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  1. No Access

    Article

    An artificial [FeFe]-hydrogenase mimic with organic chromophore-linked thiolate bridges for the photochemical production of hydrogen

    An artificial [FeFe]-hydrogenase ([FeFe]-H2ase) mimic 3II, consisting of dual organic chromophores covalently assembled to the [Fe2S2] active site, was constructed for light-driven hydrogen evolution. The structu...

    Shang Gao, Wei-Yi Zhang, Qian Duan, Qing-Cheng Liang, Da-Yong Jiang… in Chemical Papers (2017)

  2. No Access

    Article

    Influence of the methylene group between azadithiolate nitrogen atom and phenyl moiety on the protophilic properties of [FeFe]-hydrogenase model complexes

    An [FeFe]-hydrogenase mimic 4 with functional benzyl moiety covalently linked to the azadithiolate ligand was synthesized. The structure, protonation, and electrochemical properties of 4 and a phenyl substituted ...

    Shang Gao, Ting-Ting Yang, Jian-Xun Zhao, Qian Duan, Qing-Cheng Liang… in Chemical Papers (2017)