue Li, Ge Yin… in Nature Communications (2021)

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