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  1. No Access

    Article

    Copper Grown Diamond Films

    Diamond has been synthesised on copper using Microwave Plasma Chemical Vapour Deposition (MPCVD). The effect of substrate pre-treatment including different polishing and cleaning on diamond nucleation was inve...

    E. Pereira, Qi Hua Fan, J. Gracio in MRS Online Proceedings Library (1996)

  2. No Access

    Article

    Quantitative evaluation of adhesion of diamond coatings

    This paper presents a model to evaluate quantitatively the adhesion of diamond coating according to indentation tests. It is found that small indentation load causes round spallation of the coating, no matter ...

    Qi Hua Fan, A. Fernandes, E. Pereira, J. Grácio in Journal of Materials Research (1999)

  3. No Access

    Article

    Diamond deposition on copper: studies on nucleation, growth, and adhesion behaviours

    This paper presents a systematic study on diamond growth on copper by microwave plasma chemical vapour deposition (MPCVD). It includes the following four main parts. 1. Effect of substrate pre-treatment on dia...

    Q. H. Fan, E. Pereira, J. Grácio in Journal of Materials Science (1999)

  4. No Access

    Article

    A new surface pretreatment approach for enhancing diamond nucleation

    In this paper we present a new approach of surface pretreatment for enhancing diamond nucleation. The copper substrates were fixed inside a plastic cylinder container with diamond powder diluted in water. This...

    Qi Hua Fan, A. Fernandes, E. Pereira, J. Grácio in Journal of Materials Research (1999)

  5. No Access

    Article

    Study of diamond adhesion behavior on chromium and titanium for obtaining adherent diamond coatings on steel

    It is known that diamond films display poor adhesion on metals such as copper and steel. One solution to overcome the poor adhesion is to use interlayer materials. In this study we report results of an investi...

    Q. H. Fan, J. Grácio, E. Pereira, N. Ali, W. Ahmed in Journal of Materials Research (2000)

  6. No Access

    Article

    Novel Time-modulated Chemical Vapor Deposition Process for Growing Diamond Films

    Smooth polycrystalline diamond films were deposited onto silicon substrates using a newly developed time-modulated chemical vapor deposition (TMCVD) process. The distinctive feature of the TMCVD process involv...

    Q H Fan, N. Ali, Y. Kousar, W. Ahmed, J. Gracio in Journal of Materials Research (2002)

  7. No Access

    Article

    Promoting secondary nucleation using methane modulations during diamond chemical vapor deposition to produce smoother, harder, and better quality films

    In this paper, we present results obtained from a comparison study relating to the deposition of diamond films using two processes, namely, time-modulated chemical vapor deposition (TMCVD) and conventional CVD...

    N. Ali, V. F. Neto, J. Gracio in Journal of Materials Research (2003)

  8. No Access

    Article

    Role of substrate temperature during diamond film growth using the newly developed time-modulated chemical vapor deposition process

    N. Ali, Y. Kousar, Q. H. Fan, V. F. Neto, J. Gracio in Journal of Materials Science Letters (2003)

  9. No Access

    Article

    Growth of (100) oriented diamond grains by the application of lateral temperature gradients across silicon substrates

    Polycrystalline diamond films with a predominant (100) texture were deposited onto silicon substrates using hot-filament chemical vapor deposition. During film deposition, different temperature gradients were ...

    E. Titus, D. S. Misra, Manoj K. Singh, Pawan K. Tyagi in Journal of Materials Research (2004)

  10. No Access

    Article

    Time-modulated chemical vapor deposition of diamond films

    This article investigates the role of substrate temperature in the deposition of diamond films using a newly developed time-modulated chemical vapor deposition (TMCVD) process. TMCVD was used to deposit polycr...

    M. J. Jackson, G. M. Robinson, W. Ahmed in Journal of Materials Engineering and Perfo… (2005)

  11. No Access

    Article

    Structural Modeling of the Mechanical Behavior of Periodic Cellular Solids: Open-Cell Structures

    The numerical simulation of random cellular metals, e.g., metal foams, is still connected with many unsolved problems due to their stochastic structure. Therefore, a periodic model of cellular metals is develo...

