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Article
The Synthesis, Condensation, and Luminescence of Stilbenoid Oligomers with Alkoxysilane End Groups
A synthetic route to highly luminescent organic semiconductors with curable alkoxysilyl groups is described. Monodisperse oligo(phenylenevinylene)s are rigidly connected to di- and triethoxysilanes via Heck re...
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Article
Tetrahedra from Aryleneethenylenes–From small Molecules to Luminescent Glasses
The fourfold Horner olefination of tetraphenylmethane or–silane with four p-methylphosphonate groups and a variety of aromatic aldehydes with donor groups or extended conjugated systems results in the formation o...
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Article
Oligo(phenylenevinylene)s end-capped with phenothiazine or triphenylamine
Monodisperse oligo(phenylenevinylene)s end-capped with arylamines have been prepared via Horner Olefinations from bisphosphonates and arylaminobenzaldehydes. The influences of the conjugation length, different...