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Article
Synthesis, structural characterization and bonding properties of heterometallic-heterobridging cubane-type tetranuclear cluster compounds [CuMo3OS3]·I·(μ-OAc)[S2P(OC2H5)2]3·L (L=py, DMF)
By the reaction of cluster [Mo3OS3](dtp)4(H2O) used as starting material with CuI using [3+1] mode, two novel heterometallic-heterobridging cubane-type tetranuclear cluster compounds [CuMo3OS3]·I·(μ-OAc)[S2P(OC2H
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Article
The synthesis and crystal structure of novel Mo-Sn tetranuclear cubane-like cluster [Mo3(SnBr3)(μ3-O)(μ3-S)3(dtp)3(py)3]·(CH2Cl2)
The synthesis and crystal structure of the first example for hybrid Sn-Mo tetranuclear cubane-like cluster compound containing S/O mixed triple cap** atom [Mo3(SnBr3)(μ 3-O)(μ 3-...
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Article
Three Heterometallic Mo–M′ Cubane-Like Tetranuclear Cluster Compounds (M′=Cu, Pb, Sb): Synthesis, Structure and Third-Order NLO Property
Three new heterometallic tetranuclear cluster compounds with a [Mo3YS3M′] cubane-like cluster core (M′=Cu, Pb, Sb; Y=O, S), [Mo3OS3(CuI)(μ-OAc)2(dtp)2(DMF)] (1), (dtp=S2P(OC2H5)− 2), [Mo3OS3(PbI3)(dtc)3(py)3] (2)...