    T. Fiedler, A. Ochsner, J. Gracio, G. Kuhn in Mechanics of Composite Materials (2005)

  12. No Access

    Article

    Investigation of cellular solids under biaxial stress states

    The determination of the yield surface of cellular and porous materials requires experimental procedures under multi-axial stress states as the yield behavior is sensitive to the hydrostatic stress and as simp...

    A. Öchsner, G. Kuhn, J. Grácio in Experimental Mechanics (2005)

  13. No Access

    Article

    Cobalt diffusion in different microstructured WC-Co substrates during diamond chemical vapor deposition

    Our investigation on diamond deposition using cemented tungsten carbide (WC-Co) has shown that diamond particles deposit at different rates onto micrograin and coarse-grain WC-Co substrates. Diamond deposition...

    G. Cabral, N. Ali, E. Titus, J. Gracio in Journal of Phase Equilibria and Diffusion (2005)

  14. No Access

    Chapter and Conference Paper

    Numerical and experimental studies of damage in porous materials

    Metallic foams comprise a steadily growing group of porous materials and are gaining more and more importance in industrial applications. Main advantages of this innovative material are high ability of energy ...

    T. Fiedler, A. Öchsner, J. Grácio, L. Cunda in III European Conference on Computational M… (2006)

  15. No Access

    Chapter and Conference Paper

    Influence of the morphology of adhesive joining on the mechanical properties of periodic metal hollow-sphere-structures

    Hollow-sphere-structures (HSS) originate a new group of cellular materials characterised by a high reproducibility of geometry and therefore mechanical properties. Well-known advantages of cellular materials a...

    T. Fiedler, A. Öchsner, J. Grácio in III European Conference on Computational Mechanics (2006)

  16. No Access

    Article

    Time-modulated CVD process optimized using the taguchi method

    The Taguchi method is used herein to optimize the time-modulated chemical vapor deposition (TMCVD) process. TMCVD can be used to deposit smooth, nanocrystalline diamond (NCD) coatings onto a range of substrate...

    W. Ahmed, E. Ahmed, C. Maryan, M. J. Jackson in Journal of Materials Engineering and Perfo… (2006)

  17. No Access

    Article

    Human microvascular endothelial cell seeding on Cr-DLC thin films for heart valve applications

    In this investigation, Cr-modified diamond-like carbon (Cr-DLC) films were studied for potential applications in mechanical heart valves. Three Cr-DLC samples were prepared using a magnetron sputtering techniq...

    N. Ali, Y. Kousar, J. Gracio, E. Titus in Journal of Materials Engineering and Perfo… (2006)

  18. No Access

    Article

    Chemically functionalized carbon nanotubes and their characterization using thermogravimetric analysis, fourier transform infrared, and raman spectroscopy

    This article reports key findings on the chemical functionalization of carbon nanotubes (CNT). The functionalization of chemical vapor-deposited CNT was carried out by treating tubes with polyvinyl alcohol thr...

    E. Titus, N. Ali, G. Cabral, J. Gracio in Journal of Materials Engineering and Perfo… (2006)

  19. No Access

    Article

    Modelling the mechanical behaviour of adhesively bonded and sintered hollow-sphere structures

    The mechanical properties of periodic hollow-sphere structures are investigated numerically. Young’s modulus and the Poisson ratio are determined in order to describe their linearly elastic behaviour. The init...

    T. Fiedler, B. Sturm, A. Öchsner, J. Gracio, G. Kühn in Mechanics of Composite Materials (2006)

  20. No Access

    Article

    Adsorption and desorption of oxygen at metal-oxide interfaces: Two-dimensional modeling approaches

    A numerical approach is presented for the segregation of atomic oxygen at Ag-MgO interfaces for a system of MgO particles dispersed in an Ag matrix. General segregation kinetics is considered, and the coupled ...

    A. Öchsner, J. Grácio, M. Stasiek in Journal of Phase Equilibria and Diffusion (2006)

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